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ChemicalBook >> CAS DataBase List >> (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl price.
  • $25 - $485
  • Product name: (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
  • CAS: 135139-00-3
  • MF: C52H48P2
  • MW: 734.89
  • EINECS:681-146-8
  • MDL Number:MFCD01630821
  • Synonyms:2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL;(S)-(-)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl , ((S)-Xylyl ;(S)-(-)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl;(S)-3,5-Xyl-BINAP;PHOSPHINE, 1,1''-[(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYL]BIS[1,1-BIS(3,5-DIMETHYLPHENYL)-;(S)-(-)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl , 98% ((S)-Xylyl-BINAP);(S)-3,5-Xylyl-BINAP, (S)-(-)-2,2μ-Bis[di(3,5-xylyl)phoshino]-1,1μ-binaphthyl, (S)-(-)-2,2μ-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1μ-binaphthyl
Price23 Properties Safety Information Description
23 prices
Selected condition：
Brand
  • AK Scientific
  • Alfa Aesar
  • Alichem
  • Ambeed
  • Chem-Impex
  • ChemScene
  • ChemSupplyAustralia
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 100mg
  • 200mg
  • 250mg
  • 500mg
  • 1g
  • 5g
  • ManufacturerAK Scientific
  • Product number4137AL
  • Product description(S)-(-)-XylBINAP
  • Packaging200mg
  • Price$139
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product number4137AL
  • Product description(S)-(-)-XylBINAP
  • Packaging1g
  • Price$320
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH26970
  • Product description(S)-(-)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
  • Packaging100mg
  • Price$93.3
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH26970
  • Product description(S)-(-)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
  • Packaging500mg
  • Price$301
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number135139003
  • Product description(R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene
  • Packaging250mg
  • Price$183.6
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number135139003
  • Product description(R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene
  • Packaging1g
  • Price$481.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA999826
  • Product description(S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98%
  • Packaging100mg
  • Price$25
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA999826
  • Product description(S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98%
  • Packaging250mg
  • Price$45
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA999826
  • Product description(S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98%
  • Packaging1g
  • Price$85
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA999826
  • Product description(S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98%
  • Packaging5g
  • Price$340
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number41165
  • Product description(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity)
  • Packaging200MG
  • Price$63.84
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number41165
  • Product description(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity)
  • Packaging1G
  • Price$221.76
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W014408
  • Product description(S)-DM-BINAP ≥98.0%
  • Packaging500mg
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W014408
  • Product description(S)-DM-BINAP ≥98.0%
  • Packaging1g
  • Price$97
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W014408
  • Product description(S)-DM-BINAP ≥98.0%
  • Packaging5g
  • Price$485
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300007
  • Product description(S)-(-)-2,2'-Bis[di-(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl , 98%
  • Packaging250mg
  • Price$48.4
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 4137AL (S)-(-)-XylBINAP 200mg $139 2021-12-16 Buy
AK Scientific 4137AL (S)-(-)-XylBINAP 1g $320 2021-12-16 Buy
Alfa Aesar H26970 (S)-(-)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 100mg $93.3 2021-12-16 Buy
Alfa Aesar H26970 (S)-(-)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 500mg $301 2021-12-16 Buy
Alichem 135139003 (R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 250mg $183.6 2021-12-16 Buy
Alichem 135139003 (R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 1g $481.5 2021-12-16 Buy
Ambeed A999826 (S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98% 100mg $25 2021-12-16 Buy
Ambeed A999826 (S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98% 250mg $45 2021-12-16 Buy
Ambeed A999826 (S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98% 1g $85 2021-12-16 Buy
Ambeed A999826 (S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98% 5g $340 2021-12-16 Buy
Chem-Impex 41165 (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity) 200MG $63.84 2021-12-16 Buy
Chem-Impex 41165 (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity) 1G $221.76 2021-12-16 Buy
ChemScene CS-W014408 (S)-DM-BINAP ≥98.0% 500mg $75 2021-12-16 Buy
ChemScene CS-W014408 (S)-DM-BINAP ≥98.0% 1g $97 2021-12-16 Buy
ChemScene CS-W014408 (S)-DM-BINAP ≥98.0% 5g $485 2021-12-16 Buy
ChemSupplyAustralia 300007 (S)-(-)-2,2'-Bis[di-(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl , 98% 250mg $48.4 2021-12-16 Buy
Next Last

Properties

Melting point :203-206°C
alpha :-172 º (c=1 in chloroform)
Boiling point :825.3±65.0 °C(Predicted)
storage temp. :Inert atmosphere,Room Temperature
Water Solubility :Insoluble in water
form :crystal
color :white to pale yellow

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Catalyst for:
  • Asymmetric hydrogenation of benzophenone
  • Regio- and stereoselective preparation of axially chiral arylnaphthalene derivatives via rhodium-catalyzed [2+2+2] cycloaddition of diynes with naphthalenepropynoic acid derivatives in the presence of chiral biaryl bisphosphine ligands
  • Regiodivergent rhodium-catalyzed [(2+2)+2] carbocyclization of 1,6-enynes with Me propiolates
  • Ligand controlled regioselective and stereoselective desymmetrizing rhodium-catalyzed allylic arylation of meso cyclopentene dicarbonates with arylboronic acids to form regioisomeric arylcyclopentenols
  • Platinum(II) complex-catalyzed enantioselective aldol reaction with ketene silyl acetals in DMF at room temperature
  • Stereoselective preparation of chiral N,O-biaryls via Rh-catalyzed [2+2+2] cycloaddition of conjugate ynamides with diynes

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Suppliers and manufacturers

career henan chemical co
(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
$1.00 /1kg
(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl CAS:135139-00-3
XINXIANG RUNYU MATERIAL CO., LTD.
Shanghai Daken Advanced Materials Co.,Ltd
Hubei Jusheng Technology Co.,Ltd.
Chongqing Chemdad Co., Ltd
CONIER CHEM AND PHARMA LIMITED
Richest Group Ltd
Jinan Honest Pharm Co., Ltd
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
Zhengzhou Alfa Chemical Co.,Ltd