페난트렌 C화학적 특성, 용도, 생산
개요
무색의 판상 결정인데, 벤젠·에테르에는 녹지만 알코올에는 잘 녹지 않는다.
크롬산으로 산화하면 페난트렌퀴논을 생성한다.염료·의약품의 합성원료로서 중요하다.
용도
1. 페난트렌은 phenanthrenequinone를 생성할 수 있습니다,
2. 제지에서는, 펄프의 antifogging 대리인입니다;
3. 약에서는, 그것은 알카로이드를 생성할 수 있습니다;
4. 염료 기업, 그것에서는 2 아미노 phenanthrenequinone, benzanthrone 및 황 큰 통 염료에서 사용된 b3e는 할 수 있습니다;
5. 페난트렌은 제트기의 연료의 생산에서 이용될 수 있습니다.
개요
Phenanthrene is a polycyclic aromatic hydrocarbon (PAH)
composed of three fused benzene rings. The name phenanthrene
is a composite of phenyl and anthracene. In its pure
form, it is found in cigarette smoke and is a known irritant,
photosensitizing skin to light. Phenanthrene appears as a white
powder having blue fluorescence.
화학적 성질
Phenanthrene is a white crystalline substance. Weak aromatic odor. Polycyclic aromatic hydrocarbons (PAHs) are compounds containing multiple benzene rings and are also called polynuclear aromatic hydrocarbons.
물리적 성질
Colorless, monoclinic crystals with a faint, aromatic odor
용도
Phenanthrene is a polycyclic aromatic hydrocarbons, an environmental pollutant.
정의
ChEBI: A polycyclic aromatic hydrocarbon composed of three fused benzene rings which takes its name from the two terms 'phenyl' and 'anthracene.'
생산 방법
Phenanthrene occurs in coal tar and can be isolated from
several types of crude petroleum.
일반 설명
Colorless monoclinic crystals with a faint aromatic odor. Solutions exhibit a blue fluorescence.
공기와 물의 반응
Insoluble in water.
반응 프로필
Phenanthrene may react with oxidizing materials .
건강위험
The acute oral toxicity of phenanthrene is low.It is more toxic than anthracene. An oral LD50value in mice is reported at 700 mg/kg. It maycause tumor in skin at the site of application.The evidence of carcinogenicity in animals,however, is inadequate.
화재위험
Phenanthrene is combustible.
Safety Profile
Poison by intravenous route. Moderately toxic by ingestion. Mutation data reported. A human skin photosensitizer. Questionable carcinogen with experimental neoplastigenic and tumorigenic data by skin contact. Combustible when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes
잠재적 노출
Dust may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
Carcinogenicity
Phenanthrene is ineffective as an
initiator. It is not classifiable as to human carcinogenicity—
class 3 by IARC and class D by IRIS, based on
no human data and inadequate data from a single gavage
study in rats and skin painting and injection studies in
mice.
운송 방법
UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
폐기물 처리
Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
페난트렌 준비 용품 및 원자재
원자재
준비 용품
사이클로헥세인
Ziegler catalyst、Phillips catalyst
페난트렌퀴논
HALOFANTRINE
디펜산
벤젠
안트라센
phanquone
9-Bromophenanthrene
1,2,3,4,4a,9,10,10a-octahydrophenanthrene
1,2,3,4,5,6,7,8-OCTAHYDROPHENANTHRENE
4,4'-Dinitrodiphenic acid
