니켈로센
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니켈로센 속성
- 녹는점
- 171-173 °C(lit.)
- 저장 조건
- 2-8°C
- 수용성
- 물에 불용성
- 물리적 상태
- 수정 같은
- 색상
- 짙은 녹색
- 감도
- Air & Moisture Sensitive
- CAS 데이터베이스
- 1271-28-9(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | F,T | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 49-11-22-43 | ||
| 안전지침서 | 53-36/37/39-45 | ||
| 유엔번호(UN No.) | UN 1325 4.1/PG 2 | ||
| WGK 독일 | 3 | ||
| RTECS 번호 | QR6500000 | ||
| F 고인화성물질 | 10-23 | ||
| TSCA | Yes | ||
| 위험 등급 | 4.2 | ||
| 포장분류 | I | ||
| HS 번호 | 29319090 | ||
| 독성 | mouse,LD50,intraperitoneal,86mg/kg (86mg/kg),Proceedings of the Western Pharmacology Society. Vol. 11, Pg. 39, 1968. |
니켈로센 C화학적 특성, 용도, 생산
화학적 성질
Nickelocene is a solid crystalline substance of dark green color, insoluble in water or carbon tetrachloride, slightly soluble in alcohol and liquid ammonia, and readily soluble in nonpolar organic solvents.용도
Nickelocene is obtained through reacting nickel halides with sodium cyclopentadienide. It is used as a catalyst or as a complexing agent.일반 설명
Dark liquid in an 8-10% solution in toluene. Insoluble in water.공기와 물의 반응
Highly flammable. The neat material is sensitive to air. . Insoluble in water.반응 프로필
Organometallics, such as NICKELOCENE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.위험도
Toxic by inhalation and skin contact, a carcinogen (OSHA).건강위험
ACUTE/CHRONIC HAZARDS: NICKELOCENE can be absorbed through the skin.화재위험
NICKELOCENE is flammable.Safety Profile
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal and intramuscular routes. Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also NICKEL COMPOUNDS.Purification Methods
Dissolve the complex in Et2O, filter and evaporate in a vacuum. Purify it rapidly by recrystallisation from pet ether using a solid CO2/Me2CO bath, m 171-173o(in an evacuated tube). Also purify it by vacuum sublimation. [Wilkinson et al. J Am Chem Soc 76 1970 1954, Beilstein 16 IV 1831.]니켈로센 준비 용품 및 원자재
원자재
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
염화 니켈
암모니아(가스)
시클로펜타디에닐화나트륨
Nickel dichloride
시클로펜타디엔
염화니켈 헥사히드레이트
준비 용품
니켈로센 공급 업체
글로벌( 169)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Tianjin Zhongxin Chemtech Co., Ltd. | +86-022-66880623 +8618622897568 |
sales@tjzxchem.com | China | 559 | 58 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 |
sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 47465 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 |
contact@fuxinpharm.com | China | 10297 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 |
sale04@alfachem.cn | China | 12468 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 15093356674; |
laboratory@coreychem.com | China | 30255 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 |
sales@tnjchem.com | China | 34572 | 58 |
| Hunan russell chemicals technology co ltd | 731-88557738 +8613739093081 |
sales01@russellchem.com | CHINA | 291 | 58 |
| Xi'an MC Biotech, Co., Ltd. | 029-89275612 +8618991951683 |
mcbio_sales@163.com | China | 2255 | 58 |
니켈로센 관련 검색:
비스(시클로펜탄다에닐)마그네슘(II) 디에틸아연 디시클로펜타디에닐 철 니켈로센
MOLECULAR SIEVES
Azobenzene
Ferrous chloride
PETROLEUM ETHER
Boron nitride
BIS(CYCLOPENTADIENYL)RUTHENIUM
BIS(CYCLOPENTADIENYL)MANGANESE
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
BIS(METHYLCYCLOPENTADIENYL)NICKEL
BIS(TETRAMETHYLCYCLOPENTADIENYL)NICKEL
BIS(PENTAMETHYLCYCLOPENTADIENYL)NICKEL
BIS(ETHYLCYCLOPENTADIENYL)NICKEL
BIS(I-PROPYLCYCLOPENTADIENYL)NICKEL
CYCLOPENTADIENYL NICKEL CARBONYL DIMER