운데칸알

운데칸알
운데칸알 구조식 이미지
카스 번호:
112-44-7
한글명:
운데칸알
동의어(한글):
운데칸알;운데카날
상품명:
Undecanal
동의어(영문):
ALDEHYDE C-11;ALDEHYDE C-11 UNDECYLIC;HENDECANAL;n-Undecanal;1-UNDECANAL;Hendecanaldehyde;Undecanylaldehyde;FEMA 3092;UNDECANAL;α-Undecanone
CBNumber:
CB8381473
분자식:
C11H22O
포뮬러 무게:
170.29
MOL 파일:
112-44-7.mol
MSDS 파일:
SDS

운데칸알 속성

녹는점
-2 °C (lit.)
끓는 점
109-115 °C/5 mmHg (lit.)
밀도
0.825 g/mL at 25 °C (lit.)
증기 밀도
5.94 (vs air)
증기압
38Pa at 20℃
FEMA
3092 | UNDECANAL
굴절률
n20/D 1.4322(lit.)
인화점
205 °F
저장 조건
Inert atmosphere,2-8°C
색상
무색~연황색
냄새
디프로필렌 글리콜 중 1.00%. 왁스 같은 비누 꽃 무늬 알데히드 감귤류 녹색 지방 신선한 세탁물
?? ??
알데히드계
폭발한계
0.7%(V)
수용성
디프로필렌 글리콜, 고정 오일, 프로필렌 글리콜 및 물에 용해됨(25°C에서 14.27 mg/L)
감도
Air Sensitive
JECFA Number
107
BRN
1753213
Dielectric constant
2.0(20℃)
LogP
4.8 at 20℃
CAS 데이터베이스
112-44-7(CAS DataBase Reference)
NIST
Undecanal(112-44-7)
EPA
Undecanal (112-44-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38-38
안전지침서 26
WGK 독일 1
RTECS 번호 YQ1500000
TSCA Yes
HS 번호 2912.19.5000
기존화학 물질 KE-35050
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H227 가연성 액체 인화성 액체 구분 4 경고 P210, P280, P370+P378, P403+P235,P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
예방조치문구:
P403+P235 환기가 잘 되는 곳에 보관하고 저온으로 유지하시오.
NFPA 704
0
0 0

운데칸알 C화학적 특성, 용도, 생산

화학적 성질

Undecanal is a colorless liquid with a sweetish, fatty odor with an orange and rose undertone. It has a characteristic flavor. This chemical tends to polymerize unless tightly sealed. It is soluble in oils and alcohol, but insoluble in glycerol and water. Additionally, it is combustible.

출처

Reported found in essential oils of citrus peels, lemon, caviar, cooked beef, chicken, lamb, pork, coriander leaf, cucumber, fish, grapefruit juice, apple, orange juice, bilberry, cranberry, raspberry, blackberry, carrot, celery, baked potato, Gruyere cheese, Russian cheese, butter, milk, fatty fish, hop oil, beer, cognac, tea, peanut oil, pecan, starfruit, coriander seed, rice, calamus, buckwheat, red sage, loganberry and maté.

용도

Undecanal is a flavoring agent that is a liquid, colorless or pale yellow, with a sweet odor. it is soluble in most fixed oils, mineral oil, and propylene glycol; insoluble in glycerin. it is obtained by chemical synthesis. it is also termed aldehyde c-11 undecyclic and n-undecyl aldehyde.

제조 방법

Usually prepared by oxidation of the corresponding alcohol or reduction of the corresponding acid.

정의

ChEBI: Undecanal is a saturated fatty aldehyde formally arising from reduction of the carboxylic acid group of undecanoic acid. It is a component of essential oils from citrus plants like Citrus reticulata. It has a role as an antimycobacterial drug, a volatile oil component and a plant metabolite. It is a saturated fatty aldehyde, a n-alkanal and a medium-chain fatty aldehyde. It is a tautomer of an undec-1-en-1-ol.

일반 설명

Undecanal is a volatile flavor compound identified in grapefruit oil and orange essential oil. It is used as a pharmaceutical intermediate.

위험도

Toxic by ingestion and inhalation, irritant to tissue.

Safety Profile

Low toxicity by ingestion and skin contact. A skin irritant. Combustible liquid when exposed to heat or flame. To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.

참고 문헌

C.M Paleos Angelos Malliaris. Chemical evidence concerning the solubilization site of undecanal in micelles. Journal of Colloid and Interface Science. 1981, 82 (1), 244-247. DOI:10.1016/0021-9797(81)90145-4
George W. Mushrush, Robert N. Hazlett, Harold G. Eaton. Liquid-phase oxidation of undecanal by tert-butyl hydroperoxide in dodecane. Ind. Eng. Chem. Prod. Res. Dev. 1985, 24 (2), 290-293. DOI:10.1021/I300018A023
Kinetic Modeling of Rhodium‐Catalyzed Reductive Amination of Undecanal in Different Solvent Systems DOI:10.1002/cite.201900135
Chen Wen-kan. Synthesis of Undecanal by Selective Oxidation of Undecanol. Chemistry 2015

운데칸알 준비 용품 및 원자재

원자재

준비 용품


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