- 2-BROMOBENZAMIDE
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- $0.00 / 25kg
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2025-07-25
- CAS:4001-73-4
- Min. Order: 1kg
- Purity: 99%
- Supply Ability: 10000KGS
- 2-BROMOBENZAMIDE
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- $1.00 / 1KG
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2024-07-26
- CAS:4001-73-4
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 100000KG
- 2-BROMOBENZAMIDE
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- $3.00 / 1KG
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2020-02-02
- CAS:4001-73-4
- Min. Order: 1KG
- Purity: 98%
- Supply Ability: 100KG
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| | 2-BROMOBENZAMIDE Basic information |
| | 2-BROMOBENZAMIDE Chemical Properties |
| Melting point | 160-162 °C (lit.) | | Boiling point | 158-161 °C(Press: 12 Torr) | | density | 1.5488 (rough estimate) | | refractive index | 1.5500 (estimate) | | storage temp. | Sealed in dry,Room Temperature | | pka | 15.36±0.50(Predicted) | | form | Powder | | color | Beige | | Water Solubility | Slightly soluble in water. | | CAS DataBase Reference | 4001-73-4(CAS DataBase Reference) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | WGK Germany | 3 | | HS Code | 29242990 |
| | 2-BROMOBENZAMIDE Usage And Synthesis |
| Chemical Properties | Beige powder | | Uses | 2-Bromobenzamide has been used in:
- microwave assisted one-pot synthesis of substituted 3-(phenylmethylene)isoindolin-1-ones
- palladium-catalyzed synthesis of phenanthridinones
- synthesis of new water-soluble iminophosphorane ligand
| | Uses | 2-Bromobenzamide has been used in microwave assisted one-pot synthesis of substituted 3-(phenylmethylene)isoindolin-1-ones, palladium-catalyzed synthesis of phenanthridinones and in the synthesis of new water-soluble iminophosphorane ligand. | | Synthesis | General procedure for the synthesis of 2-bromobenzamide from 2-bromobenzaldehyde oxime: In a 25 mL Schlenk reaction flask, 2-bromobenzaldehyde oxime (100 mg, 0.5 mmol) and water (1 mL) were added sequentially. Subsequently, [Cp*Ir(H2O)3][OTf] catalyst was added. The reaction mixture was stirred at 110 °C for 12 h and then cooled to room temperature. Water was removed by rotary evaporation and the product was purified by column chromatography. Yield: 80%. Product characterization data: 1H NMR (500 MHz, DMSO-d6) δ 7.88 (br s, 1H, NH2), 7.64-7.58 (m, 2H, ArH), 7.41-7.34 (m, 2H, ArH); 13C NMR (125 MHz, DMSO-d6) δ 169.0, 139.3, 132.7, 130.6, 128.5, 127.5, 118.6. | | References | [1] RSC Advances, 2016, vol. 6, # 43, p. 37093 - 37098
[2] Advanced Synthesis and Catalysis, 2009, vol. 351, # 11-12, p. 1807 - 1812
[3] Catalysis Science and Technology, 2014, vol. 4, # 4, p. 988 - 996
[4] Patent: CN104418682, 2016, B. Location in patent: Paragraph 0070-0074
[5] Catalysis Communications, 2015, vol. 60, p. 120 - 123 |
| | 2-BROMOBENZAMIDE Preparation Products And Raw materials |
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