1-펜텐

1-펜텐
1-펜텐 구조식 이미지
카스 번호:
109-67-1
한글명:
1-펜텐
동의어(한글):
1-펜텐;프로필레틸린알파-n-아밀린
상품명:
1-Pentene
동의어(영문):
1-C5H10;AMYLENE;PENTENE;1-Penten;petene-1;1-PENTENE;1-AMYLENE;Pentene-1;N-AMYLENE;l-pentene
CBNumber:
CB8852784
분자식:
C5H10
포뮬러 무게:
70.13
MOL 파일:
109-67-1.mol
MSDS 파일:
SDS

1-펜텐 속성

녹는점
-165 °C
끓는 점
29.9-30.1 °C (lit.)
밀도
0.641 g/mL at 25 °C (lit.)
증기 밀도
2.4 (vs air)
증기압
10.27 psi ( 20 °C)
굴절률
n20/D 1.371(lit.)
인화점
−20 °F
저장 조건
2-8°C
용해도
알코올: 혼화성(lit.)
물리적 상태
액체
산도 계수 (pKa)
>14 (Schwarzenbach et al., 1993)
Specific Gravity
0.64
색상
무색의
냄새
휘발유처럼.
폭발한계
8.7%
Odor Threshold
0.1ppm
수용성
0.15g/L(20℃)
Merck
14,7122
BRN
1731629
Henry's Law Constant
0.406 at 25 °C (Hine and Mookerjee, 1975)
Dielectric constant
2.1(20℃)
안정성
안정적인. 강한 산화제와 호환되지 않습니다. 가연성이 높음 - 공기와 쉽게 폭발성 혼합물을 형성합니다.
LogP
2.4-2.66 at 25℃
CAS 데이터베이스
109-67-1(CAS DataBase Reference)
NIST
1-Pentene(109-67-1)
EPA
1-Pentene (109-67-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F+,Xn,F,Xi
위험 카페고리 넘버 12-52/53-65
안전지침서 61-62-16
유엔번호(UN No.) UN 1108 3/PG 1
WGK 독일 3
RTECS 번호 SB2179000
자연 발화 온도 522 °F
위험 참고 사항 Irritant/Extremely Flammable/Keep Cold
TSCA Yes
위험 등급 3
포장분류 I
HS 번호 29321900
유해 물질 데이터 109-67-1(Hazardous Substances Data)
기존화학 물질 KE-28027
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H224 극인화성 액체 및 증기 인화성 액체 구분 1 위험
H304 삼켜서 기도로 유입되면 치명적일 수 있음 흡인 유해성물질 구분 1 위험 GHS hazard pictograms
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P403+P233 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.
NFPA 704
4
1 1

1-펜텐 MSDS


1-Pentene

1-펜텐 C화학적 특성, 용도, 생산

화학적 성질

1-Pentene, C5H10, is a flammable liquid with specific gravity 0.641. It occurs in coal tar and in petroleum cracking mixtures, and polymerizes on extended periods of storage (15, 320).

물리적 성질

Clear, colorless, volatile, very flammable liquid with a disagreeable odor. An odor threshold concentration of 10 ppbv was determined by a triangular odor bag method (Nagata and Takeuchi, 1990).

용도

1-Pentene is used in the preparation of d-xylitol, l-arabinitol and hydrazones of substituted salicylaldehydes. It is also used as a blending agent for of high-octane gasoline. It reacts with p-toluenesulfinate to yield 1-(2-iodo-pentane-1-sulfonyl)-4-methyl-benzene. It is also involved in Gas Chromatography and Liquid Chromatography analysis.

생산 방법

1-Pentene is prepared from allyl bromide and ethyl magnesium bromide in ether or in dipropyl ether.

일반 설명

Colorless liquid with an odor of gasoline. Flash point -20°F(Aldrich). Insoluble in water and less dense than water. Hence floats on water. Flammable vapor is produced. Boiling point 86°F.

공기와 물의 반응

Highly flammable. Insoluble in water.

반응 프로필

1-Pentene may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. May undergo exothermic polymerization reactions in the presence of various catalysts (such as acids) or initiators.

건강위험

Acts as a simple asphyxiant or weak anesthetic in high vapor concentrations. Similar to effects caused by gasoline vapors.

화재위험

Behavior in Fire: Containers may explode in fire.

화학 반응

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

잠재적 노출

Workers in petroleum refineries and petrochemical plants.

환경귀착

Biological. Biooxidation of 1-pentene may occur yielding 4-penten-1-ol, which may oxidize to give 4-pentenoic acid (Dugan, 1972). Washed cell suspensions of bacteria belonging to the genera Mycobacterium, Nocardia, Xanthobacter, and Pseudomonas and growing on selected alkenes metabolized 1-pentene to 1,2-epoxypentane. Mycobacterium sp., growing on ethene, hydrolyzed 1,2-epoxypropane to 1,2-propanediol (Van Ginkel et al., 1987).
Photolytic. The following rate constants were reported for the reaction of 1-pentene and OH radicals in the atmosphere: 1.8 x 10-13 cm3/molecule?sec at 300 K (Hendry and Kenley, 1979); 3.14 x 10-11 cm3/molecule?sec (Atkinson, 1990). Atkinson (1990) also reported a photooxidation rate constant of 1.10 x 10-17 cm3/molecule?sec for the reaction of 1-pentene and ozone.
Chemical/Physical. Complete combustion in air yields carbon dioxide and water.

운송 방법

UN1108 1-Pentene, Hazard Class: 3; Labels: 3-Flammable liquid

비 호환성

Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Excessive heat may cause polymerization. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, heat. Incompatible with strong reducing agents such as hydrides; oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

폐기물 처리

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

1-펜텐 준비 용품 및 원자재

원자재

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