2-메틸시클로펜타디에닐 망간트리카르보닐
|
|
2-메틸시클로펜타디에닐 망간트리카르보닐 속성
- 녹는점
- -1 °C (lit.)
- 끓는 점
- 232-233 °C (lit.)
- 밀도
- 1.38 g/mL at 25 °C (lit.)
- 증기 밀도
- >1 (vs air)
- 증기압
- 0.05 mm Hg ( 20 °C)
- 굴절률
- n
20/D 1.584(lit.)
- 인화점
- 205 °F
- 저장 조건
- Poison room
- 물리적 상태
- 액체
- 색상
- 노란색
- Specific Gravity
- 1.388
- 수용성
- 물에 불용성. 탄화수소 용매, 알코올, 에테르, 아세톤에 용해됨
- 감도
- Air Sensitive
- Merck
- 14,6223
- 노출 한도
- ACGIH: TWA 0.2 mg/m3 (Skin)
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 0.2 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
- 안정성
- 안정적인. 강한 산화제와 호환되지 않습니다.
- InChIKey
- LYHJNAIHGFWRKM-UHFFFAOYSA-N
- LogP
- 3.4 at 26℃
- CAS 데이터베이스
- 12108-13-3(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | T,N,T+ | ||
---|---|---|---|
위험 카페고리 넘버 | 23/24/25-40-50/53-48/23-38-26-24/25 | ||
안전지침서 | 23-26-36/37/39-45-61-60-36/37-28 | ||
유엔번호(UN No.) | UN 3281 6.1/PG 2 | ||
WGK 독일 | 3 | ||
RTECS 번호 | OP1450000 | ||
TSCA | Yes | ||
위험 등급 | 6.1 | ||
포장분류 | II | ||
유해 물질 데이터 | 12108-13-3(Hazardous Substances Data) | ||
독성 | LD50 orally in mice, guinea pig, rabbit: 352; 905; 95 mg/kg; orally in male, female rats: 175 ±33; 89 ±14; LC50 inhalation in rat: 0.22 mg/l (Stara) | ||
기존화학 물질 | KE-34053 |
2-메틸시클로펜타디에닐 망간트리카르보닐 C화학적 특성, 용도, 생산
화학적 성질
An orange liquid with a pleasant odor. Slightly soluble in water and denser than water. May be toxic by inhalation, ingestion and/or skin absorption. Faintly pleasant, herb-like odor.용도
Methylcyclopentadienyl manganese tricarbonyl is used for doping of ZnSe nanocrystalsIt can also be used as a reactant for:
Aldol addition reactions
Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units
Molecular fragmentation using shaped femtosecond laser pulses
Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE)
일반 설명
Methylcyclopentadienyl manganese tricarbonyl (hereinafter "MMT") is an antiknock agent for gasoline discovered in the fifties and sold commercially by Ethyl Corporation. It can be made by the reaction of carbon monoxide with bis(methylcyclopentadienyl) manganese referred to as "carbonylation".공기와 물의 반응
Slightly soluble in water.반응 프로필
METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL decomposes when exposed to light. METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL is stable in water.위험도
Toxic by ingestion, inhalation, and skinabsorption. Central nervous system impairment;lung, liver and kidney damage.건강위험
In concentrated form METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL is highly toxic by all routes of exposure. Approximately 5-15 ml, when spilled on the hand and wrist of a worker, produced toxic effects within 3-5 minutes.화재위험
When heated to decomposition, METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL emits toxic fumes of carbon monoxide. Hazardous polymerization may not occur.Safety Profile
Poison by ingestion, inhalation, skin contact, intravenous, and intraperitoneal routes. A slimn irritant. When heated to decomposition it emits toxic fumes of CO. See also MANGANESE COMPOUNDS and CARBONYLS.잠재적 노출
MMT is used as an octane improver in unleaded gasoline, other distillate fuels, and fuel oils; as a smoke abater in fuels.운송 방법
UN3281 Metal carbonyls, liquid n.o.s. Hazard class 6.1. Technical name required, Potential Inhalation Hazard (Special Provision 5).비 호환성
Light causes decomposition. May be air-reactive. A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, halogens.폐기물 처리
Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number N450, must conform to USEPA regulations for storage, transportation, treatment, and disposal of waste. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Dispose of contents and container to an approved waste disposal plant. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. All federal, state, and local environmental regulations must be observed. Do not discharge into drains or sewers.2-메틸시클로펜타디에닐 망간트리카르보닐 준비 용품 및 원자재
원자재
준비 용품
2-메틸시클로펜타디에닐 망간트리카르보닐 공급 업체
글로벌( 172)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
SIMAGCHEM CORP | +86-13806087780 |
sale@simagchem.com | China | 17367 | 58 |
Tianjin Zhongxin Chemtech Co., Ltd. | +86-022-66880623 +8618622897568 |
sales@tjzxchem.com | China | 559 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |
Jinan Qinmu Fine Chemical Co.,Ltd. | +8618660799346 |
sales@qinmuchem.com | China | 1009 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8823 | 58 |
Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 |
daisy@crovellbio.com | China | 5964 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503259 +86-19930503259 |
cherry@crovellbio.com | China | 18457 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 |
peter@yan-xi.com | China | 5993 | 58 |
airuikechemical co., ltd. | +undefined86-15315557071 |
sales02@airuikechemical.com | China | 994 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12456 | 58 |