트리사이클로헥실포스핀
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트리사이클로헥실포스핀 속성
- 녹는점
- 81-83 °C (lit.)
- 끓는 점
- 383.4±9.0 °C | Condition: Press: 760 Torr
- 밀도
- 0.909 g/mL at 25 °C
- 인화점
- 48 °F
- 저장 조건
- Inert atmosphere,2-8°C
- 용해도
- Chloroform (Slightly), DMSO (Slightly, Heated, Sonicaetd), Ethyl Acetate (Slightly)
- 물리적 상태
- 액체
- Specific Gravity
- 0.9
- 색상
- 흰색에서 황백색까지
- 수용성
- 대부분의 유기용매에 용해됩니다. 물에 불용성.
- 감도
- Air Sensitive
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- BRN
- 957171
- 안정성
- 공기 민감성, 수분 민감성
- InChIKey
- WLPUWLXVBWGYMZ-UHFFFAOYSA-N
- CAS 데이터베이스
- 2622-14-2(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | Xi,Xn,F | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 36/37/38-22-37/38-36-19-11-67-65-63-48/20-40 | ||
| 안전지침서 | 26-36/37-62-37/39-36-33-29-16 | ||
| 유엔번호(UN No.) | UN 2056 3/PG 2 | ||
| WGK 독일 | 3 | ||
| TSCA | Yes | ||
| 위험 등급 | 3 | ||
| 포장분류 | III | ||
| HS 번호 | 29319090 | ||
| 유해화학물질 필터링 | 2019-1-921(신규화학물질) | ||
| 함량 및 규제정보 | 물질구분: 유독물질; 혼합물(제품)함량정보: 트리사이클로헥실포스핀 및 이를 25% 이상 함유한 혼합물 |
트리사이클로헥실포스핀 C화학적 특성, 용도, 생산
화학적 성질
clear colorless to pale yellow solution용도
- Tricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry.
- Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides.
- suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides.
- This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.
- As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations.
- Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions.
- Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.
Purification Methods
It recrystallises from EtOH [Boert et al. J Am Chem Soc 109 7781 1987]. [Beilstein 16 IV 947.]트리사이클로헥실포스핀 준비 용품 및 원자재
원자재
브로모사이클로헥산
삼염화 인
디에틸에테르
염화 암모늄
마그네슘
Tricyclohexylphosphine Carbon Disulfide
TRICYCLOHEXYLPHOSPHINE SULFIDE
TRICYCLOHEXYLPHOSPHINE OXIDE
클로로시클로헥산
사이클로헥산올
디시 클로 헥실 클로로 포스 핀
준비 용품
Bis(tricyclohexylphosphine)palladium(II) Dichloride
Diphosphine, tetracyclohexyl-
Dicyclohexylphosphine oxide
METHYL 2-CHLORO-3-NITROBENZOATE
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct
트리사이클로헥실포스핀 공급 업체
글로벌( 449)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 |
sales@runvmat.com | China | 402 | 58 |
| Shanghai Bojing Chemical Co.,Ltd. | +86-86-02137122233 +8613795318958 |
bj1@bj-chem.com | China | 298 | 55 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 |
info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9348 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32480 | 60 |
| AB PharmaTech,LLC | 323-480-4688 |
United States | 989 | 55 | |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
트리사이클로헥실포스핀 관련 검색:
트리 시클로 헥실 포스 포늄 테트라 플루오로 보레이트 포스핀(기체) 트리사이클로헥실포스핀
TRICYCLOHEXYLPHOSPHINE OXIDE
DICYCLOHEXYLPHOSPHINE
TRICYCLOPENTYLPHOSPHINE
TRIHEXYLPHOSPHINE
O-(2,2,2-Trifluoroethyl)hydroxylamine hydrochloride
Trimethylsilyl 2-(fluorosulfonyl)difluoroacetate
(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)rutheniuM(IV) Dichloride
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
TRICYCLOHEXYL-D33-PHOSPHINE CARBON DISULFIDE COMPLEX
Bis(tricyclohexylphosphine)palladium(0)
Bis(tricyclohexylphosphine)palladium(II) Dichloride
BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE
GRUBBS CATALYST 2ND GENERATION
Dichlorobis(tricyclohexylphosphine) palladium
CYCLOHEXYLPHOSPHINE