D-GALACTURONIC ACID

D-GALACTURONIC ACID 구조식 이미지
카스 번호:
685-73-4
상품명:
D-GALACTURONIC ACID
동의어(영문):
D-GALACTURONATE;ALPHA-D-GALACTURONIC ACID;D-galactopyranuronic acid;galaturonate;GALACTURONATE;D-galaturonate;D-GALACTURONIC ACID;A-D-GALACTURONIC ACID;GALACTURONIC ACID, D-;α-D-Galactouronic acid
CBNumber:
CB9351325
분자식:
C6H10O7
포뮬러 무게:
194.14
MOL 파일:
685-73-4.mol

D-GALACTURONIC ACID 속성

녹는점
166°C
끓는 점
250.56°C (rough estimate)
밀도
1.4301 (rough estimate)
굴절률
1.4455 (estimate)
산도 계수 (pKa)
3.30±0.35(Predicted)
LogP
-1.490 (est)
EPA
D-Galacturonic acid (685-73-4)

안전

WGK 독일 3

D-GALACTURONIC ACID C화학적 특성, 용도, 생산

개요

D-Galacturonic acid is a sugar acid, an oxidized form of Dgalactose. It is the main component of pectin, in which it exists as the polymer polygalacturonic acid. It has an aldehyde group at C1 and a carboxylic acid group at C6. Other oxidized forms of D-galactose are D-galactonic acid (carboxylic group at C1) and meso-galactaric acid (mucic acid) (carboxylic groups at C1 and C6). It is also a uronic acid or hexuronic acid. Naturally occurring uronic acids are D-glucuronic acid, D-galacturonic acid, L-iduronic acid and D-mannuronic acid.

화학적 성질

The α form melts with decomposition at 159–160C. Soluble in water, slightly soluble in hot alcohol; insoluble in ether

용도

Biochemical research

정의

ChEBI: The pyranose form of D-galacturonic acid

Purification Methods

Crystallisation of the acid from 95% EtOH and drying it in a vacuum desiccator (12mm) over P2O5 gives the monohydrate mixture of and anomers (mostly -) as white micro needles, which sinter at ~100-111o and melt at 159-160o, [] D 20 +107o (initial, c 4 in H2O mutarotating to +51o). [Link & Sell Biochemical Preparations 3 74, 78 1953, Beilstein 3 IV 2000.] The -anomer is obtained by warming the -anomer in EtOH, AcOH or EtOAc and has m 1 6 0o (165o, sinters at 1 4 0o), [] D 20 +27o (initial, c 2 in H2O mutarotating to +55.3o in 24hours). The sodium salt [14984-39-5] M 216.1 has [] D 20 +27o (c 10 in H2O after 5hours). The phenylhydrazone has m 141o(from MeOH). [Ehrlich & Schubert Chem Ber 62 1974, 2014 1929, Anderson & King J Chem Soc 5333 1961, Beilstein 3 IV 2001.]

D-GALACTURONIC ACID 준비 용품 및 원자재

원자재

준비 용품


D-GALACTURONIC ACID 공급 업체

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