Hydrocarbon halides

Hydrocarbon halide, or hydrocarbon for short, refers to the product produced during the process of hydrogen atoms replaced by by halogen (fluorine, chlorine, bromine, iodine) in the hydrocarbon molecules. According to the different hydrocarbon groups, it could be divided into categories like aliphatic halogenated hydrocarbons (including saturated and unsaturated halogenated hydrocarbons), aromatic halogenated hydrocarbons. According to the amount of halogen atoms contained in the molecule, it could be divided into categories like halogenated hydrocarbons, dihalogenated hydrocarbons and polyhalogenated hydrocarbons. Most of the halogenated hydrocarbons are liquid. The proportion of Iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. They are insoluble in water and could be dissolved in any proportion with hydrocarbons, they also could dissolve many other organics. The proportion of Hydrocarbon halide would decreases with the increase of the amount of carbon atoms. When there are the same hydrocarbon groups, the boiling point and the proportion of the halogenated hydrocarbons would increase in the order of chlorinated hydrocarbons, brominated hydrocarbons, and iodinated hydrocarbons. In the isomer, the more branches it gets, the lower boiling point it has. Most of these substances are toxic and can burn. And their combustion properties decrease with the increase of the amount of halogen atoms in the compound. When it comes to storage, fire hazard should be managed in A, B, C three categories according to fire risk indicators. When it catch fire, the gas should be treated by the C class of fire treatment, liquid by B class of fire treatment. Eenough attention should be payed to anti-virus.
The amount of naturally occurring halo hydrocarbons is very small, and the majority of halo hydrocarbons are synthesized by halogenation of alkanes, and compounded by unsaturated hydrocarbons. It also could be compounded during the reaction between alcohol with hydrohalic acid.
The amount of Halohydrocarbons are more isomers than corresponding hydrocarbons. Apart from the carbon isomerism, unsaturated bond position isomerization, cis-trans isomerism and optical isomerism, there are halogen atom isomerizations as well.. when the Halogenated hydrocarbon was named, the hydrocarbon plays a rule as the matrix while halogen atom plays as substituents. The position, number and name of halogen should be lined out before the name of the hydrocarbon. At room temperature, apart from methyl chloride, methyl bromide, ethyl chloride, vinyl chloride and others which are gas in room temperature, the halo hydrocarbon is liquid in general and the highly  halogenated hydrocarbon is solid.
Halohydrocarbons is not dissolvable in water, but soluble in a variety of organic solvents, and can be dissolved in a variety of weak polarity and non-polar organic compounds. So it  is a kind of commonly used solvent. The relative density of iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. The boiling point of halogenated hydrocarbons increases with the increasing atomic amount of halogen atoms. The boiling point of the same series of halogenated hydrocarbons increases with increase of the amount of carbon chain. The more branched the isomer, the lower the boiling point would it have (except from fluorinated alkanes).
The chemical property of halogenated hydrocarbons is much more active than paraffin, so  halogenated hydrocarbons can produce a variety of chemical reactions, and turn them into various types of compounds. It has an important position in organic synthesis. Halo hydrocarbon has been applied widely in many trades, apart from being used as a solvent, it also could be used as refrigerant, extinguishing agent, anesthetics and preservatives.
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Structure Chemical Name CAS MF
Cyclobutyl chloride Cyclobutyl chloride 1120-57-6 C4H7Cl
2-Chloro-1,4-dimethylbenzene 2-Chloro-1,4-dimethylbenzene 95-72-7 C8H9Cl
2-BROMO-2-BUTENE 2-BROMO-2-BUTENE 13294-71-8 C4H7Br
HEXAKIS(BROMOMETHYL)BENZENE HEXAKIS(BROMOMETHYL)BENZENE 3095-73-6 C12H12Br6
DIBROMODIFLUOROMETHANE DIBROMODIFLUOROMETHANE 75-61-6 CBr2F2
2-BROMO-1-PHENYLPROPANE 2-BROMO-1-PHENYLPROPANE 2114-39-8 C9H11Br
3-(Bromomethyl)biphenyl 3-(Bromomethyl)biphenyl 14704-31-5 C13H11Br
1,6-Diiodododecafluorohexane 1,6-Diiodododecafluorohexane 375-80-4 C6F12I2
1,1,2-Trichlorotrifluoroethane 1,1,2-Trichlorotrifluoroethane 76-13-1 C2Cl3F3
P,P'-DDD P,P'-DDD 72-54-8 C14H10Cl4
1-IODOOCTADECANE 1-IODOOCTADECANE 629-93-6 C18H37I
ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-M-XYLENE ALPHA,ALPHA,ALPHA',ALPHA'-TETRABROMO-M-XYLENE 36323-28-1 C8H6Br4
3,4,5-TRIFLUOROBENZYL BROMIDE 3,4,5-TRIFLUOROBENZYL BROMIDE 220141-72-0 C7H4BrF3
4-BROMO-2,3,5,6-TETRAFLUOROBENZOTRIFLUORIDE 4-BROMO-2,3,5,6-TETRAFLUOROBENZOTRIFLUORIDE 17823-46-0 C7BrF7
4-Iodo-1,2-dimethylbenzene 4-Iodo-1,2-dimethylbenzene 31599-61-8 C8H9I
Methyl bromide Methyl bromide 74-83-9 CH3Br
4-(Chloromethyl)biphenyl 4-(Chloromethyl)biphenyl 1667-11-4 C13H11Cl
1,6-DIIODOHEXANE 1,6-DIIODOHEXANE 629-09-4 C6H12I2
PERFLUOROTETRACOSANE PERFLUOROTETRACOSANE 1766-41-2 C24F50
PERFLUOROALLYLBENZENE PERFLUOROALLYLBENZENE 67899-41-6 C9F10
2-Iodobenzyl chloride 2-Iodobenzyl chloride 59473-45-9 C7H6ClI
1-CHLORO-2-METHYLBUTANE 1-CHLORO-2-METHYLBUTANE 616-13-7 C5H11Cl
(4-IODOPHENYLETHYNYL)TRIMETHYLSILANE (4-IODOPHENYLETHYNYL)TRIMETHYLSILANE 134856-58-9 C11H13ISi
BENZAL BROMIDE BENZAL BROMIDE 618-31-5 C7H6Br2
2,6-DICHLORO-OMEGA-NITROSTYRENE 2,6-DICHLORO-OMEGA-NITROSTYRENE 22482-43-5 C8H5Cl2NO2
2,2'-DIBROMO-1,1'-BINAPHTHYL 2,2'-DIBROMO-1,1'-BINAPHTHYL 74866-28-7 C20H12Br2
1,4-DIIODOOCTAFLUOROBUTANE 1,4-DIIODOOCTAFLUOROBUTANE 375-50-8 C4F8I2
1-ETHYL-4-IODOBENZENE 1-ETHYL-4-IODOBENZENE 25309-64-2 C8H9I
(3-CHLOROPROPYL)TRIMETHYLSILANE (3-CHLOROPROPYL)TRIMETHYLSILANE 2344-83-4 C6H15ClSi
(2-BROMOPHENYLETHYNYL)TRIMETHYLSILANE (2-BROMOPHENYLETHYNYL)TRIMETHYLSILANE 38274-16-7 C11H13BrSi
1-ETHYNYL-2.4-DIFLUOROBENZENE  97 1-ETHYNYL-2.4-DIFLUOROBENZENE 97 302912-34-1 C8H4F2
3-CHLORO-2-FLUOROIODOBENZENE 3-CHLORO-2-FLUOROIODOBENZENE 72373-82-1 C6H3ClFI
1,11-DIBROMOUNDECANE 1,11-DIBROMOUNDECANE 16696-65-4 C11H22Br2
1-CHLORO-4-IODOBUTANE 1-CHLORO-4-IODOBUTANE 10297-05-9 C4H8ClI
Dichloroethane Dichloroethane 1300-21-6 C2H4Cl2
4-BROMO-3-IODOTOLUENE 4-BROMO-3-IODOTOLUENE 858841-53-9 C7H6BrI
3-BROMO-1,1,1-TRICHLOROPROPANE 3-BROMO-1,1,1-TRICHLOROPROPANE 13749-37-6 C3H4BrCl3
1-CHLORO-2-OCTYNE 1-CHLORO-2-OCTYNE 51575-83-8 C8H13Cl
1,2-DICHLOROBUTANE 1,2-DICHLOROBUTANE 616-21-7 C4H8Cl2
3-Bromo-3-buten-1-ol 3-Bromo-3-buten-1-ol 76334-36-6 C4H7BrO
11-BROMO-1-UNDECENE 11-BROMO-1-UNDECENE 7766-50-9 C11H21Br
2-METHYL-4-(TRIFLUOROMETHOXY)IODOBENZENE 2-METHYL-4-(TRIFLUOROMETHOXY)IODOBENZENE 886763-05-9 C8H6F3IO
2-BROMONONANE 2-BROMONONANE 2216-35-5 C9H19Br
1,3-Difluoro-5-iodobenzene 1,3-Difluoro-5-iodobenzene 2265-91-0 C6H3F2I
Perfluorobutyl iodide Perfluorobutyl iodide 423-39-2 C4F9I
TRIMETHYL(PENTAFLUOROPHENYL)SILANE TRIMETHYL(PENTAFLUOROPHENYL)SILANE 1206-46-8 C9H9F5Si
3,5-DI-TERT-BUTYLBENZYL BROMIDE 3,5-DI-TERT-BUTYLBENZYL BROMIDE 62938-08-3 C15H23Br
Chloromethane Chloromethane 74-87-3 CH3Cl
2,4-DIBROMOMESITYLENE 2,4-DIBROMOMESITYLENE 6942-99-0 C9H10Br2
6-Chlorohex-1-ene 6-Chlorohex-1-ene 928-89-2 C6H11Cl
1,3-DIBROMO-1-PROPENE 1,3-DIBROMO-1-PROPENE 627-15-6 C3H4Br2
1,3,5-Trichloro-2,4,6-trifluorobenzene 1,3,5-Trichloro-2,4,6-trifluorobenzene 319-88-0 C6Cl3F3
Chloropentafluorobenzene Chloropentafluorobenzene 344-07-0 C6ClF5
1,2,3,4-Tetrachlorobenzene 1,2,3,4-Tetrachlorobenzene 634-66-2 C6H2Cl4
TRANS-3-CHLORO-BETA-NITROSTYRENE TRANS-3-CHLORO-BETA-NITROSTYRENE 37888-03-2 C8H6ClNO2
1,2-DIBROMOETHYLENE 1,2-DIBROMOETHYLENE 540-49-8 C2H2Br2
1,2-DIBROMO-1,2-DIPHENYLETHANE 1,2-DIBROMO-1,2-DIPHENYLETHANE 13440-24-9 C14H12Br2
2,4-DIBROMOPENTANE 2,4-DIBROMOPENTANE 19398-53-9 C5H10Br2
9-IODOPHENANTHRENE 9-IODOPHENANTHRENE 17024-12-3 C14H9I
4,4'-DIMETHOXYOCTAFLUOROBIPHENYL 4,4'-DIMETHOXYOCTAFLUOROBIPHENYL 2200-71-7 C14H6F8O2
1-BROMO-2,3,5,6-TETRAMETHYLBENZENE 1-BROMO-2,3,5,6-TETRAMETHYLBENZENE 1646-53-3 C10H13Br
9,10-DICHLOROANTHRACENE 9,10-DICHLOROANTHRACENE 605-48-1 C14H8Cl2
HEXACHLOROBENZENE HEXACHLOROBENZENE 118-74-1 C6Cl6
CIS-4-CHLORO-2-BUTENYLAMINE HYDROCHLORIDE CIS-4-CHLORO-2-BUTENYLAMINE HYDROCHLORIDE 7153-66-4 C4H9Cl2N
3-(CHLOROMETHYL)PENTANE 3-(CHLOROMETHYL)PENTANE 4737-41-1 C6H13Cl
1,1,2-TRIBROMOETHANE 1,1,2-TRIBROMOETHANE 78-74-0 C2H3Br3
1-CHLORO-4-PHENYLBUTANE 1-CHLORO-4-PHENYLBUTANE 4830-93-7 C10H13Cl
1-BROMO-2-METHYLNAPHTHALENE 1-BROMO-2-METHYLNAPHTHALENE 6627-78-7 C11H9Br
ALPHA-HCH ALPHA-HCH 319-84-6 C6H6Cl6
2-BROMODODECANE 2-BROMODODECANE 13187-99-0 C12H25Br
1 2-DIBROMO-4-TERT-BUTYLBENZENE  97 1 2-DIBROMO-4-TERT-BUTYLBENZENE 97 6683-75-6 C10H12Br2
1-BROMO-4-FLUOROBUTANE 1-BROMO-4-FLUOROBUTANE 462-72-6 C4H8BrF
2-Bromo-5-(trifluoromethoxy)toluene 2-Bromo-5-(trifluoromethoxy)toluene 261951-96-6 C8H6BrF3O
1,2-Dibromotetrafluoroethane 1,2-Dibromotetrafluoroethane 124-73-2 C2Br2F4
2-BROMOPHENETOLE 2-BROMOPHENETOLE 583-19-7 C8H9BrO
3,4-DICHLORO-1-BUTENE 3,4-DICHLORO-1-BUTENE 760-23-6 C4H6Cl2
2,6-DICHLORO-OMEGA-NITROSTYRENE 2,6-DICHLORO-OMEGA-NITROSTYRENE 120355-50-2 C8H5Cl2NO2
1-IODO-2-METHYLBUTANE 1-IODO-2-METHYLBUTANE 616-14-8 C5H11I
PENTAERYTHRITYL TETRABROMIDE PENTAERYTHRITYL TETRABROMIDE 623-97-2 C5H8Cl2O3
Difluorochloromethane Difluorochloromethane 75-45-6 CHClF2
VINYL(CHLOROMETHYL)DIMETHYLSILANE VINYL(CHLOROMETHYL)DIMETHYLSILANE 16709-86-7 C5H11ClSi
1,2-Dibromotetrafluorobenzene 1,2-Dibromotetrafluorobenzene 827-08-7 C6Br2F4
1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE 1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE 3975-77-7 C18H29Br
4-ETHYNYL-1-FLUORO-2-METHYLBENZENE  97 4-ETHYNYL-1-FLUORO-2-METHYLBENZENE 97 351002-93-2 C9H7F
4-ISOPROPYL BENZYL BROMIDE  97 4-ISOPROPYL BENZYL BROMIDE 97 73789-86-3 C10H13Br
2-CHLOROPHENETHYL BROMIDE 2-CHLOROPHENETHYL BROMIDE 16793-91-2 C8H8BrCl
2-IODOOCTANE 2-IODOOCTANE 629-27-6 C8H17I
PENTACHLOROBENZENE PENTACHLOROBENZENE 608-93-5 C6HCl5
1,5-Diiodopentane 1,5-Diiodopentane 628-77-3 C5H10I2
2,4-DICHLORO-OMEGA-NITROSTYRENE 2,4-DICHLORO-OMEGA-NITROSTYRENE 18984-21-9 C8H5Cl2NO2
1-Ethyl-3,5-difluorobenzene 1-Ethyl-3,5-difluorobenzene 117358-52-8 C8H8F2
1,8-BIS(BROMOMETHYL)NAPHTHALENE 1,8-BIS(BROMOMETHYL)NAPHTHALENE 2025-95-8 C12H10Br2
1-CHLOROANTHRACENE 1-CHLOROANTHRACENE 4985-70-0 C14H9Cl
3,4-Dichlorobenzotrichloride 3,4-Dichlorobenzotrichloride 13014-24-9 C7H3Cl5
1-Bromoicosane 1-Bromoicosane 4276-49-7 C20H41Br
4-FLUORO-3-IODOTOLUENE 4-FLUORO-3-IODOTOLUENE 452-82-4 C7H6FI
2-Bromoresorcinol 2-Bromoresorcinol 6751-75-3 C6H5BrO2
2-(BROMOVINYL)TRIMETHYLSILANE 2-(BROMOVINYL)TRIMETHYLSILANE 41309-43-7 C5H11BrSi
PERFLUORONONANE PERFLUORONONANE 375-96-2 C9F20
1-Iodononane 1-Iodononane 4282-42-2 C9H19I
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