오렌지꽃오일

오렌지꽃오일
오렌지꽃오일 구조식 이미지
카스 번호:
8016-38-4
한글명:
오렌지꽃오일
동의어(한글):
오렌지꽃오일
상품명:
Neroli oil
동의어(영문):
FEMA 2771;NEROLI OIL;Oils,neroli;OIL OF ORANGE;ESSENCEOFNEROLI;CITRUS AURANTIUM;SWEET ORANGE OIL;Orangeblossomoil;ORANGE FLOWER OIL;OILNEROLITUNISIAN
CBNumber:
CB8280699
분자식:
포뮬러 무게:
0
MOL 파일:
Mol file
MSDS 파일:
SDS

오렌지꽃오일 속성

끓는 점
163 °C(lit.)
밀도
0.868 g/mL at 25 °C(lit.)
증기압
0.002-536Pa at 25℃
굴절률
n20/D 1.47(lit.)
FEMA
2771 | NEROLI BIGARDE OIL (CITRUS AURANTIUM L.)
인화점
70 °C
물리적 상태
액체
색상
연한 노란색에서 호박색의 액체. 네롤리 오일의 주성분은 디펜텐, 피넨, 캄펜, l-리나룰, l-리나릴 아세테이트 등입니다.
냄새
100.00%에서. 꽃무늬의 오렌지꽃 감귤류의 페티그레인 만다린 허브
?? ??
꽃향기
LogP
2.05-5.77
EPA
Oils, neroli (8016-38-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
WGK 독일 2
RTECS 번호 QQ0960000
독성 The acute oral LD50 value in rats was reported as 4.55 ±0.105 g/kg and the acute dermal LD50 value in rabbits exceeded 5 g/kg (McGee, 1974).
기존화학 물질 KE-27147
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H304 삼켜서 기도로 유입되면 치명적일 수 있음 흡인 유해성물질 구분 1 위험 GHS hazard pictograms
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P272 작업장 밖으로 오염된 의복을 반출하지 마시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P310 즉시 의료기관(의사)의 진찰을 받으시오. 삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.
P321 (…) 처치를 하시오.
P332+P313 피부 자극이 생기면 의학적인 조치· 조언을 구하시오.
P333+P313 피부자극성 또는 홍반이 나타나면 의학적인 조치·조언를 구하시오.
P362 오염된 의복을 벗고 세척 후에 재사용하기
P363 다시 사용전 오염된 의류는 세척하시오.
P391 누출물을 모으시오.
P501 ...에 내용물 / 용기를 폐기 하시오.

오렌지꽃오일 C화학적 특성, 용도, 생산

개요

Neroli bigarade is a product obtained by processing flowers of the bitter orange tree. The blossoming flowers are the only part used. Neroli bigarade has a very powerful floral odor with a bitter flavor.
The essential oil is obtained in ca 0.1% yields by steam distillation of the flowers. The distillation waters, rich in dissolved essence, are used as is in perfumery, cosmetics, and sweets. Neroli bigarade essential oil, or simply neroli oil, has slightly different physical- chemical properties depending on its origin. Italian neroli oil, qualitatively equal to the French product of much larger production, is a pale-yellow to amber liquid, slightly fluorescent, with an intense, suave, flowery aroma.
The main constituents include pinene, camphene, dipentene, lina-lool, ι-linalyl acetate, α-terpineol, geraniol, nerol, nerolidol, methyl anthranilate, indole, farnesol, and phenylacetic acid esters.
The derivatives are concrete and absolute. Orange flower concrete is obtained in 0.24 to 0.28% yields by extracting freshly picked flowers with a solvent (usually petroleum ether). Treatment of the concrete with ethanol produces the orange flower absolute in approximately 50% yields. The absolute is a yellow-red liquid with an extremely suave odor typical of the flower.

화학적 성질

Neroli oil and orange flower absolute are obtained from the blossoms of the bitter orange tree, C. aurantium L., which is grown in the Mediterranean region. Neroli oil is produced by steam distillation and is a pale yellow to amber-colored liquid, with a slight blue fluorescence and a characteristic sweet, spicy, bitter odor of orange blossom.
d2020 0.863–0.876/0.870–0.880; n20D 1.464–1.474/1.465–1.472; α20D +2 ° to +12 °/+2 ° to +11 °; solubility: 1 vol in not more than 3.5 vol of 85% ethanol at 20 ℃; acid number: max. 2.0; linalool content by GC 26–48%/26–55% (oils of Tunisia and Morocco/Egypt).
After separation of neroli oil, the aqueous layer of the steam distillate, known as orange blossom water, is extracted with suitable solvents (e.g., petroleum ether). Evaporation gives orange flower water absolute (absolue de 1’eau de fleurs d’oranger), which is a dark brown-red liquid. It contains less terpene hydrocarbons and correspondingly more polar compounds than neroli oil.
Orange flower absolute is obtained from the blossoms by solvent extraction via the concrete. It is a dark brown liquid with a warm, spicy, bitter odor.
Themain volatile constituent of all three products is linalool. Their typical flavor is created by a number of nitrogen-containing trace constituents, such as indole and derivatives of anthranilic acid.

물리적 성질

Neroli bigarade essential oil has slightly different physical chemical properties depending on its origin. Italian neroli oil, qualitatively equal to the French product of much larger production, is a pale-yellow to amber liquid, slightly fluorescent

출처

Found in the blossoms of C. aurantium L. (Fam. Rutaceae) (Guenther, 1949).

용도

neroli oil is a fragrance. It is used in skin care preparations to stimulate cell regeneration. given its sedative and soothing properties, it is indicated for sensitive and delicate skin. However, neroli oil appears beneficial for all skin types. True neroli is extracted from bitter orange blossom. This is one of the most expensive oils and, therefore, is widely adulterated with the distillation of other citrus blossoms such as sweet orange, lemon, and mandarin.

제조 방법

By distillation of the blossoms of C. aurantium (Poucher, 1974).

Essential oil composition

The main constituents include pinene, camphene, dipentene, linalool, l-linalyl acetate, α-terpineol, geraniol, nerol, nerolidol, methyl anthranilate, indole, farnesol and phenylacetic acid esters (Burdock, 1997). Neroli essential oil has been reported to contain terpenic hydrocarbons (mainly limonene 9 to 18%, β-pinene 7 to 17%, α-pinene <2%, myrcenel), terpenic alcohols and esters (linalool 28 to 44%, α-terpineol 2 to 5.5%, nerolidol 1 to 5%, farnesol 1 to 4%, linalyl acetate 3 to 15%, neryl acetate <2.5%, geranyl acetate 1 to 5%) (CoE, 2000).

일반 설명

Clear golden, fluorescent liquid with a very intense and pleasant odor.

공기와 물의 반응

Insoluble in water.

반응 프로필

FEMA 2771 turns brown on exposure to light.

화재위험

FEMA 2771 is probably combustible.

오렌지꽃오일 준비 용품 및 원자재

원자재

준비 용품


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