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| (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Basic information | Reaction |
Product Name: | (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE | Synonyms: | (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine;Ferrocene,1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)-,(2R)-;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%;(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] ethyldi-t-butylphosphine, min. 97%;(R,R)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-(DICYCLOHEXYLPHOSPHINO)FERROCENE;(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine,min.97% | CAS: | 158923-11-6 | MF: | C32H52FeP2 10* | MW: | 554.55 | EINECS: | 238-086-9 | Product Categories: | organophosphine ligand;Chiral Phosphine;Ferrocene Series;Josiphos Series | Mol File: | 158923-11-6.mol | |
| (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Chemical Properties |
Melting point | 118-120oC | alpha | -185° ±10° (c 0.5, CHCl3) | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | solubility | Chloroform (Slightly), Methanol (Very Slightly) | form | Powder | color | orange |
Safety Statements | 22-24/25 | WGK Germany | 3 | HS Code | 29319090 |
| (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Usage And Synthesis |
Reaction |
- Ligand for Palladium-catalyzed C-N cross-coupling.
- Ligand for Palladium-catalyzed C-S cross-coupling.
- Ligand for Palladium-catalyzed Kumada couplings of aryl and vinyl tosylates.
- Ligand for Rhodium-catalyzed hydroacylation of cyclopropenes, an enatioselective desymmetrization method.
- Ligand for Palladium-catalyzed C-O cross-coupling.
- Ligand for Rhodium-catalyzed coupling of imidazole derivatives with terminal allenes.
- Ligand for Ruthenium-catalyzed C-C coupling of alkynes and alcohols to form branched products of carbonyl allylation
| Chemical Properties | Orange powder | Uses | It may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates. | General Description | sold in collaboration with Solvias AG |
| (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Preparation Products And Raw materials |
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