2-카르복시에틸 2-프로페노산염

2-카르복시에틸 2-프로페노산염
2-카르복시에틸 2-프로페노산염 구조식 이미지
카스 번호:
24615-84-7
한글명:
2-카르복시에틸 2-프로페노산염
동의어(한글):
2-카르복시에틸2-프로페노산염;2-카르복시에틸2-프로페노산염(2-CARBOXYETHYL2-PROPENOATE);카복시에틸아크릴레이트
상품명:
2-Carboxyethyl acrylate
동의어(영문):
B-CEA;3-(acryloyloxy)propanoic acid;β-Carboxyethyl acrylate;sipomerb-cea;Solvay β-CEA;Einecs 246-359-9;RARECHEM AL BO 0311;2-CARBOXYETHYL ACRYLATE;B-Carboxyethyl acrylate;hydracrylicacid,acrylate
CBNumber:
CB8481270
분자식:
C6H8O4
포뮬러 무게:
144.13
MOL 파일:
24615-84-7.mol
MSDS 파일:
SDS

2-카르복시에틸 2-프로페노산염 속성

끓는 점
103 °C/19 mmHg (lit.)
밀도
1.214 g/mL at 25 °C (lit.)
굴절률
n20/D 1.457(lit.)
인화점
>230 °F
저장 조건
2-8°C
용해도
H2O: 용해성
산도 계수 (pKa)
3.95±0.10(Predicted)
수소이온지수(pH)
2.95 (10wt. % in H2O)
Merck
13,132
InChI
InChI=1S/C6H8O4/c1-2-6(9)10-4-3-5(7)8/h2H,1,3-4H2,(H,7,8)
InChIKey
CYUZOYPRAQASLN-UHFFFAOYSA-N
SMILES
C(OCCC(O)=O)(=O)C=C
LogP
0.600 (est)
EPA
Hydracrylic acid acrylate (24615-84-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C,Xi
위험 카페고리 넘버 34-36/37/38
안전지침서 23-26-36/37/39-45-36
유엔번호(UN No.) UN 3265 8/PG 2
WGK 독일 3
RTECS 번호 UD3325250
HS 번호 29161290
기존화학 물질 KE-29487
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
예방조치문구:
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P330+P331 삼켰다면 입을 씻어내시오. 토하게 하려 하지 마시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P363 다시 사용전 오염된 의류는 세척하시오.

2-카르복시에틸 2-프로페노산염 C화학적 특성, 용도, 생산

화학적 성질

Colorless to light yellow viscid liquid

용도

2-Carboxyethyl Acrylate is used in the preparation of DNase enzyme derivatives that act as potent preventative material of bacterial adhesion and biofilm formation in biomaterials.

주요 응용

2-Carboxyethyl acrylate can be polymerized in solution or emulsion to produce acrylic, vinyl acrylic, or styrene acrylic polymers, which are distinguished by their low glass transition temperatures (<30°C) as homopolymers. Greater elasticity, as well as improved adhesion.

제조 방법

Synthesis of 1-ethoxyethyl acrylate (EEA) and protected 2-carboxyethyl acrylate (proCEA)
EEA and proCEA were synthesized following a previously published procedure and distilled prior to use. For the synthesis of proCEA (Figure 1), phosphoric acid (109 mg, 1.11 mmol) was weighed into a dry round bottom flask in a glovebox and then taken outside the glovebox, taking care that the phosphoric acid stayed dry. 2-Carboxyethyl acrylate (80 g, 555 mmol) and ethyl vinyl ether (48 g, 666 mmol) were added and the reaction was stirred for two days at room temperature. Hydrotalcite (Mg6Al2(OH)16CO3·4H2O, ~1 g) was added, stirred for one hour and filtered off. Excess ethyl vinyl ether was removed under reduced pressure and the product was distilled under reduced pressure (80 °C, 1.3 mbar).
Synthesis of proCEA
Figure 1 Synthesis of proCEA

위험도

A severe skin irritant.

참고 문헌

[1] Emilia Pietrzak, Mikolaj Szafran, Paulina Wiecinska. “2-carboxyethyl acrylate as a new monomer preventing negative effect of oxygen inhibition in gelcasting of alumina.” Ceramics International 42 12 (2016): Pages 13682-13688.
[2] Naveed Ullah . “Coupling of carboxymethyl starch with 2-carboxyethyl acrylate: A new sorbent for the wastewater remediation of methylene blue.” Environmental Research 219 (2023): Article 115091.
[3] Amit K. Tripathi, Donald C. Sundberg*, Jenna Vossoughi. “Partitioning of 2-Carboxyethyl Acrylate between Water and Vinyl Monomer Phases Applied to Emulsion Polymerization: Comparisons with Hydroxy Acrylate and Other Vinyl Acid Functional Monomers.” Industrial Engineering Chemistry Research 54 9 (2015): 2447–2452.

2-카르복시에틸 2-프로페노산염 준비 용품 및 원자재

원자재

준비 용품


2-카르복시에틸 2-프로페노산염 공급 업체

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