2-메틸시클로펜타디에닐 망간트리카르보닐

2-메틸시클로펜타디에닐 망간트리카르보닐
2-메틸시클로펜타디에닐 망간트리카르보닐 구조식 이미지
카스 번호:
12108-13-3
한글명:
2-메틸시클로펜타디에닐 망간트리카르보닐
동의어(한글):
2-메틸시클로펜타디에닐망간트리카르보닐;2-메틸시클로펜타디에닐망간트리카르보닐;메틸사이클로펜타다이엔일 망간 트라이카보닐
상품명:
Methylcyclopentadienyl manganese tricarbonyl
동의어(영문):
carbon monoxide,manganese,5-methylcyclopenta-1,3-diene;CI-2;MCMT;Ak-33x;mmt[qr];ci-2[qr];EthylMMT;NSC22316;Hitec3000;ak-33x[qr]
CBNumber:
CB9231289
분자식:
C9H7MnO35*
포뮬러 무게:
218.09
MOL 파일:
12108-13-3.mol

2-메틸시클로펜타디에닐 망간트리카르보닐 속성

녹는점
-1 °C (lit.)
끓는 점
232-233 °C (lit.)
밀도
1.38 g/mL at 25 °C (lit.)
증기 밀도
>1 (vs air)
증기압
0.05 mm Hg ( 20 °C)
굴절률
n20/D 1.584(lit.)
인화점
205 °F
저장 조건
Poison room
물리적 상태
액체
색상
노란색
Specific Gravity
1.388
수용성
물에 불용성. 탄화수소 용매, 알코올, 에테르, 아세톤에 용해됨
감도
Air Sensitive
Merck
14,6223
노출 한도
ACGIH: TWA 0.2 mg/m3 (Skin)
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 0.2 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
안정성
안정적인. 강한 산화제와 호환되지 않습니다.
InChIKey
LYHJNAIHGFWRKM-UHFFFAOYSA-N
LogP
3.4 at 26℃
CAS 데이터베이스
12108-13-3(CAS DataBase Reference)
EPA
Methylcyclopentadienyl manganese tricarbonyl (12108-13-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N,T+
위험 카페고리 넘버 23/24/25-40-50/53-48/23-38-26-24/25
안전지침서 23-26-36/37/39-45-61-60-36/37-28
유엔번호(UN No.) UN 3281 6.1/PG 2
WGK 독일 3
RTECS 번호 OP1450000
TSCA Yes
위험 등급 6.1
포장분류 II
유해 물질 데이터 12108-13-3(Hazardous Substances Data)
독성 LD50 orally in mice, guinea pig, rabbit: 352; 905; 95 mg/kg; orally in male, female rats: 175 ±33; 89 ±14; LC50 inhalation in rat: 0.22 mg/l (Stara)
기존화학 물질 KE-34053
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H372 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킴 특정 표적장기 독성 - 반복 노출 구분 1 위험 GHS hazard pictograms P260, P264, P270, P314, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P262 눈, 피부, 의복에 묻지 않도록 하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
NFPA 704
0
4 0

2-메틸시클로펜타디에닐 망간트리카르보닐 C화학적 특성, 용도, 생산

화학적 성질

An orange liquid with a pleasant odor. Slightly soluble in water and denser than water. May be toxic by inhalation, ingestion and/or skin absorption. Faintly pleasant, herb-like odor.

용도

Methylcyclopentadienyl manganese tricarbonyl is used for doping of ZnSe nanocrystals
It can also be used as a reactant for:
Aldol addition reactions
Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units
Molecular fragmentation using shaped femtosecond laser pulses
Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE)

일반 설명

Methylcyclopentadienyl manganese tricarbonyl (hereinafter "MMT") is an antiknock agent for gasoline discovered in the fifties and sold commercially by Ethyl Corporation. It can be made by the reaction of carbon monoxide with bis(methylcyclopentadienyl) manganese referred to as "carbonylation". 

공기와 물의 반응

Slightly soluble in water.

반응 프로필

METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL decomposes when exposed to light. METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL is stable in water.

위험도

Toxic by ingestion, inhalation, and skinabsorption. Central nervous system impairment;lung, liver and kidney damage.

건강위험

In concentrated form METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL is highly toxic by all routes of exposure. Approximately 5-15 ml, when spilled on the hand and wrist of a worker, produced toxic effects within 3-5 minutes.

화재위험

When heated to decomposition, METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL emits toxic fumes of carbon monoxide. Hazardous polymerization may not occur.

Safety Profile

Poison by ingestion, inhalation, skin contact, intravenous, and intraperitoneal routes. A slimn irritant. When heated to decomposition it emits toxic fumes of CO. See also MANGANESE COMPOUNDS and CARBONYLS.

잠재적 노출

MMT is used as an octane improver in unleaded gasoline, other distillate fuels, and fuel oils; as a smoke abater in fuels.

운송 방법

UN3281 Metal carbonyls, liquid n.o.s. Hazard class 6.1. Technical name required, Potential Inhalation Hazard (Special Provision 5).

비 호환성

Light causes decomposition. May be air-reactive. A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, halogens.

폐기물 처리

Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number N450, must conform to USEPA regulations for storage, transportation, treatment, and disposal of waste. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Dispose of contents and container to an approved waste disposal plant. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. All federal, state, and local environmental regulations must be observed. Do not discharge into drains or sewers.

2-메틸시클로펜타디에닐 망간트리카르보닐 준비 용품 및 원자재

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