흑연, 분말

흑연, 분말
흑연, 분말 구조식 이미지
카스 번호:
7782-42-5
한글명:
흑연, 분말
동의어(한글):
캘그래프G;흑연;그래파이트
상품명:
Graphite
동의어(영문):
Graphite powder;Flake graphite;pg50;shungite;GRAPHITE FOIL;GRAPHITE ELECTRODE;Amorphous graphite;Plumbago;GRAPHITE ROD;graphite flakes
CBNumber:
CB9369364
분자식:
C24X12
포뮬러 무게:
288.26
MOL 파일:
7782-42-5.mol
MSDS 파일:
SDS

흑연, 분말 속성

녹는점
3652-3697 °C(lit.)
끓는 점
4830°C
밀도
2.2 g/mL at 25 °C
저장 조건
no restrictions.
용해도
insoluble in H2O
물리적 상태
막대 모양
색상
검은색
Specific Gravity
2.25
수소이온지수(pH)
5-6 (50g/l, H2O, 20℃)(slurry)
비저항
(Electrical resistivity: surface 0.06 Ω/sq, sheet 2.7 μΩ m)
수용성
물에 불용성.
감도
Air & Light Sensitive
Crystal Structure
Hexagonal
Merck
13,4554
Dielectric constant
12.0(Ambient)
노출 한도
ACGIH: TWA 2 mg/m3
OSHA: TWA 15 mg/m3; TWA 5 mg/m3
NIOSH: IDLH 1250 mg/m3; TWA 2.5 mg/m3
NIST
Graphite(7782-42-5)
EPA
Graphite (7782-42-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,Xn
위험 카페고리 넘버 36/37-20
안전지침서 26-36-37/39-22
WGK 독일 1
RTECS 번호 MD9659600
TSCA Yes
HS 번호 3801 10 00
유해 물질 데이터 7782-42-5(Hazardous Substances Data)
IDLA 1,250 mg/m3
기존화학 물질 KE-18101
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H228 인화성 고체 인화성 고체 구분 1
구분 2
위험
경고
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P304+P340 흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P405 밀봉하여 저장하시오.
NFPA 704
1
2 0

흑연, 분말 C화학적 특성, 용도, 생산

용도

분말 야금, 전도성 도료, 연필심, 샤프심 브레이크, 내열도료 윤활유, 카본.

화학적 성질

Graphite is crystallized carbon and usually appears as soft, black scales. There are two types of graph ite, natural and artificial (activated). Natural and synthetic graphite may be mixed with each other or contain other additives.

출처

Graphite is usually found in metamorphic rocks as veins, lenses, and pockets and as thin laminae disseminated in gneisses, schists, and phyllites. Depending upon the mode of occurrence and origin, it is graded into three forms: flake graphite found in metamorphosed rocks as vein deposits, crystalline graphite found as fissure-filled veins, and cryptocrystalline graphite formed in metamorphosed coal beds. Natural graphite occurs in many parts of the world in fair abundance and it has been used in various applications.
In nature, graphite is found usually in association with feldspars, mica, quartz, pyroxene, rutile, pyrites, and apatite. These impurities are associated with vein graphite. The impurities with amorphous graphite are shale, slate, sandstone, quartz, and limestone. Graphite is found in almost every country, but Ceylon, Madagascar, Mexico, western Germany, and Korea all possess particularly plentiful reserves. Major industrial producers of graphite are South Korea, the largest producer in the world, followed by Austria.

용도

High-temperature lubricant, crucible container for handling molten metals such as Mg, Al, Zn, Ga, Sb, and Bi

용도

For "lead" pencils, refractory crucibles, stove polish; as pigment, lubricant, graphite cement; for matches and explosives, commutator brushes, anodes, arc-lamp carbons, electroplating; polishing Compounds, rust and needle-paper; coating for cathode ray tubes; moderator in nuclear piles.

정의

An allotrope of CARBON. Graphite is a good conductor of heat and electricity. The atoms are arranged in layers which cleave easily and graphite is used as a solid lubricant.

일반 설명

A mineral form of the element carbon. Hexagonal crystals or thin leaf-like layers. Steel-gray to black with a metallic luster and a greasy feel. An electrical conductor. Used for high-temperature crucibles, as a lubricant and in "lead" pencils.

반응 프로필

GRAPHITE is non-flammable in bulk form, but combustible. A reducing agent. Mixtures of graphite dust and air are explosive when ignited.Reacts violently with very strong oxidizing agents such as fluorine, chlorine dioxide, and potassium peroxide. Almost inert chemically when in bulk form. Keep away from ignition sources and oxidizing agents.

건강위험

Pure synthetic graphite acts as an inert or nuisance dust.

공업 용도

Graphite is a form of carbon. It was formerlyknown as black lead, and when first used forpencils was called Flanders’ stone. It is a naturalvariety of elemental carbon with a grayishblackcolor and a metallic tinge.
Carbon and graphite have been used inindustry for many years, primarily as electrodes,arc carbons, brush carbons, and bearings.In the last decade or so, development ofnew types and emergence of graphite fibers asa promising reinforcement for high-performancecomposites have significantly increasedthe versatility of this family of materials.

잠재적 노출

Natural graphite is used in foundry facings, steel making lubricants, refractories, crucibles, pencil “lead,” paints, pigments, and stove polish. Artificial graphite may be substituted for these uses with the excep tion of clay crucibles; other types of crucibles may be pro duced from artificial graphite. Additionally, it may be used as a high temperature lubricant or for electrodes. It is uti lized in the electrical industry in electrodes, brushes, con tacts, and electronic tube rectifier elements; as a constituent in lubricating oils and greases; to treat friction elements, such as brake linings; to prevent molds from sticking together; and in moderators in nuclear reactors. In addition, concerns have been expressed about synthetic graphite in fibrous form. Those exposed are involved in production of graphite fibers from pitch or acrylonitrile fibers and the manufacture and use of composites of plastics, metals, or ceramics reinforced with graphite fibers.

운송 방법

UN1362 Carbon, activated, Hazard Class: 4.2; Labels: 4.2-Spontaneously combustible material, International.

Purification Methods

Treat graphite with hot 1:1 HCl. Then filter, wash and the dried powdered is heated in an evacuated quartz tube at 1000o until a high vacuum is obtained. Cool this and store it in an atmosphere of helium [Craig et al. J Phys Chem 60 1225 1956].

비 호환성

Graphite is a strong reducing agent and reacts violently with oxidizers, such as fluorine, chlorine trifluoride, and potassium peroxide. Forms an explosive mixture with air. May be spontaneously combustible in air.

폐기물 처리

Do not incinerate. Carbon (graphite) fibers are difficult to dispose of by incineration. Waste fibers should be packaged and disposed of in a land fill authorized for the disposal of special wastes of this nature, or as otherwise may be required by law.

흑연, 분말 준비 용품 및 원자재

원자재

준비 용품


흑연, 분말 공급 업체

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