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Terephthalaldehyde

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CAS:623-27-8
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Products Intro: Product Name:Terephthalaldehyde
CAS:623-27-8
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Terephthalaldehyde Basic information
Product Name:Terephthalaldehyde
Synonyms:TEREPHTHALDIALDEHYDE;TEREPHTHALALDEHYDE;P-PHTHALICDICARBOXALDEHYDE;p-Benzenedialdehyde;p-Benzenedicarboxaldehyde;p-Formylbenzaldehyde;p-Phthaldialdehyde;terephtaldehydes
CAS:623-27-8
MF:C8H6O2
MW:134.13
EINECS:210-784-8
Product Categories:Aromatics;Fluorenes, etc. (reagent for high-performance polymer research);Functional Materials;Reagent for High-Performance Polymer Research;Aromatic Aldehydes & Derivatives (substituted);Miscellaneous Reagents;Pyridines;intermediates;bc0001
Mol File:623-27-8.mol
Terephthalaldehyde Structure
Terephthalaldehyde Chemical Properties
Melting point 114-116 °C (lit.)
Boiling point 245-248 °C (lit.)
density 1,06 g/cm3
vapor pressure 0.25-0.46Pa at 20-25℃
refractive index 1.4800 (estimate)
Fp 76 °C
storage temp. Store below +30°C.
solubility 3g/l
form Crystalline Powder
color White to light yellow
Water Solubility 3 g/L (50 ºC)
Sensitive Air Sensitive
BRN 385863
InChIKeyKUCOHFSKRZZVRO-UHFFFAOYSA-N
LogP1 at 20.1℃ and pH6.6-6.8
CAS DataBase Reference623-27-8(CAS DataBase Reference)
NIST Chemistry Reference1,4-Benzenedicarboxaldehyde(623-27-8)
EPA Substance Registry System1,4-Benzenedicarboxaldehyde (623-27-8)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-36/37
Safety Statements 22-24/25-36-26-37/39
WGK Germany 1
RTECS WZ0430000
Hazard Note Irritant
TSCA Yes
HS Code 29122900
Hazardous Substances Data623-27-8(Hazardous Substances Data)
MSDS Information
ProviderLanguage
1,4-Phthalaldehyde English
SigmaAldrich English
ACROS English
ALFA English
Terephthalaldehyde Usage And Synthesis
DescriptionTerephthalaldehyde is an aromatic dialdehyde. Theoretically, the two aldehydes of terephthalaldehyde (TPA) are equivalent, so the single or double Schiff base from TPA and d-glucosamine (Glc) may be formed at the same time. It is used as an intermediate for the preparation of dyes and fluorescent whitening agents and in the synthesis of polyimines by reacting with aliphatic diamines. It is also used as a precursor for the preparation of paramagnetic microporous polymeric organic frameworks (POFs) through copolymerization with pyrrole, indole, and carbazole. As a good crosslinking agent, it could used in crosslinked chitosan hydrogel for the selective removal of anionic dyes[1].
Chemical PropertiesWHITE TO LIGHT YELLOW CRYSTALLINE POWDER
UsesTerephthalaldehyde (cas# 623-27-8) is a compound useful in organic synthesis.
Synthesis Reference(s)Organic Syntheses, Coll. Vol. 3, p. 788, 1955
Tetrahedron Letters, 36, p. 2285, 1995 DOI: 10.1016/0040-4039(95)00191-E
Purification MethodsTerephthalaldehyde [623-27-8] M 134.1, m 116o, b 245 -248o/771mm. Crystallise terephthalaldehyde from water. [Beilstein 7 IV 2140.]
References[1] Weng Q, et al. Controllable Synthesis and Biological Application of Schiff Bases from d-Glucosamine and Terephthalaldehyde. ACS Omega, 2020; 5: 24864–24870.
Tag:Terephthalaldehyde(623-27-8) Related Product Information
Terephthalic acid 4-Hydroxybenzaldehyde p-Anisaldehyde mono-Methyl terephthalate Terephthaloyl chloride 1,4-Dimethoxybenzene 1,4-Dicyanobenzene Dioctyl terephthalate Pyromellitic acid Trimellitic Anhydride 3,3',4,4'-Benzophenonetetracarboxylic dianhydride 1,2,4-Benzenetricarboxylic acid Pyromellitic Dianhydride 2-Bromoterephthalic acid MELLITIC ACID 4-Acetylbenzoic acid ANTHRAQUINONE-2-CARBOXYLIC ACID o-Phthalaldehyde

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