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ChemicalBook >> CAS DataBase List >> Sodium bis(trimethylsilyl)amide

Sodium bis(trimethylsilyl)amide

Sodium bis(trimethylsilyl)amide price.
  • $22.4 - $3090
  • Product name: Sodium bis(trimethylsilyl)amide
  • CAS: 1070-89-9
  • MF: C6H18NNaSi2
  • MW: 183.37
  • EINECS:213-983-8
  • MDL Number:MFCD00009835
  • Synonyms:N-SODIUMHEXAMETHYLDISILAZANE;HEXAMETHYLDISILAZANE SODIUM SALT;HMN NA SALT;1,1,1,3,3,3-HEXAMETHYLDISILAZANE SODIUM SALT;SODIUM BIS(TRIMETHYLSILYL)AMIDE, ~1 M IN THF;SODIUM BIS(TRIMETHYLSILYL)AMIDE SOL., ~0 .6 M IN TOLUENE;SODIUM BIS(TRIMETHYLSILYL)AMIDE, 1.0M SO LUTION IN TETRAHYDROFURAN;SODIUM BIS(TRIMETHYLSILYL)AMIDE, 0.6M SO LUTION IN TOLUENE
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  • ManufacturerAHH
  • Product numberMT-22288
  • Product descriptionSodium bis(trimethylsilyl)amide 98%
  • Packaging100g
  • Price$298
  • Updated2021-12-16
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  • ManufacturerAlfa Aesar
  • Product number033505
  • Product descriptionSodium bis(trimethylsilyl)amide, 98%
  • Packaging2g
  • Price$22.65
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product numberL08779
  • Product descriptionSodium bis(trimethylsilyl)amide, 1M soln. in THF
  • Packaging100ml
  • Price$58
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product numberL13352
  • Product descriptionSodium bis(trimethylsilyl)amide, 2M soln. in THF
  • Packaging100ml
  • Price$73.4
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product number033505
  • Product descriptionSodium bis(trimethylsilyl)amide, 98%
  • Packaging10g
  • Price$83.6
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product numberL08779
  • Product descriptionSodium bis(trimethylsilyl)amide, 1M soln. in THF
  • Packaging500ml
  • Price$168
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product numberL13352
  • Product descriptionSodium bis(trimethylsilyl)amide, 2M soln. in THF
  • Packaging500ml
  • Price$283
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product number033505
  • Product descriptionSodium bis(trimethylsilyl)amide, 98%
  • Packaging50g
  • Price$305
  • Updated2024-03-01
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  • ManufacturerApolloscientific
  • Product numberOR33650
  • Product descriptionSodium bis(trimethylsilyl)amide, 2M in THF
  • Packaging100ml
  • Price$135
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR33650
  • Product descriptionSodium bis(trimethylsilyl)amide, 2M in THF
  • Packaging500ml
  • Price$304
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number30795
  • Product descriptionSodiumbis(trimethylsilyl)amide,99%(Titration) 99%(Titration)
  • Packaging5G
  • Price$22.4
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number24551
  • Product descriptionSodium bis(trimethylsilyl)amide solution, 1.0 M in THF
  • Packaging250ML
  • Price$45
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number30795
  • Product descriptionSodiumbis(trimethylsilyl)amide,99%(Titration) 99%(Titration)
  • Packaging25G
  • Price$78.4
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number24551
  • Product descriptionSodium bis(trimethylsilyl)amide solution, 1.0 M in THF
  • Packaging1L
  • Price$160
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number30794
  • Product descriptionSodium bis(trimethylsilyl)amide solution, 0.6 M in Toluene
  • Packaging1L
  • Price$185
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number30795
  • Product descriptionSodium bis(trimethylsilyl)amide ≥ 99%(Titration)
  • Packaging100G
  • Price$240
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-22288 Sodium bis(trimethylsilyl)amide 98% 100g $298 2021-12-16 Buy
Alfa Aesar 033505 Sodium bis(trimethylsilyl)amide, 98% 2g $22.65 2024-03-01 Buy
Alfa Aesar L08779 Sodium bis(trimethylsilyl)amide, 1M soln. in THF 100ml $58 2024-03-01 Buy
Alfa Aesar L13352 Sodium bis(trimethylsilyl)amide, 2M soln. in THF 100ml $73.4 2024-03-01 Buy
Alfa Aesar 033505 Sodium bis(trimethylsilyl)amide, 98% 10g $83.6 2024-03-01 Buy
Alfa Aesar L08779 Sodium bis(trimethylsilyl)amide, 1M soln. in THF 500ml $168 2024-03-01 Buy
Alfa Aesar L13352 Sodium bis(trimethylsilyl)amide, 2M soln. in THF 500ml $283 2024-03-01 Buy
Alfa Aesar 033505 Sodium bis(trimethylsilyl)amide, 98% 50g $305 2024-03-01 Buy
Apolloscientific OR33650 Sodium bis(trimethylsilyl)amide, 2M in THF 100ml $135 2021-12-16 Buy
Apolloscientific OR33650 Sodium bis(trimethylsilyl)amide, 2M in THF 500ml $304 2021-12-16 Buy
Chem-Impex 30795 Sodiumbis(trimethylsilyl)amide,99%(Titration) 99%(Titration) 5G $22.4 2021-12-16 Buy
Chem-Impex 24551 Sodium bis(trimethylsilyl)amide solution, 1.0 M in THF 250ML $45 2021-12-16 Buy
Chem-Impex 30795 Sodiumbis(trimethylsilyl)amide,99%(Titration) 99%(Titration) 25G $78.4 2021-12-16 Buy
Chem-Impex 24551 Sodium bis(trimethylsilyl)amide solution, 1.0 M in THF 1L $160 2021-12-16 Buy
Chem-Impex 30794 Sodium bis(trimethylsilyl)amide solution, 0.6 M in Toluene 1L $185 2021-12-16 Buy
Chem-Impex 30795 Sodium bis(trimethylsilyl)amide ≥ 99%(Titration) 100G $240 2021-12-16 Buy

Properties

Melting point :171-175 °C (lit.)
Boiling point :67°C
Density :0.904 g/mL at 25 °C
Flash point :43 °F
storage temp. :2-8°C
solubility :Soluble in hexane, toluene, ether,terahydrofuran, benzene and toluene.
form :Liquid
Specific Gravity :0.9
color :Clear orange to brown
Water Solubility :reacts
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Sensitive :Moisture Sensitive
BRN :3629917
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) CAS DataBase Reference :1070-89-9(CAS DataBase Reference)
EPA Substance Registry System :Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, sodium salt (1070-89-9)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363 Wash contaminated clothing before reuse.

Description

Sodium bis(trimethylsilyl)amide is useful for the generation of carbenes, the amination of sulfonamides, and for the preparation of lanthanide complexes. It is significantly accelerated the polymerization of pheneylacetylene in conjunction with rhodium (I) catalysis. It is used to deprotonate ketones and esters to generate enolate derivatives, phosphonium salts, generating Wittig reagents.

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