엔도탈

엔도탈
엔도탈 구조식 이미지
카스 번호:
145-73-3
한글명:
엔도탈
동의어(한글):
엔도탈;1,2-벤젠다이카복실산, 헥사하이드로-3,6-엔도-옥시-;1,2-사이클로헥세인다이카복실산, 3,6-엔도-에폭시-;3,6-엔도-에폭시-1,2-사이클로헥세인다이카복실산;3,6-엔도옥소헥사하이드로프탈산;3,6-엔독소헥사하이드로프탈산;7-옥사바이사이클로[2.2.1]헵테인-2,3-다이카복실산;7-옥사비시클로(2.2.1)헵탄-2,3-디카르복시산;헥사하이드로-3,6-엔도-옥시-1,2-벤젠다이카복실산;헥사하이드로-3,6-엔도옥시프탈산
상품명:
ENDOTHAL
동의어(영문):
Hydout;ENDOTHAL;Aquothol;Emdothal;Aquathol;Hydrothol;ENDOTHALL;Hydrothal;Niagrathal;ACCELERATE
CBNumber:
CB8477916
분자식:
C8H10O5
포뮬러 무게:
186.16
MOL 파일:
145-73-3.mol
MSDS 파일:
SDS

엔도탈 속성

녹는점
179-180℃
끓는 점
447.8±40.0 °C(Predicted)
밀도
1.431 g/cm3
저장 조건
+2C to +8C
용해도
DMF: 15 mg/ml,DMSO: 15 mg/ml,Ethanol: 15 mg/ml,PBS (pH 7.2): 0.2 mg/ml
물리적 상태
흰색 고체
산도 계수 (pKa)
3.62±0.40(Predicted)
수용성
물(>25 mg/ml), 메탄올, 아세톤 및 DMSO에 용해됩니다. 벤젠에 불용성.
안정성
흡습성
CAS 데이터베이스
145-73-3(CAS DataBase Reference)
EPA
Endothall (145-73-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T
위험 카페고리 넘버 21-25-36/37/38
안전지침서 36/37/39-45
유엔번호(UN No.) UN 2811 6.1/PG 2
WGK 독일 1
RTECS 번호 RN7875000
위험 등급 6.1(a)
포장분류 II
유해 물질 데이터 145-73-3(Hazardous Substances Data)
독성 LD50 in adult male, female rats (mg/kg): 57, 46 orally (Gaines, Linder)
기존화학 물질 KE-05-0940
유해화학물질 필터링 97-1-194
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 엔도탈 및 이를 1% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H312 피부와 접촉하면 유해함 급성 독성 물질 - 경피 구분 4 경고 GHS hazard pictograms P280,P302+P352, P312, P322, P363,P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P405 밀봉하여 저장하시오.
NFPA 704
0
2 0

엔도탈 C화학적 특성, 용도, 생산

화학적 성질

Endothall, when pure, is a white crystalline solid. The technical grade is a light brown liquid

용도

Endothall is used as an inhibitor of PP2A phosphatase activity. It is also used as a defoliant. It is used as a cell adhesion inhibitor.

일반 설명

The monohydrate is in the form of colorless crystals. Non corrosive. Used as a selective herbicide.

공기와 물의 반응

Stable up to 90°C, above which ENDOTHAL undergoes slow hydrolysis.

반응 프로필

A phthalic acid derivative.

위험도

Strong irritant to eyes and skin.

농업용

Herbicide, Algaecide: Endothall is used as a cotton defoliant and as a selective contact herbicide on both terrestrial and aquatic weeds. The potassium and amine salts of endothall are used as aquatic herbicides to control a variety of plants including plankton, pondweed, niad, coontail, milfoil, elodea, and algaes in water bodies and rice fields. Endothall is also used to control annual grass and broadleaf weeds in sugar beets, spinach and turf. It reduces sucker branch growth in hops. Endothall is a desiccant to aid the harvest of alfalfa, potatoes, clover, and cotton. Not approved for use in EU countries. Approved for use in the U.S. and other countries. There are 24 global suppliers.

상품명

ACCELERATE®; AQUATHOL®; DES-I-CATE®; HYDOUT®; HYDROTHAL-47®; HYDROTHOL®; NIAGARATHOL®; RIPENTHOL®; TRI-ENDOTHAL®

Safety Profile

Poison by ingestion. Very irritating to skin, eyes, and mucous membranes. Causes dlarrhea. When heatedto decomposition it emits acrid smoke and fumes

잠재적 노출

Endothall is dicarboxylic acid defoliant and herbicide used on both terrestrial and aquatic weeds.

환경귀착

Biological. Incubation of 14C-ring labeled endothall (10 mg/mL) by Arthrobacter sp., which was isolated from pond water and a hydrosol, in aerobic sediment-water suspensions revealed that after 30 days, 40% evolved as 14CO2. Glutamic acid was the major transformation product. Minor products were alanine, citric and aspartic acids and unidentified products, some of which were tentatively identified as phosphate esters (Sikka and Saxena, 1973). In pond water treated with endothall (2 and 4 ppm), detectable levels were found after 7 days (Sikka and Rice, 1973). Biodegradation was rapid in an Ontario soil sample. After 1 week, 70% of endothall added was converted to carbon dioxide (Simsiman et al., 1976).
Chemical/Physical. Reacts with bases forming water-soluble salts. Above 90°C, endothall is slowly converted to the anhydride (Windholz et al., 1983; Hartley and Kidd, 1987) and water (Humburg et al., 1989). Endothall is stable to light (Hartley and Kidd, 1987).

운송 방법

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

비 호환성

Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur)

폐기물 처리

Small quantities may be disposed of by burial in soil which is rich in organic matter. Large quantities are best disposed of by incineration. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (5100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office

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