(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine

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Company Name: Hebei Chuanghai Biotechnology Co., Ltd
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Products Intro: Product Name:(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine
CAS:68737-65-5
Purity:99% Package:1KG;0.00;USD|25KG;0.00;USD
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Products Intro: Product Name:(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine
CAS:68737-65-5
Purity:99% Package:25KG
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Products Intro: Product Name:(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine
CAS:68737-65-5
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Products Intro: Product Name:(R,R)-(-)-N,N'-Dimethyl-1,2-cyclohexanediamine
CAS:68737-65-5
Purity:98%(Min,HPLC) Package:1G;1KG;100KG
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
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Products Intro: Product Name:(1R,2R)-(-)-N,N'-Dimethyl-1,2-cyclohexanediamine
CAS:68737-65-5
Purity:99% Package:1KG,5KG,10KG

(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine manufacturers

(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine Basic information
Product Name:(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine
Synonyms:(1R,2R)-(-)-1,2-BIS(METHYLAMINO)CYCLOHEXANE;(1R,2R)-1,2-BIS(METHYLAMINO)CYCLOHEXANE;(1R,2R)-(-)-N,N'-DIMETHYLCYCLOHEXANE-1,2-DIAMINE;trans-1,2-Bis(methylamino)cyclohexane, (R,R)-(-)-N,Nμ-Dimethyl-1,2-diaminocyclohexane;(R,R)-(-)-N,N'-Dimethyl-1,2-cyclohexandiamine;(R,R)-1,2-Bis(methylamino)cyclohexane.;N,N'-Dimethyl-cyclohexane-1,2-diamine;trans-(1R,2R)-N,N'-Bismethyl-1,2-cyclohexane
CAS:68737-65-5
MF:C8H18N2
MW:142.24
EINECS:
Product Categories:Chiral Building Blocks;e.e. / Absolute Configuration Determination (NMR);Enantiomer Excess & Absolute Configuration Determination;Synthetic Organic Chemistry;Amines and Anilines;Amines (Chiral);Analytical Chemistry;chiral;Chiral Nitrogen;DACH&Trost Series
Mol File:68737-65-5.mol
(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine Structure
(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine Chemical Properties
Melting point 39-44 °C
alpha -145 º (c=4.47 in chloroform)
Boiling point 249.85°C (rough estimate)
density 0.902
refractive index -140 ° (C=4, CHCl3)
Fp 74 °C
storage temp. 2-8°C
pka11.04±0.40(Predicted)
form Low Melting Solid
color White to light yellow
Optical Rotation[α]/D -145±5°, c = 4.47 in chloroform
InChIInChI=1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m1/s1
InChIKeyJRHPOFJADXHYBR-HTQZYQBOSA-N
SMILES[C@@H]1(NC)CCCC[C@H]1NC
CAS DataBase Reference68737-65-5(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34-22
Safety Statements 45-36/37/39-25-26
RIDADR 3259
WGK Germany 3
HazardClass 8
PackingGroup 
HS Code 29213000
MSDS Information
ProviderLanguage
ACROS English
(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses(R,R)-(?)-N,N′-Dimethyl-1,2-cyclohexanediamine can be used:
  • As a ligand in the preparation of 4H-benzo[f]imidazo[1,4]diazepin-6-one through multi-component Ullmann coupling reaction.
  • In one of the key synthetic steps for the preparation of tricyclic γ-secretase modulators.
  • To prepare chiral fluorous diamino-diol proligand, which is used in the synthesis of zirconium metal complexes applicable as catalysts in 1-hexene polymerization.

General Description(R,R)-(-)-N,N′-Dimethyl-1,2-cyclohexanediamine is a N,N′-dimethylated derivative of enantiopure 1,2-diaminocyclohexane. It can be formed during the hydrolysis of (R3a,R7a)-1,3-(dimethyl)-2-phenyl-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3,2-benzodiazaphosphole 2-oxide using HCl-methanol.
(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine Preparation Products And Raw materials
Tag:(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine(68737-65-5) Related Product Information
Dimethyl ether 1,2-Diaminocyclohexane (+/-)-trans-1,2-Diaminocyclohexane Dimethyl phthalate N,N-Dimethylformamide Dimethyl fumarate Dimethyl sebacate Dimethyl sulfoxide 1,2-Cyclohexanedione 1,2-Cyclohexylenedinitrilotetraacetic acid Hexamethylenediamine Dimethyl carbonate ETHANE trans-1,4-Diaminocyclohexane N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine,(S,S)-(+)-N,Nμ-Dimethyl-1,2-cyclohexanediamine CDTA (+)-U-50488 HYDROCHLORIDE

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