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3-아미노페놀

3-아미노페놀
3-아미노페놀 구조식 이미지
카스 번호:
591-27-5
한글명:
3-아미노페놀
동의어(한글):
3-아미노-1-히드록시벤젠;3-아미노페놀;M-아미노페놀
상품명:
3-Aminophenol
동의어(영문):
furroeg;nakoteg;renaleg;ursoleg;Furro EG;Nako TEG;Renal EG;Ursol EG;98.5%(T);c.i.76545
CBNumber:
CB8853903
분자식:
C6H7NO
포뮬러 무게:
109.13
MOL 파일:
591-27-5.mol

3-아미노페놀 속성

녹는점
120-124 °C (lit.)
끓는 점
164 °C/11 mmHg (lit.)
밀도
0.99
굴절률
1.5444 (estimate)
인화점
155 °C
저장 조건
2-8°C
용해도
26g/l
물리적 상태
Crystalline Powder
산도 계수 (pKa)
4.37, 9.82(at 20℃)
색상 색인 번호
76545
색상
White to pinkish or light gray
수소이온지수(pH)
6.8 (10g/l, H2O, 20℃)
냄새
odorless
수용성
35 g/L (20 ºC)
Merck
14,460
BRN
636059
안정성
Stable. Combustible. Incompatible with strong oxidizing agents, bases, mineral acids. May be light or air-sensitive.
CAS 데이터베이스
591-27-5(CAS DataBase Reference)
NIST
Phenol, 3-amino-(591-27-5)
EPA
3-Aminophenol (591-27-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N
위험 카페고리 넘버 20/22-51/53
안전지침서 28-61-28A
유엔번호(UN No.) UN 2512 6.1/PG 3
WGK 독일 2
RTECS 번호 SJ4900000
TSCA Yes
위험 등급 6.1
포장분류 III
HS 번호 29222900
유해 물질 데이터 591-27-5(Hazardous Substances Data)
독성 LD50 i.p. in mice: 4.5 mg/20g (Koelzer, Giesen)
기존화학 물질 KE-01528
그림문자(GHS):
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 P264, P270, P301+P312, P330, P501
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 P264, P280, P305+P351+P338,P337+P313P
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 P261, P271, P304+P340, P312
H371 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음(노출되어도 특정 표적장기 독성을 일으키지 않는다는 결정적인 노출경로가 있다면 노출경로를 기재) 특정 표적장기 독성 - 2회 노출 구분 2 경고 P260, P264, P270, P309+P311, P405,P501
H373 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음 특정 표적장기 독성 - 반복 노출 구분 2 경고 P260, P314, P501
H401 수생생물에 유독함 수생 환경유해성 물질 - 급성 구분 2 P273, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 P273, P391, P501
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P391 누출물을 모으시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P405 밀봉하여 저장하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
0
2 0

3-아미노페놀 MSDS


3-Aminophenol

3-아미노페놀 C화학적 특성, 용도, 생산

화학적 성질

Light grey crystal powder

화학적 성질

o-Aminophenol appears as colorless needles or as white crystalline substance turning tan to brown on exposure to air.

용도

m-Aminophenol (MAP) is an important starting material for dyes, including a variety of leuco (or latent) dyes used in imaging technology, optical bleaches and fluorescent agents, drugs, agricultural chemicals; and high-performance polymers. Although the synthesis of m-aminophenol(s) by the reaction of resorcinol with ammonia or (di)alkylarnines has been known for about 100 years,the preferred manufacturing process had been for many years a route involving the sulfonation of nitrobenzene to m-nitrobenzenesulfonic acid, the reduction of the nitro group to give m-aminobenzenesulfonic acid, followed by the caustic fusion of sodium m-aminobenzenesulfonate to yield sodium m-aminophenolate. The m-aminophenol was isolated/purified by neutralization, filtration, and recrystallization; the overall yield of m-aminophenol from nitrobenzene was estimated by SRI International to be 58%. (Doubtless, process improvements were made by the producers using this process.) The nitrobenzene/sulfonationlreductionlcaustic fusion route is still being used commercially, notably by ACNA in Italy, the largest producer of MAP, as well as a few smaller manufacturers. Sumitomo Chemical Co. used this process as well into the early 1980s and had licensed their knowhow to Hindustani Organic Chemicals, Ltd. of India which started up a plant on this basis with a capacity for MAP of 1.5 mill. lb /yr in 1970.The output of the Indian plant was said to be devoted to making sodium p-aminosalycilate (PAS), a tuberculostatic agent.

용도

coupler for hair dyes; dye intermediate; in the manufacturing of 4-aminosalicylic acid

용도

Dye intermediate, manufacture of p-aminosalicylic acid.

정의

ChEBI: An aminophenol that is one of three amino derivatives of phenol which has the single amino substituent located meta to the phenolic -OH group.

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 1479, 1984 DOI: 10.1016/S0040-4039(01)80191-X

일반 설명

White crystals or off-white flakes.

공기와 물의 반응

3-Aminophenol may be sensitive to prolonged exposure to air and light. Slightly soluble in water.

반응 프로필

3-Aminophenol may react with strong oxidizers and mineral acids or bases.

위험도

Toxic by ingestion.

화재위험

Flash point data for 3-Aminophenol are not available. 3-Aminophenol is probably combustible.

Safety Profile

Poison by ingestion, subcutaneous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. A skin and eye irritant. When heated to decomposition it emits toxic fumes of NOx,.

잠재적 노출

Workers may be exposed to oAminophenol during its use as a chemical intermediate; in the manufacture of azo and sulfur dyes; and in the photographic industry. There is potential for consumer exposure to o-Aminophenol because of its use in dyeing hair, fur, and leather. The compound is a constituent of 75 registered cosmetic products suggesting the potential for widespread consumer exposure. p-Aminophenol is used mainly as a dye, dye intermediate and as a photographic developer; and in small quantities in analgesic drug preparation. Consumer exposure to p-aminophenol may occur from use as a hairdye or as a component in cosmetic preparations. mAminophenol is used mainly as a dye intermediate

운송 방법

UN2512 Aminophenols (o-; m-; p-), Hazard Class: 6.1; Labels: 6.1-Poisonous materials

Purification Methods

Crystallise it from hot water or toluene. [Beilstein 13 IV 952.]

비 호환성

These phenol/cresol materials can react with oxidizers; reaction may be violent. Incompatible with strong reducing substances such as alkali metals, hydrides, nitrides, and sulfides. Flammable gas (H2) may be generated, and the heat of the reaction may cause the gas to ignite and explode. Heat may be generated by the acidbase reaction with bases; such heating may initiate polymerization of the organic compound. Reacts with boranes, alkalies, aliphatic amines, amides, nitric acid, sulfuric acid. Phenols are sulfonated very readily (e.g., by concentrated sulfuric acid at room temperature). These reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid and can explode when heated. Many phenols form metal salts that may be detonated by mild shock.

폐기물 처리

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

3-아미노페놀 준비 용품 및 원자재

원자재

준비 용품


3-아미노페놀 공급 업체

글로벌( 420)공급 업체
공급자 전화 팩스 이메일 국가 제품 수 이점
CD Chemical Group Limited
+8613651442114
0086-13651442114 info@codchem.com China 20384 58
Springchem New Material Technology Co.,Limited
+8613917661608 +86-021-62885108
info@spring-chem.com China 2064 57
Capot Chemical Co.,Ltd.
+86(0)13336195806 +86-571-85586718
+86-571-85864795 sales@capotchem.com China 20012 60
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 20918 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22607 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679
86-0551-65418697 info@tnjchem.com China 3000 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29954 58
NINGBO INNO PHARMCHEM CO., LTD.
13867897135
sales@nbinno.com CHINA 925 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Jinan Finer Chemical Co., Ltd
+8615508631887 +86-531-88989536
+86-531-88989539 sales@finerchem.com CHINA 1706 58

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