- TRIPHENYLSILANE
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- $0.00 / 1KG
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2024-01-23
- CAS:789-25-3
- Min. Order: 1KG
- Purity: 98.00%
- Supply Ability: 1000KG /month
- Triphenylsilane
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- $2.00 / 1KG
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2019-07-06
- CAS:789-25-3
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: customsie
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| | Triphenylsilane Basic information |
| | Triphenylsilane Chemical Properties |
| Melting point | 43-45 °C (lit.) | | Boiling point | 152 °C/2 mmHg (lit.) | | refractive index | 1.6160 | | Fp | 169 °F | | storage temp. | Inert atmosphere,2-8°C | | solubility | sol most organic solvents. | | form | Powder | | color | off-white | | Water Solubility | REACTS | | Sensitive | Air Sensitive | | Hydrolytic Sensitivity | 3: reacts with aqueous base | | BRN | 978182 | | InChIKey | AKQNYQDSIDKVJZ-UHFFFAOYSA-N | | CAS DataBase Reference | 789-25-3(CAS DataBase Reference) | | NIST Chemistry Reference | Silane, triphenyl-(789-25-3) | | EPA Substance Registry System | Silane, triphenyl- (789-25-3) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37 | | WGK Germany | 1 | | TSCA | Yes | | HS Code | 29310095 |
| | Triphenylsilane Usage And Synthesis |
| Chemical Properties | Triphenylsilane is an off-white solid that is soluble in most organic solvents. It is used in certain cases for the preparation of triphenylsilyl ethers, which serve as alcohol-protecting groups. The triphenylsilyl group is considerably more stable (about 400 times) than the TMS group toward acidic hydrolysis. | | Uses | Triphenylsilane acts as a reactant or reagent for catalytic hydrogen deuterium exchange reactions of silanes, to be oxidized by carbon nanotube-gold nanohybrids, for hydrolysis by ruthenium complexes, for hydrosilylation to produce enolsilanes, for synthesis of bromosilanes, for ozone oxidation of silyl-alkenes for synthesis of α-O-silylated acyloin derivatives. It is used to synthesize hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes. | | Preparation | Triphenylsilane can be synthesized by reducing phenylsilane (PhSiH3) with a reducing agent such as lithium aluminum hydride (LiAlH4). The overall reaction equation is as follows:
3 PhSiH3 + 2 LiAlH4 → C18H16Si + 2 LiH + 2 AlH3
This reaction is typically carried out in anhydrous conditions and under inert gas atmosphere. | | Application | More effective radical-based reagent for reduction of organic halides than the trialkylsilanes.
Compares well with tri-n-butyltin hydride in reduction of enones to ketones.
Shows good selectivity in the reduction of cyclic hemiacetals.
Converts O-acetyl furanoses and pyranoses to deoxy sugars.
Hexaphenyldisiloxane can be conveniently made by the action of aqueous alkali on triphenylsilane, Ph3SiH.
Tristriphenylsilylbismuth, (Ph3Si)3Bi, is made similarly from triethylbismuth and triphenylsilane: Et3Bi+3Ph3SiH==Heat==(Ph3Si)3Bi+3EtH. | | Purification Methods | Purify it by recrystallisation from MeOH. [Gilman & Zuech J Am Chem Soc 81 5925 1959, Westermark Acta Chem Scand 9 947 1955, IR: Kaplan J Am Chem Soc 76 5880 1954, Beilstein 16 II 605, 16 III 1199, 16 IV 1369.] |
| | Triphenylsilane Preparation Products And Raw materials |
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