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(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate

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Products Intro: Product Name:(-)-1,2-bis((2r,5r)-dimethylphospholano)benzene(cyclooctadiene)rhodium(i) tetrafluoroborate
CAS:210057-23-1
Purity:99% Package:1kg
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Products Intro: Product Name:(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:210057-23-1
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Products Intro: Product Name:(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:210057-23-1
Purity:95% Package:$99.9/100mg;$267.9/250mg;$427.9/500mg;$999.9/1g;$1539.9/2g;Bulk package Remarks:95%
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Products Intro: Product Name:(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:210057-23-1
(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Basic information
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Product Name:(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate
Synonyms:(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (R,R)-Me-DUPHOS-Rh;(-)-1,2-Bis[(2R,5R)-2,5-diMethylphospholano]benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate;Bisdimethylphospholanobenzenecyclooctadienerho;1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO&;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(R,R)-Me-DUPHOS-Rh;(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate;(-)-1,2-Bis((2R,5R)-2,5-diMethylphospholano)benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (R,R)-Me-DUPHOS-Rh
CAS:210057-23-1
MF:C26H40BF4P2Rh4*
MW:604.25
EINECS:
Product Categories:Chiral Catalysts, Ligands, and Reagents;DuPhos/BPE;Privileged Ligands and Complexes;organometallic complex
Mol File:210057-23-1.mol
(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Structure
(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties
form crystal
color red-orange
Water Solubility insoluble
Sensitive air sensitive
CAS DataBase Reference210057-23-1(CAS DataBase Reference)
Safety Information
Risk Statements 36/37/38
Safety Statements 24/25
WGK Germany 3
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Usage And Synthesis
Reactions
  1. The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
  2. Forms superior catalysts for asymmetric reductive aminations.
  3. Catalyst used for the asymmetric hydrogenation of enol phosphonates.
  4. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
  5. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
  6. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
  7. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
  8. Palladium catalyzed asymmetric phosphination.
Reactions of 210057-23-1_1
Reactions of 210057-23-1_2
Chemical Propertiesred or red-brown crystalline powder
UsesDuPhos and BPE Ligands: Highly Efficient Privileged Ligands
(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials
Tag:(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate(210057-23-1) Related Product Information
Xylene Benzene 1,3-CYCLOOCTADIENE Rhodium (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE 1,2-BIS(PHOSPHINO)BENZENE (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene,98+%(S,S)-Me-DUPHOS,(+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE,(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane,98+%(R,R)-Me-BPE (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (R,R,R,R)-2,3-BIS(2,5-DIMETHYL-PHOSPHOLANYL)BENZO[B]THIOPHENE CYCLOOCTADIENE RHODIUM(I) TETRAFLUOROBORATE COMPLEX 2,3-Bis[(2R,5R)-2,5-dimethylphospholano]-N-(3,5-dimethylphenyl)maleimide 2,3-Bis[(2R,5R)-2,5-dimethylphospholano]-N-benzylmaleimide(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate (-)-2,3-Bis[(2R,5R)-2,5-dimethylphospholano]maleic anhydride(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]-3,3,4,4-tetrafluoro-1-cyclobutene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate