p-클로로페놀

p-클로로페놀
p-클로로페놀 구조식 이미지
카스 번호:
106-48-9
한글명:
p-클로로페놀
동의어(한글):
4-클로로페놀;p-클로로페놀;4-클로로페놀;4-하이드록시클로로벤젠;1-클로로-4-에톡시벤젠;4-클로로-1-하이드록시벤젠;p-모노클로로페놀;p-클로로펜산;파라클로로페놀;페놀, 4-클로로-;페놀, p-클로로-;페놀,4-클로로-
상품명:
4-Chlorophenol
동의어(영문):
PARA CHLORO PHENOL;P-CHLOROPHENOL;4-CHLORPHENOL;4-chloro-1-hydroxybenzene;Chloroether;Phenol,4-chloro-;4-Chlorophenol(form2);4-Chlorophenol 5g [106-48-9];4-CHLOROPHENOL SOLUTION 725 MG/L FORAOX DETERMINATION ACCORDING TO DIN 38409-H41;(GC)>98%
CBNumber:
CB9477357
분자식:
C6H5ClO
포뮬러 무게:
128.56
MOL 파일:
106-48-9.mol
MSDS 파일:
SDS

p-클로로페놀 속성

녹는점
42-45 °C
끓는 점
220 °C (lit.)
밀도
1.306 g/mL at 25 °C (lit.)
증기 밀도
4.43 (vs air)
증기압
1 mm Hg ( 49.8 °C)
굴절률
1.5579
인화점
240 °F
저장 조건
2-8°C
용해도
에탄올: 가용성 50mg/mL, 투명하거나 매우 약간 흐릿함, 무색 내지 희미한 갈색을 띤 노란색
물리적 상태
저융점 결정질 덩어리
산도 계수 (pKa)
9.18(at 25℃)
색상
흰색에서 연한 노란색
냄새
페놀성
Odor Threshold
30 ppm
수용성
물에 용해 2.7g/100mL(20℃)
감도
Air Sensitive
Merck
14,2154
BRN
507004
Dielectric constant
9.5(54.0℃)
안정성
안정적인. 산 염화물, 산 무수물, 산화제, 철과 호환되지 않습니다.
LogP
2.5 at 35℃
CAS 데이터베이스
106-48-9(CAS DataBase Reference)
NIST
p-Chlorophenol(106-48-9)
EPA
p-Chlorophenol (106-48-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N
위험 카페고리 넘버 20/21/22-51/53-50
안전지침서 28-61-28A-24/25-60-36/37
유엔번호(UN No.) UN 2020 6.1/PG 3
WGK 독일 2
RTECS 번호 SK2800000
F 고인화성물질 10-23
TSCA Yes
위험 등급 6.1
포장분류 III
HS 번호 29081000
유해 물질 데이터 106-48-9(Hazardous Substances Data)
독성 LD50 orally in rats: 0.67 g/kg (Deichmann)
기존화학 물질 KE-05804
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
4 0

p-클로로페놀 MSDS


4-Chlorophenol

p-클로로페놀 C화학적 특성, 용도, 생산

화학적 성질

off-white to light tan crystals or powder

용도

It is used as main raw material of compounding for medicine, dye, plastic and other industries. 4-Chlorophenol was used in visible-light-induced degradation of 4-chlorophenol in aqueous suspension of pure TiO2.

정의

ChEBI: A monochlorophenol substituted at the pare position by a chlorine atom.

일반 설명

White crystals with a strong phenol odor Slightly soluble to soluble in water, depending on the isomer, and denser than water. Noncombustible. Used as an intermediate in organic synthesis of dyes and drugs.

공기와 물의 반응

Slightly soluble to soluble in water.

반응 프로필

CHLOROPHENOLS, SOLID are incompatible with acid chlorides, acid anhydrides and oxidizing agents. Also incompatible with iron . Liquefy and darken in color at temperatures above 108°F.

위험도

Toxic by skin absorption, inhalation, or ingestion; strong irritant to tissue.

건강위험

Inhalation causes headache, dizziness, weak pulse. Ingestion causes irritation of mouth and stomach; headache, dizziness, weak pulse. Contact with eyes causes severe irritation and burning. Contact with skin causes irritation and burn; if absorbed, causes same symptoms as inhalation.

화재위험

Special Hazards of Combustion Products: Toxic and irritating hydrogen chloride and chlorine gases may form in fires.

Safety Profile

Poison by inhalation and intraperitoneal routes. Moderately toxic by ingestion, skin contact, and subcutaneous routes. A severe skin and eye irritant. Human systemic effects by inhalation: excitement, irritability. Mutation data reported. Combustible when exposed to heat or flame. To fight fire, use water, spray, mist, fog, foam, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLOROPHENOLS and CHLORIDES.

잠재적 노출

Monochlorophenols are used in the manufacture of fungicides, slimicides, bactericides, pesticides, herbicides, disinfectants, wood and glue preservatives; in the production of phenolic resins; in the extraction of certain minerals from coal; as a denaturant for ethanol; as an antiseptic; as a disinfectant, and others.

운송 방법

UN 2020 (solid); UN2021 (liquid) Chlorophenols, solid and liquid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Distil the phenol, then crystallise it from pet ether (b 40-60o) or hexane, and dry it under vacuum over P2O5 at room temperature. [Bernasconi & Paschalis J Am Chem Soc 108 2969 1986, Beilstein 6 IV 820.]

비 호환성

May form explosive mixture with air. Contact with oxidizing agents can cause fire and explosion hazard. Heat produces hydrogen chloride and chlorine. Corrosive to aluminum, copper and other chemically active metals.

폐기물 처리

Incinerate in admixture with flammable solvent in furnace equipped with afterburner and scrubber.

p-클로로페놀 준비 용품 및 원자재

원자재

준비 용품


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