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| 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Basic information |
| 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Chemical Properties |
Melting point | <0°C | Boiling point | 44-45 °C2 mm Hg(lit.) | density | 1.17 g/mL at 25 °C(lit.) | refractive index | n20/D 1.483(lit.) | Fp | 145 °F | storage temp. | 2-8°C | solubility | Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly) | form | Oil | color | Colourless to Pale Yellow | Specific Gravity | 1.351 | Water Solubility | Immiscible with water. | Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions | BRN | 2037650 | Stability: | Hygroscopic | InChIKey | GAPRPFRDVCCCHR-UHFFFAOYSA-N | CAS DataBase Reference | 38002-45-8(CAS DataBase Reference) |
| 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Usage And Synthesis |
Chemical Properties | Clear colorless to pale yellow liquid | Uses | 3-Bromo-1-(trimethylsilyl)-1-propyne may be used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It may be used as reagent for the alkylation of dianion of β-keto esters at γ-carbon. It may be employed in the preparation of terminal conjugated enynes and allenic alcohols. | General Description | 3-Bromo-1-(trimethylsilyl)-1-propyne is reported as a propargylating agent. Selective reaction of 3-bromo-1-(trimethylsilyl)-1-propyne with α-keto ester using indium metal has been studied. |
| 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Preparation Products And Raw materials |
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