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ChemicalBook >> CAS DataBase List >>Hydrazine hydrate

Hydrazine hydrate suppliers

Hydrazine hydrate

CAS:
7803-57-8
MF:
H6N2O
MW:
50.06

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Properties

Melting point:
−51.7 °C(lit.)
Boiling point:
120.1 °C(lit.)
Density 
1.03 g/mL at 20 °C
vapor density 
>1 (vs air)
vapor pressure 
5 mm Hg ( 25 °C)
refractive index 
n20/D 1.428(lit.)
Flash point:
204 °F
storage temp. 
0-6°C
solubility 
Acetonitrile (Sparingly), DMSO (Sparingly), Methanol (Slightly), Water (Sparingly)
form 
fuming liquid
Specific Gravity
1.032
color 
fuming liquid
PH
10-11 (10g/l, H2O, 20℃)
explosive limit
>3.4-99%(V)
Water Solubility 
Soluble in chloroform, DMSO, methanol. Slightly soluble in water.
Merck 
14,4771
BRN 
878137
Exposure limits
ACGIH: TWA 0.01 ppm (Skin)
OSHA: TWA 1 ppm(1.3 mg/m3)
NIOSH: IDLH 50 ppm; Ceiling 0.03 ppm(0.04 mg/m3)
Stability:
Stability Incompatible with a wide variety of materials, including oxidizing agents, heavy metal oxides, dehydrating agents, alkali metals, rust, silver salts. Combustible. Contact with many materials may cause fire or explosive decomposition. May react explosively with a variety of materials, including dehydrating agents, heavy metal ox
InChIKey
IKDUDTNKRLTJSI-UHFFFAOYSA-N

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06,GHS08,GHS09
Signal word 
Danger
Hazard statements 
H226-H301+H311-H314-H317-H330-H350-H410
Precautionary statements 
P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
T,N
Risk Statements 
45-20/21/22-34-43-51/53-50/53-23/24/25-10
Safety Statements 
53-45-60-61-36/37/39-26
RIDADR 
UN 3293 6.1/PG 3
WGK Germany 
3
RTECS 
MV8050000
23
Autoignition Temperature
280 °C
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
28251000
Toxicity
LD50 orally in Rabbit: 169 mg/kg

Use

Hydrazine hydrate is prepared by treating hydrazine sulfate, N2H4H2SO4 with sodium hydroxide. The product is collected by distillation under nitrogen. It also is obtained as a by-product in the Bayer Ketazine process for producing hydrazine in which hydrazine solution is hydrolysed under pressure in a ketazine column.

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