(-)-O-ACETYL-D-MANDELIC ACID

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Products Intro: Product Name:(R)-(-)-alpha-acetoxyphenylacetic acid
CAS:51019-43-3
Purity:98% (Min,GC) Package:1G;1KG;100KG
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CAS:51019-43-3
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Products Intro: Product Name:(R)-(-)-alpha-Acetoxyphenylacetic Acid
CAS:51019-43-3
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(-)-O-ACETYL-D-MANDELIC ACID Basic information
Product Name:(-)-O-ACETYL-D-MANDELIC ACID
Synonyms:(R)-(-)-ALPHA-ACETOXYPHENYLACETIC ACID;(R)-ALPHA-ACETOXYPHENYLACETIC ACID;(R)-(-)-O-ACETYLMANDELIC ACID;(R)-(+)-O-ACETYLMANDELIC ACID;(-)-O-ACETYL-D-MANDELIC ACID;(-)-O-Acetyl-D-mandelic acid, (R)-(-)-α-Acetoxyphenylacetic acid;(-)-D-Mandelic acid acetate;(R)-α-Acetoxybenzeneacetic acid
CAS:51019-43-3
MF:C10H10O4
MW:194.19
EINECS:610-598-0
Product Categories:Cosmetic;chiral;for Resolution of Alcohols & Thiols;for Resolution of Bases;Optical Resolution;Synthetic Organic Chemistry;Chiral Compound
Mol File:51019-43-3.mol
(-)-O-ACETYL-D-MANDELIC ACID Structure
(-)-O-ACETYL-D-MANDELIC ACID Chemical Properties
Melting point 97-99 °C(lit.)
Boiling point 317.8±30.0 °C(Predicted)
density 1.259±0.06 g/cm3(Predicted)
refractive index -153 ° (C=2, Acetone)
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility Soluble in methanol. (almost transparency)
pka2.76±0.10(Predicted)
form powder to crystal
color White to Almost white
optical activity[α]20/D 152.4°, c = 2 in acetone
BRN 2694110
InChIKeyYCCSWLJUVZBEAS-SECBINFHSA-N
LogP1.780 (est)
CAS DataBase Reference51019-43-3(CAS DataBase Reference)
Safety Information
Risk Statements 36/37/38
Safety Statements 22-24/25-60-37-26
WGK Germany 3
HS Code 29181990
MSDS Information
ProviderLanguage
SigmaAldrich English
(-)-O-ACETYL-D-MANDELIC ACID Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses(R)-(-)-O-Acetylmandelic acid may be used as a precursor to prepare a chiral diamine, which is an intermediate to prepare Utenone A. It may also be used to prepare ethyl (2′R)-2′-acetoxy-2′-phenylethanoate.
UsesThe (R)- and (S)-isomers are chiral derivatizing agents for NMR determination of enantiomeric purity of α-deuterated carboxylic acids, alcohols, and amines.
General Description(R)-(-)-O-Acetylmandelic acid is a chiral derivatizing agent for NMR determination of enantiomeric purity of α-deuterated carboxylic acids, alcohols, and amines.
Purification MethodsIt crystallises from H2Owith 1mol of solvent which is removed on drying, or from other solvents as for the S-iso
(-)-O-ACETYL-D-MANDELIC ACID Preparation Products And Raw materials
Preparation Products(S)-(+)-O-Acetyl-L-mandelic acid
Tag:(-)-O-ACETYL-D-MANDELIC ACID(51019-43-3) Related Product Information
2-HYDROXYETHYL ACETATE ALPHA-METHYLBENZYL ALCOHOL (R)-(-)-1-Phenyl-1,2-ethanediol 1-PHENYL-1,2-ETHANEDIOL Mandelic acid Ethoxyacetic acid (R)-Lactate 2-Formyl-3,4-dihydro-2H-pyran Acetoxyacetic acid (R)-(+)-2-METHOXYPROPIONIC ACID Benzyl acetate DL-alpha-Methoxyphenylacetic acid DL-Mandelic acid ACETYLOXYACETALDEHYDE Styralyl acetate Glycolic acid (R)-(-)-alpha-Methoxyphenylacetic acid 2-METHOXY-2-PHENYLETHANOL