(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03

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Products Intro: Product Name:(2,4-pentadienyl)trimethylsilane
CAS:72952-73-9
Purity:98% HPLC Package:5G;10G;25G;50G;100G;250G;1KG
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Products Intro: Product Name:trimethyl(penta-2,4-dienyl)silane
CAS:72952-73-9
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Products Intro: Product Name:(2,4-Pentadienyl)trimethylsilane
CAS:72952-73-9
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Products Intro: Product Name:(2,4-Pentadienyl)Trimethylsilane
CAS:72952-73-9
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Products Intro: Product Name:(2,4-Pentadienyl)trimethylsilane
CAS:72952-73-9
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Basic information
Product Name:(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03
Synonyms:(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03;Pentadienyltrimethylsilane;5-(Trimethylsilyl)-1,3-pentadiene;Silane, trimethyl(2E)-2,4-pentadien-1-yl-;trimethyl(penta-2,4-dienyl)silane
CAS:72952-73-9
MF:C8H16Si
MW:140.3
EINECS:
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Mol File:72952-73-9.mol
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC  06/13/03 Structure
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Chemical Properties
Boiling point 127°C
density 0.758±0.06 g/cm3(Predicted)
Fp 18°C
solubility sol hexane, benzene, CH2Cl2, ether, THF.
Safety Information
Risk Statements 11-36/37/38
Safety Statements 16-26-36
RIDADR 1993
MSDS Information
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Usage And Synthesis
Physical propertiesbp 41 °C/36 mmHg or 105 °C/760 mmHg; n20/ D 1.4570.
Uses5-Trimethylsilyl-1,3-pentadiene is a useful pentadienylation reagent; an allyl silane; a precursor for 1-trimethylsilyldienes and intramolecular Diels–Alder substrates).
Preparation5-Trimethylsilyl-1,3-pentadiene may be prepared in 85% yield by the reaction of pentadienyllithium with chlorotrimethylsilane in THF at room temperature.1–3 Generally the product is ≈95% (E) isomer as judged by IR (strong band at 1000 cm?1) or NMR(trans coupling constant of 15.2 Hz for proton at C-3, 5.92 ppm).
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Preparation Products And Raw materials
Tag:(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03(72952-73-9) Related Product Information
Clotrimazole ALLYLDIMETHYLSILANE Allyltrimethylsilane (2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03