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4-메톡시벤조일 클로라이드

4-메톡시벤조일 클로라이드 구조식 이미지

카스 번호:: 100-07-2

한글명:: 4-메톡시벤조일 클로라이드

동의어(한글):: 4-메톡시벤조일클로라이드

상품명:: 4-Methoxybenzoyl chloride

동의어(영문):: P-ANISOYL CHLORIDE;ANISOYL CHLORIDE;4-methoxybenzoyl;P-METHOXYBENZOYL CHLORIDE;Anisoylchlorid;P-ANSIOYHLORIDE;P-anisoylcloride;AKOS BBS-00003907;4-ANISOYL CHLORIDE;4-Anisoylchloride99%

CBNumber:: CB8726991

분자식:: C8H7ClO2

포뮬러 무게:: 170.59

MOL 파일:: 100-07-2.mol

MSDS 파일:: SDS

속성

안전

용도

공급 업체 459

4-메톡시벤조일 클로라이드 속성

녹는점: 22 °C(lit.)

끓는 점: 262-263 °C(lit.)

밀도: 1.260 g/mL at 20 °C(lit.)

증기압: 1.853Pa at 25℃

굴절률: n20/D 1.581(lit.)

인화점: 190 °F

저장 조건: 2-8°C

물리적 상태: 녹은 후에 액체

색상: 무색투명~갈색

냄새: 날카롭고 관통력이 있습니다.

수용성: 물에서 반응합니다.

감도: Moisture Sensitive

Merck: 14,673

BRN: 471918

안정성: 안정적이지만 물과 격렬하게 반응합니다. 압력 상승을 방지하기 위해 이 물질이 저장된 용기에 습기가 들어가지 않도록 하십시오. 물, 습기, 강염기, 강산화제와 혼합되지 않습니다.

InChIKey: MXMOTZIXVICDSD-UHFFFAOYSA-N

LogP: 1.52

CAS 데이터베이스: 100-07-2(CAS DataBase Reference)

NIST: 4-Methoxybenzoic acid chloride(100-07-2)

EPA: Benzoyl chloride, 4-methoxy- (100-07-2)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	C,F
위험 카페고리 넘버	14-34-67-65-63-48/20-11
안전지침서	26-36/37/39-45-62-16
유엔번호(UN No.)	UN 1729 8/PG 2
WGK 독일	1
RTECS 번호	CA0270000
F 고인화성물질	10-21
TSCA	Yes
위험 등급	8
포장분류	II
HS 번호	29163990
유해 물질 데이터	100-07-2(Hazardous Substances Data)
기존화학 물질	2012-3-5353

그림문자(GHS):

신호 어:

Danger

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	그림 문자	P- 코드
H314	피부에 심한 화상과 눈에 손상을 일으킴	피부부식성 또는 자극성물질	구분 1A, B, C	위험		P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501

예방조치문구:

P260	분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P280	보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353	피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.

NFPA 704

	1
3		0

4-메톡시벤조일 클로라이드 C화학적 특성, 용도, 생산

화학적 성질

4-methoxybenzoyl chloride appears as an amber-colored crystalline solid. Melting point 72 °F. Corrosive to metals and skin. Vapors may cause serious burns to the eyes. Decompose with water or alcohol, soluble in acetone and benzene.

Synthesis

4-Methoxybenzoyl chloride is synthesized from the direct chlorination of 4-methoxybenzoic acid by thionyl chloride.

주요 응용

4-Methoxybenzoyl chloride is one of the reactive acylating agents that can react with carboxylic acids, alcohols and amines to yield respective carboxylic anhydrides, esters and amides.
4-Methoxybenzoyl chloride can be used as radical precursor in visible-light photocatalysis to synthesize various heterocyclic compounds.
It can be used to synthesize acylphosphine ligands for the rhodium-catalyzed hydrosilylation of alkenes.
Incorporation of 4-methoxybenzoyl chloride modified indium tin oxide (ITO) as cathode for the fabrication of organic light-emitting diodes (OLEDs) has been reported.
1,3 diketones synthesized from 4-methoxybenzoyl chloride can be used in one pot synthesis of various pyrazole derivatives.
It can also be used in the total synthesis of bioactive compounds like echinoside A and salinosporamide A.

일반 설명

4-methoxybenzoyl chloride appears as an amber-colored crystalline solid. Melting point 72°F. Corrosive to metals and skin. Vapors may cause serious burns to the eyes.

공기와 물의 반응

Fumes in air. Reacts exothermically with water (including moisture in air or soil) to form hydrochloric acid and insoluble anisic acid [Merck 11th ed. 1989].

반응 프로필

ANISOYL CHLORIDE reacts exothermically with bases, including amines. Incompatible with water, strong oxidizing agents, alcohols. Sealed containers held at room temperature may explode, due to slow decomposition that builds up pressure. This situation is more dangerous with heat. May react vigorously or explosively with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

위험도

Solutions corrosive to tissue. Explosion risk when in closed containers due to pressure caused by decomposition at room temperature.

건강위험

Vapor irritates mucous membranes. Contact of liquid with eyes or skin causes severe irritation. Ingestion causes severe irritation of mouth and stomach.

화재위험

Special Hazards of Combustion Products: Irritating hydrogen chloride fumes may be formed.

화학 반응

Reactivity with Water Reacts slowly to generate hydrogen chloride (hydrochloric acid). The reaction is not hazardous; Reactivity with Common Materials: Corrodes metal slowly; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with water, rinse with sodium bicarbonate or lime solution; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Corrosive to skin, eyes, mucous membranes, and other tissue.Evolves HCl by hydrolysis. A storage hazard; can explode spontaneously at room temperature. When heated to decomposition it emits toxic fumes of Cland may explode.

저장

Stored in a closed container can cause an explosion due to the pressure caused by decomposition, should be stored at low temperature (5°C).

Structure and conformation

Anisoyl chloride, also known as methoxybenzoyl chloride), is an acyl halide, specifically an aromatic acyl chloride, and may be formed from anisic acid by replacing a hydroxyl group of the carboxylic acid with a chloride group. There are three isomers: the ortho-, meta-, and para- forms. 4-Methoxybenzoyl chloride is para- forms. Their structures differ in the arene substitution pattern—the location of the methoxy group on the ring as compared to the acyl halide.

4-메톡시벤조일 클로라이드 준비 용품 및 원자재

원자재

p-아니식애씨드 염화 티오닐

준비 용품

NOCODAZOLE Amiodarone (4-AMINO-3-NITROPHENYL)-(2-THIENYL)METHANONE Aniracetam BENZAMIDE, 4-METHOXY-N-[2-[2-(1-METHYL-2-PIPERIDINYL)ETHYL]PHENYL]- N,N'-(9,10-dihydro-4,8-dihydroxy-9,10-dioxoanthracene-1,5-diyl)bis[4-methoxybenzamide] (4-Methoxy-3-nitrophenyl)-(thiophen-2-yl)methanone ,98% 2-(4-METHOXYBENZOYL)THIOPHENE Robustaflavone 메틸(2-)3-헵타논 5-Iodoisobenzofuran-1,3-dione (2-Butyl-5-nitro-3-benzofuranyl)[4-[3-(dibutylamino)propoxy]phenyl]methanone ETHYL 4-METHOXYBENZOYLACETATE 4-hydroxy-4'-methylbenzophenone 4-Fluoro-4'-methoxybenzophenone N,N'-(9,10-dihydro-4,8-dihydroxy-9,10-dioxoanthracene-1,5-diyl)bis[4-methoxybenzamide] (αE)-β-Chloro-4'-methoxyacrylophenone 3-FORMYLPHENYL 4-METHOXYBENZOATE

4-메톡시벤조일 클로라이드 공급 업체

글로벌( 459)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5993	58
Hebei Best Biological Technology Co., Ltd		amy@chbbest.com	China	284	58
Hebei Endun Biological Technology Co. LTD	+86-8615932657220 +86-15932657220	sales05@hebeiendun.cn	China	300	58
Firsky International Trade (Wuhan) Co., Ltd	+8615387054039	admin@firsky-cn.com	China	436	58
Henan Bao Enluo International TradeCo.，LTD	+86-17331933971 +86-17331933971	deasea125996@gmail.com	China	2503	58
Anhui Ruihan Technology Co., Ltd	+8617756083858	daisy@anhuiruihan.com	China	994	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7786	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55

4-메톡시벤조일 클로라이드 관련 검색:

P-아니시딘 염화 암모늄 염화칼슘 플로로(2-)벤조일 p-톨루오일 염화물 p-클로로벤조일 클로라이드 염화나트륨 염화칼륨 염화 티오닐 M-톨우오일 염화물 염화벤조일 아니스알데히드 염화콜린 염화 폴리비닐 p-니트로벤조일클로라이드 아니소일클로라이드 4-Methoxybenzoic acid Methyl anisate