Triethylsilane manufacturers and suppliers

Triethylsilane suppliers

Properties

Melting point:: -157°C

Boiling point:: 107-108 °C (lit.)

Density: 0.728 g/mL at 25 °C (lit.)

vapor pressure: >1 hPa (20 °C)

refractive index: n20/D 1.412(lit.)

Flash point:: 25 °F

storage temp.: Store below +30°C.

solubility: insol H2O; sol hydrocarbons, halocarbons, ethers.

form: liquid

Specific Gravity: 0.728

color: colorless

Water Solubility: Miscible with water.

Sensitive: Moisture Sensitive

Hydrolytic Sensitivity: 3: reacts with aqueous base

BRN: 1098278

Stability:: Stable, but moisture sensitive. Highly flammable. Generates highly flammable gas (hydrogen) in contact with water, acids and bases.

LogP: 3.6 at 20℃

Safety Information

Symbol(GHS): GHS02,GHS07

Signal word: Danger

Hazard statements: H225-H315-H319-H335

Precautionary statements: P210-P233-P240-P241-P303+P361+P353-P305+P351+P338

Hazard Codes: F,Xi

Risk Statements: 11-36/37/38-52/53

Safety Statements: 9-16-29-33-37/39-26-61

RIDADR: UN 1993 3/PG 2

WGK Germany: 1

F: 10-21

TSCA: Yes

HazardClass: 3

PackingGroup: II

HS Code: 29310095

Use

R. Boukherroub,,, C. Chatgilialoglu,, and, and G. Manuel. PdCl2-Catalyzed Reduction of Organic Halides by Triethylsilane. Organometallics 15.5(1996):1508-1510. Jian Yang and, and M. Brookhart. Iridium-Catalyzed Reduction of Alkyl Halides by Triethylsilane. Journal of the American Chemical Society 129.42(2007):12656-7. And, Pijus K. Mandal, and J. S. Mcmurray. PdC-Induced Catalytic Transfer Hydrogenation with Triethylsilane. Journal of Organic Chemistry 72.17(2007):6599-6601. Chen, Bang Chi, et al. Novel triethylsilane mediated reductive N -alkylation of amines: improved synthesis of 1-(4-imidazolyl)methyl-4-sulfonylbenzodiazepines, new farnesyltransferase inhibitors. Tetrahedron Letters 42.7(2001):1245-1246.

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