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Di(trimethylol propane)

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CAS:23235-61-2
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  • 2023-12-29
  • CAS:23235-61-2
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  • 2023-10-09
  • CAS:23235-61-2
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Di(trimethylol propane) Basic information
Product Name:Di(trimethylol propane)
Synonyms:2,2'-OXYBIS(METHYLENE)BIS(2-ETHYL-1,3-PROPANEDIOL);2,2’-[oxybis(methylene)]bis[2-ethyl-3-propanediol;3-Propanediol,2,2’-[oxybis(methylene)]bis[2-ethyl-1;Ditrimethylol;1,3-Propanediol, 2,2-oxybis(methylene)bis2-ethyl-;Perstorp Di-Trimethylolpropane;Bis[2,2-di(hydroxymethyl)butyl] ether;Einecs 245-509-0
CAS:23235-61-2
MF:C12H26O5
MW:250.33
EINECS:245-509-0
Product Categories:
Mol File:23235-61-2.mol
Di(trimethylol propane) Structure
Di(trimethylol propane) Chemical Properties
Melting point 108-111 °C(lit.)
Boiling point 215 °C4 mm Hg(lit.)
density 1.0187 (rough estimate)
vapor pressure 0Pa at 25℃
refractive index 1.4560 (estimate)
solubility soluble in Methanol
form powder to crystal
pka13.90±0.10(Predicted)
color White to Almost white
Water Solubility 21g/L at 20℃
BRN 1860782
LogP0.88 at 25℃
EPA Substance Registry System1,3-Propanediol, 2,2'-[oxybis(methylene)]bis[2-ethyl- (23235-61-2)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 29094990
MSDS Information
ProviderLanguage
SigmaAldrich English
Di(trimethylol propane) Usage And Synthesis
DescriptionDi(trimethylol propane), Di-TMP, 2,2-[oxybis(methylene)]-bis(2-ethyl)-1,3-propanediol is a colorless and crystalline substance (mp 112 – 114 ℃), only slightly soluble in water at ambient temperature (2.6 g/100 g at 25 ℃).It is a byproduct of 2-ethyl-2-hydroxymethyl-1,3-propanediol (TMP) production and can be isolated from the residue of the TMP distillation step. Newer investigations show that ditrimethylolpropane can be prepared in high yield and selectivity by the reaction of TMP, formaldehyde, and 2-ethylacrolein.
UsesDi(trimethylolpropane) can be used for the synthesis of lipase catalyzed hyperbranched polymers. It can also be used in the formation of biodegradable polymers for drug delivery applications.
ApplicationDi-trimethylolpropane is mainly used for production of acrylic monomers and oligomers for radiation-curable coatings and inks, including lithography, ink jet, and flexography inks. Di-TMP tetraacrylate has a very high reactivity, low skin irritation, and gives coatings with good scratch and chemical resistance, hence it also find uses in hard coats for electronics. Di-TMP is used as costabilizer in some lead-free PVC stabilizers based on calcium – zinc. Minor uses are in coating resins and synthetic lubricants.
Synthesis Reference(s)Canadian Journal of Chemistry, 53, p. 1103, 1975 DOI: 10.1139/v75-154
General DescriptionDi(trimethylolpropane) is a monomeric unit with primary hydroxyl groups, that can be used as a tetrafunctional core molecule.
Flammability and ExplosibilityNot classified
Di(trimethylol propane) Preparation Products And Raw materials
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