나이트릴로트라이아세트산

나이트릴로트라이아세트산
나이트릴로트라이아세트산 구조식 이미지
카스 번호:
139-13-9
한글명:
나이트릴로트라이아세트산
동의어(한글):
나이트릴로트라이아세트산;나이트릴로트라이아세트산(나이트릴로트리아세트산);니트릴로트리아세트산;아미노트리아세트산
상품명:
Nitrilotriacetic acid
동의어(영문):
NTA;TRIGLYCINE;NITRILOTRIACETATE;NTA acid;TRILON A;Nitrilotriacetic;NITRILOACETIC ACID;2,2',2''-Nitrilotriacetic acid;nci-c02766;NITRILOACETATE
CBNumber:
CB9241989
분자식:
C6H9NO6
포뮬러 무게:
191.14
MOL 파일:
139-13-9.mol
MSDS 파일:
SDS

나이트릴로트라이아세트산 속성

녹는점
245 °C (dec.)(lit.)
끓는 점
326.86°C (rough estimate)
밀도
1.5784 (rough estimate)
증기압
0-0Pa at 20-25℃
굴절률
1.4860 (estimate)
인화점
100 °C
저장 조건
2-8°C
용해도
0.1 M NaOH: 0.1 M @20°C, 투명, 무색
물리적 상태
가루
산도 계수 (pKa)
3.03, 3.07, 10.70(at 20℃)
색상
하얀색
수용성
불용성. 23&C에서 <0.01g/100mL
최대 파장(λmax)
λ: 260 nm Amax: 1.5
λ: 280 nm Amax: 0.05
Merck
14,6579
BRN
1710776
LogP
-3.81 at 25℃
CAS 데이터베이스
139-13-9(CAS DataBase Reference)
NIST
Nitrilotriacetic acid(139-13-9)
IARC
2B (Vol. 48, 73) 1999
EPA
Nitrilotriacetic acid (139-13-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,T
위험 카페고리 넘버 22-36-40-36/37/38-45-20/21/22
안전지침서 26-36/37-45-36/37/39-53
유엔번호(UN No.) 2811
WGK 독일 2
RTECS 번호 AJ0175000
F 고인화성물질 21
TSCA Yes
위험 등급 8
포장분류 II
HS 번호 29224995
유해 물질 데이터 139-13-9(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 1100 mg/kg
기존화학 물질 KE-25936
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
NFPA 704
0
2 0

나이트릴로트라이아세트산 MSDS


Nitrilotriacetic acid

나이트릴로트라이아세트산 C화학적 특성, 용도, 생산

화학적 성질

Nitrilotriacetic acid, also known as NTA, is a white crystalline powder. It can dissolve in ammonia and alkali solutions while being slightly soluble in hot water. However, it is insoluble in water and most organic solvents. NTA can form mono-, di-, and tribasic salts, all of which are soluble in water. Combustible. 70% biodegradable.

제조 방법

The synthesis of nitrilotriacetic acid involves the following steps:
Chloroacetic acid is reacted with sodium hydroxide to produce sodium chloroacetate.
Sodium chloroacetate then reacts with ammonium chloride to form sodium aminotriacetate.
The resulting sodium aminotriacetate is acidified to obtain nitrilotriacetic acid.

일반 설명

Odorless white solid. Sinks in and mixes with water.

공기와 물의 반응

Water Insoluble.

반응 프로필

Nitrilotriacetic acid is incompatible with strong oxidizers, aluminum, copper, copper alloy and nickel. Nitrilotriacetic acid is also incompatible with strong bases.

위험도

Possible carcinogen.

건강위험

Toxicity and health hazard of these compounds are low. Contact with eyes causes irritation.

화재위험

Flash point data for Nitrilotriacetic acid are not available; however, Nitrilotriacetic acid is probably combustible.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx,.

잠재적 노출

Nitrilotriacetic acid (NTA) was used as a phosphate replacement in laundry detergents in the late 1960s. In 1971, the use of NTA was discontinued. The possibility of resumed use arose in 1980. NTA is now used in laundry detergents in states where phosphates are banned. NTA is also used as a boiler feed-water additive at a maximum use level of 5 ppm of trisodium salt. Currently, the remaining nondetergent uses of NTA are for water treatment, textile treatment; metal plating and cleaning; and pulp and paper processing.

Carcinogenicity

Nitrilotriacetic acid is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

운송 방법

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Purification Methods

Crystallise it from water and dry it at 110o. [Beilstein 4 IV 2441.]

비 호환성

Dust may form explosive mixture with air. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur). Attacks aluminum, copper, copper alloy and nickel.

폐기물 처리

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

나이트릴로트라이아세트산 준비 용품 및 원자재

원자재

준비 용품


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