Vanadinocene Dichloride

Vanadinocene Dichloride 구조식 이미지
카스 번호:
12083-48-6
상품명:
Vanadinocene Dichloride
동의어(영문):
dichlorovanadocene;VANADOCENE CHLORIDE;VANADOCENE DICHLORIDE;VANADINOCENE DICHLORIDE;Cyclopentane Dichlorovanadium;Dicyclopentadienyldichlorovanadium;Dicyclopentadienevanadium dichloride;Dichlorobis(cyclopentadienyl)vanadium;dichlorodi-pi-cyclopentadienyl-vanadiu;dichlorodi-pi-cyclopentadienylvanadium
CBNumber:
CB8763194
분자식:
C10H10Cl2V10*
포뮬러 무게:
252.03
MOL 파일:
12083-48-6.mol

Vanadinocene Dichloride 속성

녹는점
182-194 °C (dec.)(lit.)
밀도
1,6 g/cm3
저장 조건
2-8°C
용해도
soluble in H2O, chloroform, ethanol
물리적 상태
수정 같은
Specific Gravity
1.6
색상
녹색
수용성
물과 반응
감도
Air & Moisture Sensitive
노출 한도
NIOSH: Ceiling 0.05 mg/m3
CAS 데이터베이스
12083-48-6(CAS DataBase Reference)
EPA
Vanadocene dichloride (12083-48-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T
위험 카페고리 넘버 25-36/37/38
안전지침서 26-28-36/37/39-45
유엔번호(UN No.) UN 3285 6.1/PG 3
WGK 독일 3
RTECS 번호 YW1580000
위험 등급 8
포장분류 II
HS 번호 29310099
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P405 밀봉하여 저장하시오.
NFPA 704
1
3 0

Vanadinocene Dichloride C화학적 특성, 용도, 생산

화학적 성질

dark green crystalline powder

용도

Vanadocene dichloride is used like other metallocenes as a catalyst, ultraviolet absorber, reducing agent, free radical scavenger, antiknock agent in gasoline, and as a developmental anticancer drug.

일반 설명

Pale green crystals or green powder.

공기와 물의 반응

Extremely sensitive to exposure to air. Also extremely sensitive to moisture; decomposes in water

반응 프로필

Organometallics, such as BIS(CYCLOPENTADIENYL)VANADIUM DICHLORIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Organometallics containing halogens (fluorine, chlorine, bromine, iodine) bonded to the metal typically with generate gaseous hydrohalic acids (HF, HCl, HBr, HI) with water.

화재위험

Flash point data for BIS(CYCLOPENTADIENYL)VANADIUM DICHLORIDE are not available. BIS(CYCLOPENTADIENYL)VANADIUM DICHLORIDE is probably combustible.

Pharmaceutical Applications

Vanadocene dichloride [( η5-C5H5)2VCl2, dichloro bis(η5-cyclopentadienyl)vanadium(IV)] is structurally very similar to Cp2TiCl2. It also consists of a metal centre with an oxidation number of +IV, in this case vanadium, and two Cp and two chloride ligands. Vanadocene dichloride is a 17-electron complex containing an unpaired electron and is therefore paramagnetic .
Vanadocene dichloride has found application as a catalyst for polymerisation reactions, but was also intensively studied as an anticancer agent in parallel to Cp2TiCl2 because of their structural similarities. Vanadocene dichloride has proven to be even more effective than its titanium analogue as an antiproliferative agent against both animal and human cell lines in preclinical testing. The main problems are the difficult characterisation of the active vanadium compounds and their fast hydrolysis.

Vanadinocene Dichloride 준비 용품 및 원자재

원자재

준비 용품


Vanadinocene Dichloride 공급 업체

글로벌( 70)공급 업체
공급자 전화 이메일 국가 제품 수 이점
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 47465 58
Career Henan Chemica Co
+86-0371-86658258 15093356674;
laboratory@coreychem.com China 30255 58
Xi'an MC Biotech, Co., Ltd.
029-89275612 +8618991951683
mcbio_sales@163.com China 2255 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167
1026@dideu.com China 9358 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739
info@dycnchem.com CHINA 52867 58
Alfa Chemistry
+1-5166625404
Info@alfa-chemistry.com United States 21317 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503259 +86-19930503259
cherry@crovellbio.com China 18457 58
PT CHEM GROUP LIMITED
+86-85511178 +86-85511178
peter68@ptchemgroup.com China 35453 58
GIHI CHEMICALS CO.,LIMITED
+8618058761490
info@gihichemicals.com China 49999 58

Vanadinocene Dichloride 관련 검색:

Copyright 2019 © ChemicalBook. All rights reserved