테트라에틸렌펜트아민

테트라에틸렌펜트아민
테트라에틸렌펜트아민 구조식 이미지
카스 번호:
112-57-2
한글명:
테트라에틸렌펜트아민
동의어(한글):
테트라에틸렌펜타민;테트라에틸렌펜트아민;1,11-다이아미노-3,6,9-트리아자운데칸;1,2-에탄아이아민, N-(2-아미노에틸)-N-(2-((2-아미노에틸)아미노)에틸)-;1,4,7,10,13-펜타아자트리데칸;3,6,9-트리아자운데칸-1,11-다이아미노
상품명:
1,4,7,10,13-Pentaazatridecane
동의어(영문):
TETRAETHYLENEPENTAMINE;Tetren;Tetraethyenepentamine;2-Ethanediamine;N1-(2-aMinoethyl)-N2-(2-((2-aMinoethyl)aMino)ethyl)ethane-1,2-diaMine;deh26;TETRENE;TETRAEN;D.E.H. 26;Texlin 400
CBNumber:
CB9715701
분자식:
C8H23N5
포뮬러 무게:
189.3
MOL 파일:
112-57-2.mol
MSDS 파일:
SDS

테트라에틸렌펜트아민 속성

녹는점
-40 °C (lit.)
끓는 점
340 °C
밀도
0.998 g/mL at 25 °C (lit.)
증기 밀도
6.53 (vs air)
증기압
<0.01 mm Hg ( 20 °C)
굴절률
n20/D 1.505(lit.)
인화점
365 °F
저장 조건
Store below +30°C.
용해도
6540g/L
산도 계수 (pKa)
pK1:2.98(+5);pK2:4.72(+4);pK3:8.08(+3);pK4:9.10(+2);pK5:9.67(+1) (25°C,)
물리적 상태
액체
색상
투명한
수소이온지수(pH)
11.8 (20g/l, H2O, 20℃)
냄새
암모니아 냄새
폭발한계
0.1-15%(V)
수용성
녹는
감도
air sensitive
BRN
506966
안정성
안정적인. 타기 쉬운. 강한 산화제, 무기산, 할로겐화 탄화수소, 과산화수소와 호환되지 않습니다.
CAS 데이터베이스
112-57-2(CAS DataBase Reference)
NIST
Tetraethylenepentamine(112-57-2)
EPA
Tetraethylenepentamine (112-57-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C,N
위험 카페고리 넘버 21/22-34-43-51/53
안전지침서 26-36/37/39-45-61
유엔번호(UN No.) UN 2320 8/PG 3
WGK 독일 2
RTECS 번호 KH8585000
F 고인화성물질 21
자연 발화 온도 610 °F
위험 등급 8
포장분류 III
HS 번호 29212900
유해 물질 데이터 112-57-2(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 3990 mg/kg LD50 dermal Rabbit 660 mg/kg
기존화학 물질 KE-01347
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
3 0

테트라에틸렌펜트아민 MSDS


1,4,7,10,13-Pentaazatridecane

테트라에틸렌펜트아민 C화학적 특성, 용도, 생산

화학적 성질

colourless to green-yellow viscous liquid

용도

Solvent for sulfur, acid gases, and various resins and dyes; saponifying agent for acidic materials; manufacture of synthetic rubber; dispersant in motor oils; intermediate for oil additives.

일반 설명

A viscous liquid. Slightly less dense than water. Vapors heavier than air. Corrosive to the eyes, skin, mouth, throat and stomach. Vapors irritate the eyes and corrosive to the upper respiratory tract. Vapors may irritate the eyes. Flash point 325°F.

공기와 물의 반응

Soluble in water. Hygroscopic.

반응 프로필

1,4,7,10,13-Pentaazatridecane is hygroscopic. 1,4,7,10,13-Pentaazatridecane can react with oxidizing materials and strong acids. 1,4,7,10,13-Pentaazatridecane may attack some forms of plastics.

위험도

Strong irritant to eyes and skin.

건강위험

Inhalation may cause nausea and slight irritation; compound is a sensitizer, and prolonged contact may cause asthma. Ingestion can cause burns of mouth, esophagus, and possibly stomach. Contact with eyes or skin may cause burns. Repeated skin contact may cause dermatitis.

화재위험

Special Hazards of Combustion Products: Ammonia and toxic oxides of nitrogen may form in fires.

Safety Profile

Poison by ingestion and intravenous routes. Moderately toxic by skin contact. Mutation data reported. A corrosive irritant to skin, eyes, and mucous membranes. Combustible when exposed to heat or flame. Can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits toxic fumes of NOx.

잠재적 노출

Tetraethylenepentamine is used as a solvent for resins and dyes, in manufacture of synthetic rubber; and intermediate for oil additives; in papermaking.

운송 방법

UN2320 Tetraethylenepentamine, Hazard class: 8; Labels: 8-Corrosive material.

Purification Methods

Distil the amine under vacuum. Also purify via its penta hydrochloride, nitrate or sulfate. Jonassen, Frey and Schaafsma [J Phys Chem 61 504 1957] cooled a solution of 150g of the base in 300mL of 95% EtOH, and added dropwise 180mL of conc HCl, keeping the temperature below 20o. The white precipitate was filtered off, crystallised three times from EtOH/water, then washed with diethyl ether and dried by suction. Reilley and Holloway [J Am Chem Soc 80 2917 1958], starting with a similar solution cooled to 0o, added slowly (keeping the temperature below 10o) a solution of 4.5g-moles of HNO3 in 600mL of aqueous 50% EtOH (also cooled to 0o). The precipitate was filtered by suction, recrystallised five times from aqueous 5% HNO3, then washed with acetone and absolute EtOH and dried at 50o. [For purification via the sulfate see Reilley and Vavoulis (Anal Chem 31 243 1959), and for an additional purification step using the Schiff base with benzaldehyde see Jonassen et al. J Am Chem Soc 79 4279 1957]. [Beilstein 4 IV 1244.]

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. This chemical is strongly alkaline; reacts with acids.

테트라에틸렌펜트아민 준비 용품 및 원자재

원자재

준비 용품


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