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Bis(triphenylphosphine)palladium(II) chloride

Bis(triphenylphosphine)palladium(II) chloride 구조식 이미지

카스 번호:: 13965-03-2

상품명:: Bis(triphenylphosphine)palladium(II) chloride

동의어(영문):: DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM;BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE;(PPh3)2PdCl2;DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);BIS(TRIPHENYLPHOSPHINE)PALLADIUM CHLORIDE;Bis(triphenylphosphine)dichloropalladium;BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);TRIPHENYLPHOSPHINE PALLADIUM CHLORIDE;Bis(triphenylphosphine)palladium(ll) chloride;PALLADIUM BIS(TRIPHENYLPHOSPHINE) DICHLORIDE

CBNumber:: CB9364066

분자식:: C36H30Cl2P2Pd

포뮬러 무게:: 701.9

MOL 파일:: 13965-03-2.mol

MSDS 파일:: SDS

속성

안전

MSDS

용도

공급 업체 630

Bis(triphenylphosphine)palladium(II) chloride 속성

녹는점: 260°C

증기압: 0Pa at 25℃

RTECS 번호: RT3578000

저장 조건: Store below +30°C.

용해도: 클로로포름(약간 용해됨), 디클로로메탄(약간 용해됨, 가열), 메탄올(약간 용해됨）

물리적 상태: 가루

색상: 노란색

수용성: 물에 불용성. 벤젠, 톨루엔에 용해됩니다.

감도: Hygroscopic

BRN: 4935975

InChI: InChI=1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChIKey: ILBDOZRDKNIJBS-UHFFFAOYSA-N

SMILES: P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Pd](Cl)Cl

LogP: 5.69 at 20℃

CAS 데이터베이스: 13965-03-2(CAS DataBase Reference)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	Xn
위험 카페고리 넘버	36/37/38-22-40-19
안전지침서	37/39-26-36/37
WGK 독일	3
F 고인화성물질	3-10-21
TSCA	No
HS 번호	28439090

그림문자(GHS):

신호 어:

Warning

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	그림 문자	P- 코드
H317	알레르기성 피부 반응을 일으킬 수 있음	피부 과민성 물질	구분 1	경고		P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H413	장기적 영향에 의해 수생생물에 유해의 우려가 있음	수생 환경유해성 물질 - 만성	구분 4

예방조치문구:

P261	분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P272	작업장 밖으로 오염된 의복을 반출하지 마시오.
P273	환경으로 배출하지 마시오.
P280	보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352	피부에 묻으면 다량의 물로 씻으시오.
P333+P313	피부자극성 또는 홍반이 나타나면 의학적인 조치·조언를 구하시오.

NFPA 704

	1
0		0

Bis(triphenylphosphine)palladium(II) chloride MSDS

Dichlorobis(triphenylphosphine)palladium(II)

Bis(triphenylphosphine)palladium(II) chloride C화학적 특성, 용도, 생산

화학적 성질

Bis(triphenylphosphine)palladium chloride is a coordination compound of palladium containing two triphenylphosphine and two chloride ligands. This yellow solid is insoluble in water but can dissolve in some organic solvents, such as toluene and benzene, and is slightly soluble in acetone and chloroform. It is used for palladium-catalyzed coupling reactions, e.g. the Sonogashira–Hagihara reaction. The complex adopts a square planar geometry and numerous similar complexes are known, with different phosphine ligands.

용도

Bis(triphenylphosphine)palladium(II) chloride is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of me tallacyclic complexes which show antiinflammatory and antifungal properties.

Synthesis

The synthesis of Bis(triphenylphosphine)palladium(II) chloride can be achieved by the reaction of palladium(II) chloride with triphenylphosphine, resulting in the formation of Bis(triphenylphosphine)palladium(II) chloride. This chemical process is represented by the balanced equation: PdCl2 + 2 PPh3 → PdCl2(PPh3)2.

일반 설명

Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium.

Bis(triphenylphosphine)palladium(II) chloride 준비 용품 및 원자재

원자재

아세토나이트릴 에틸알코올 톨루엔 하이드라진, 모노수화물 팔라듐 염화물 초산에틸 트리페닐포스핀 4-METHOXYPHENYL ISOCYANIDE 테트라 키스 (트리 페닐 포스 핀) 팔라듐 (0) 팔라듐 1-Butyl nitrite

준비 용품

5-(2-PHENYLETH-1-YNYL)THIOPHENE-2-CARBALDEHYDE 4-ETHYNYLANILINE 4-Azaindole 4-PHENYLETHYNYLPHTHALIC ANHYDRIDE 2-CHLORO-7H-PYRROLO[2,3-D]PYRIMIDINE 3,4-DICHLOROPHENYLACETYLENE

Bis(triphenylphosphine)palladium(II) chloride 공급 업체

글로벌( 630)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Shaoxin Catsyn Co., Ltd.	+undefined-0575-82040869 +86-0575-82040869;	sales@catsyn.com	China	6116	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5993	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7378	58
Springchem New Material Technology Co.,Limited	+86-021-62885108 +8613917661608	info@spring-chem.com	China	2068	57
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15371	58
Beijing Cooperate Pharmaceutical Co.,Ltd	010-60279497	sales01@cooperate-pharm.com	CHINA	1811	55
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9352	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60

Bis(triphenylphosphine)palladium(II) chloride 관련 검색:

팔라듐 염화물 염화칼슘 염화 코발트 염화콜린 염화 암모늄 팔라듐 염화 폴리비닐 염화나트륨 트리페닐포스핀 염화칼륨 테트라 키스 (트리 페닐 포스 핀) 팔라듐 (0) (트리페닐포스포라닐리덴)아세트알데히드 디클로로 [비스 (2- (디 페닐 포스 피노) 페닐) 에테르] 팔라듐 (II) 디클로로 [(R) - (+) - 2,2'- 비스 (디 페닐 포스 피노) -1,1'- 바이 나프 틸] 팔라듐 (II) DICHLOROTRIPHENYLPHOSPHORANE Tris(triphenylphosphine)ruthenium(II) chloride Trifluoromethanesulfonimide Bis(acetonitrile)dichloropalladium(II)