루테늄 카보닐
|
|
루테늄 카보닐 속성
- 녹는점
- 150 °C
- 저장 조건
- Inert atmosphere,Room Temperature
- 용해도
- 탄화수소(예: 헥산, 시클로헥산, 벤젠) 및 아세톤에 약간 용해됩니다.
- 물리적 상태
- 수정 같은
- 색상
- 오렌지 레드
- 색상
- 오렌지색
- CAS 데이터베이스
- 15243-33-1(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | F,Xn | ||
---|---|---|---|
위험 카페고리 넘버 | 11-20-2017/11/20 | ||
안전지침서 | 24/25 | ||
유엔번호(UN No.) | 1325 | ||
WGK 독일 | 3 | ||
위험 참고 사항 | Flammable/Harmful | ||
TSCA | Yes | ||
위험 등급 | 6.1 | ||
포장분류 | II | ||
HS 번호 | 28439000 | ||
기존화학 물질 | KE-34786 |
루테늄 카보닐 C화학적 특성, 용도, 생산
개요
Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.화학적 성질
The substance appears as orange plates or powder and is soluble in non-polar organic solvents.용도
Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).화학 반응
- Catalyst for the conversion of enynes to catechol derivatives.
- Catalyst for the intermolecular [2+2+1] cycloaddition of ketones, CO and alkenes or alkynes.
- 3-Component couplings.
- Reaction of α,β-unsaturated imines with carbon monoxide and alkenes to form β,γ-unsaturated γ-butyroactams.
- Ester decarboxylation.
- Catalyst for hydroamination and C-H bond activation.
- Used in sp3 C-H bond arylation and carbonylation.
- Ru/halide catalytic system for C-C bond forming reaction between alkynes and unsaturated carbonyl compounds.
- Amination of α-hydroxy amides.
일반 설명
Atomic number of base material: 44 Ruthenium루테늄 카보닐 준비 용품 및 원자재
원자재
준비 용품
루테늄 카보닐 공급 업체
글로벌( 206)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15928 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8823 | 58 |
Shanghai Longyu Biotechnology Co., Ltd. | +8615821988213 |
info@longyupharma.com | China | 2531 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 47465 | 58 |
career henan chemical co | +86-0371-86658258 15093356674; |
factory@coreychem.com | China | 29826 | 58 |
Richest Group Ltd | 18017061086 |
oled@richest-group.com | CHINA | 5601 | 58 |
SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 |
contact@trustwe.com | China | 5738 | 58 |
Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 |
daeyeon001@vip.163.com | China | 2062 | 58 |
루테늄 카보닐 관련 검색:
[1,3- 비스 (디 페닐 포스 피노) 프로판] 디클로로 니켈 (II) 트리스(트리페닐포스핀)루테늄(II) 염화물 트리스(트리페닐포스핀)로듐(I) 염화물 로디움(II) 아세틸아세토네이트 헥사카보닐 텅스텐 몰리브덴 카르보닐 루비듐 루테늄 카보닐 루테늄
Benzeneruthenium(II) chloride dimer
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
Dichloro(p-cymene)ruthenium(II) dimer
Rhodium(II) acetate dimer
Ruthenium(II) chloride mesitylene dimer
Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
TPP
Dihydridotris(triphenylphosphine)ruthenium carbonyl