ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic manganese >(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOH

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Suppliers list
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 86-18871470254
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Products Intro: Product Name:(R,R)-(-)-N,N-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
CAS:138124-32-0
Purity:0.99 Package:5KG;1KG
Company Name: Accela ChemBio Inc.
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Products Intro: Product Name:(R,R)-(-)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride
CAS:138124-32-0
Purity:95% Package:5g Remarks:SY007841
Company Name: Chongqing Chemdad Co.,Ltd
Tel: +86-19923101450
Email: sales@chemdad.com
Products Intro: Product Name:(R,R)-(-)-N N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine-Manganese(Iii) Chloride
CAS:138124-32-0
Package:1KG,2KG,5KG,10KG,25KG, As U request
Company Name: Chongqing Chemdad Co., Ltd
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Products Intro: Product Name:(R,R)-(-)-N,N-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
CAS:138124-32-0
Package:1KG,2KG,5KG,10KG,25KG, As U request
Company Name: Alchem Pharmtech,Inc.
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Products Intro: Product Name:(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylid ene)-1,2-cyclohexanediamino-manganese(I)chloride
CAS:138124-32-0
Purity:97+% Package:1g;10g;100g;;1kg Remarks:Z-51813
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Basic information
Product Name:(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
Synonyms:(R,R)-(-)-N,N'-BIS(3.5-DI-T-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE-MANGANESE (III) CHLORIDE;(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE;(R,R)-JACOBSEN CATALYST;(R,R)-JACOBSEN'S CATALYST;(R,R)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX;(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE(III)CHLORIDE;JACOBSEN'S CATALYST;(-)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO-
CAS:138124-32-0
MF:C36H52ClMnN2O2
MW:635.2
EINECS:
Product Categories:Jacobsen Metal;Other Metal;Chiral Reagents
Mol File:138124-32-0.mol
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Structure
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Chemical Properties
Melting point 330-332 °C(lit.)
alpha D23 +580° (c = 0.01 in ethanol)
storage temp. Inert atmosphere,2-8°C
form Liquid May Develop Some Turbidity or Precipitate
color Light yellow to gold to brown
λmax509nm(CH2Cl2)(lit.)
Merck 14,5252
InChIKeyLJVAWOSDJSQANR-OHRASPNLSA-K
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36-36/37/39
WGK Germany 3
9
HS Code 29349990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Usage And Synthesis
Chemical Properties(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE is Dark brown powder or chunks
Uses(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE is a coordinated compound of manganese and a salen-type ligand. It is also used as an asymmetric catalyst used to enantioselectively transform prochiral alkenes into epoxides.
UsesChiral catalyst for epoxidation of olefins.
Reactions
  1. Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
  2. Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
  3. symmetric Kinetic resolution of secondary alcohols in water.
  4. Enantioselective Reformatsky reaction with ketones.
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Preparation Products And Raw materials
Tag:(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE(138124-32-0) Related Product Information
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE Manganese chloride tetrahydrate Manganese (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE HYDROCHLORIDE CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE N-benzylidenecyclohexylamine N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE