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Phosphorus tribromide

CAS:
7789-60-8
MF:
Br3P
MW:
270.69

Properties

Melting point:
-41.5 °C (lit.)
Boiling point:
175 °C (lit.)
Density 
2.88 g/mL at 20 °C (lit.)
vapor density 
9.3 (vs air)
vapor pressure 
0.27 psi ( 54 °C)
refractive index 
n20/D 1.697(lit.)
Flash point:
172.9°C
storage temp. 
Store below +30°C.
form 
Liquid
Specific Gravity
2.88
color 
Clear to slightly hazy colorless to yellow or light brown
Odor
Irritating odour
Water Solubility 
reacts
FreezingPoint 
-40℃
Sensitive 
Moisture Sensitive
Merck 
14,7357
BRN 
3903060
Stability:
Stable, but reacts violently with water. Incompatible with moisture, strong bases, strong oxidizing agents, reactive metals, acids, alcohols.
InChIKey
IPNPIHIZVLFAFP-UHFFFAOYSA-N

Safety Information

Symbol(GHS) 

GHS05,GHS07,GHS08
Signal word 
Danger
Hazard statements 
H314-H335-H336-H351-H373-H318
Precautionary statements 
P260h-P301+P330+P331-P303+P361+P353-P405-P501a-P261-P280-P305+P351+P338-P310
Hazard Codes 
C
Risk Statements 
34-37-40-14-67
Safety Statements 
26-45-36/37-36/37/39
RIDADR 
UN 3264 8/PG 2
WGK Germany 
2
RTECS 
TH4460000
21
TSCA 
Yes
HS Code 
2812 90 00
HazardClass 
8
PackingGroup 
II

Use

Phosphorus tribromide reacts with oxidizing agents to generate heat and products that may be flammable, combustible, or otherwise reactive; the reactions may be violent. Forms complexes with potassium or sodium metal that explode when shocked. Drop wise addition to 3-phenylpropanol caused an explosion when stirring of the mixture was discontinued [Chem. Brit., 1974, 10, 101-102].

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Phosphorus tribromide Related Search:

Sodium triacetoxyborohydrideTrimethylsilylacetyleneTrimethylsilyl trifluoromethanesulfonatePyridinium tribromidePOTASSIUM TRIFLUOROMETHANESULFONATEIodotrimethylsilane2,2,2-TribromoethanolTribromoacetaldehydeVANADIUM(III) ACETYLACETONATETriethylboraneBis(tributyltin) oxideTributylphosphineSodium acetate trihydratePHOSPHORUS PENTABROMIDEPhosphorusPhosphorus oxybromide THIOPHOSPHORYL BROMIDEPhosphorus tribromide
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