Company Name: |
Shaanxi Dideu Newmaterial Co., Ltd.
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Tel: |
029-87576359 15353716720 |
Email: |
1039@dideu.com |
Products Intro: |
Product Name:disodium tetracarbonylferrate(2-) CAS:14878-31-0 Purity:99% Package:25KG
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Company Name: |
yaoyangpharm
|
Tel: |
17739007752 17324281842 |
Email: |
m1773900775@163.com |
Products Intro: |
CAS:14878-31-0
|
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| disodium tetracarbonylferrate(2-) Basic information |
| disodium tetracarbonylferrate(2-) Chemical Properties |
solubility | sol THF, DMF, N-methylpyrrolidone (NMP), EtOH. | form | solid | color | colorless to red |
| disodium tetracarbonylferrate(2-) Usage And Synthesis |
Uses | Disodium Tetracarbonylferrate(-II) is used as a carbonylating agent for halides, producing aldehydes and ketones; hydroacylates Michael acceptors; forms
cyclic ketones from β- and γ-haloalkenes; selectively reduces unsaturations α to a carbonyl; catalyst for
dismutation of aromatic aldehydes to esters; produces [(η4-diene)Fe(CO)3] complexes via nucleophilic
displacement. | storage | Disodium Tetracarbonylferrate(-II) (Na2Fe(CO)4) is very air sensitive and is pyrophoric. The solid is stable
over moderately long periods of time under inert atmosphere at rt, if kept in the dark. The potassium salt is
also air sensitive but is not pyrophoric. These materials are best stored and handled in a nitrogen or argon
filled dry box. Tetracarbonylferrate is considered to be a neural, renal, and hepatic toxin and is a cancer
suspect agent. |
| disodium tetracarbonylferrate(2-) Preparation Products And Raw materials |
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