8-Hydroxy-2-naphthylamine-3,6-disulfonic acid

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Products Intro: Product Name:8-Hydroxy-2-naphthylamine-3,6-disulfonic acid
CAS:90-40-4
Purity:0.99 Package:5KG;1KG Remarks:C10H9NO7S2
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Products Intro: Product Name:8-Hydroxy-2-naphthylamine-3,6-disulfonic acid
CAS:90-40-4
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Products Intro: Product Name:(2R)-2-amino-3-[[(2R)-2-amino-2-carboxypropyl]trisulfanyl]-2-methylpropanoic acid
CAS:90-40-4
Purity:0.97 Package:mgs,gs,kgs Remarks:A843534
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Products Intro: Product Name:3-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid
CAS:90-40-4
Purity:99% Package:1 kg,5 kg, 10 kg,25kg and 1 MT
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Products Intro: Product Name:3-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid
CAS:90-40-4
Purity:98% Package:1 kg,5 kg, 10 kg,25kg and 1 MT
8-Hydroxy-2-naphthylamine-3,6-disulfonic acid Basic information
Product Name:8-Hydroxy-2-naphthylamine-3,6-disulfonic acid
Synonyms:8-Hydroxy-2-naphthylamine-3,6-disulfonic acid;3-amino-5-hydroxynaphthalene-2,7-disulphonic acid;3-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid;3-amino-5-hydroxynaphthalene-2,7-disulfonic acid;3-azanyl-5-hydroxy-naphthalene-2,7-disulfonic acid;2,7-Naphthalenedisulfonicacid, 3-aMino-5-hydroxy-;2-Amino-8-naphthol-6-disulfonic acid;(2R)-2-amino-3-[[(2R)-2-amino-2-carboxypropyl]trisulfanyl]-2-methylpropanoic acid
CAS:90-40-4
MF:C10H9NO7S2
MW:319.31
EINECS:201-989-3
Product Categories:Intermediates of Dyes and Pigments
Mol File:90-40-4.mol
8-Hydroxy-2-naphthylamine-3,6-disulfonic acid Structure
8-Hydroxy-2-naphthylamine-3,6-disulfonic acid Chemical Properties
Boiling point 603.18℃[at 101 325 Pa]
density 1.88[at 20℃]
vapor pressure 0Pa at 25℃
Water Solubility 35.36g/L at 25℃
LogP-2.334
EPA Substance Registry System2,7-Naphthalenedisulfonic acid, 3-amino-5-hydroxy- (90-40-4)
Safety Information
MSDS Information
8-Hydroxy-2-naphthylamine-3,6-disulfonic acid Usage And Synthesis
Chemical Properties2-Amino-8-hydroxynaphthalene-3,6-disulfonic acid [90-40-4]. (3-amino-5-hydroxy2,7-disulfonic acid), RR acid, 2 R acid, Columbia acid, C10H9NO7S2, Mr 319.3, and its alkali salts are readily soluble in water. Coupling with diazo compounds takes place under alkaline conditions in the position ortho to the hydroxyl group.
UsesThe RR acid is used as a coupling component in azo dyes, e.g., C.I. Food Black 2 and C.I. Direct Brown 151.
Production Methods2-Aminonaphthalene-3,6,8-trisulfonic acid liquor is concentrated by evaporation and heated with sodium hydroxide liquor in an autoclave [7]. The temperature is raised to 195℃ over 10 h and held at 195℃ for another 8 – 10 h until completion of the reaction is determined by working up a test sample and obtaining a strength by alkaline coupling equal to the diazotization titer. After dilution, acidification, and stirring while hot until all sulfur dioxide is expelled, the product is filtered off as its monosodium salt at 55℃ and washed with brine. Most of the isomeric 2-amino-3-hydroxynaphthalene-6,8-disulfonic acid impurity is removed in the filtrate. Crude RR acid is obtained in 65 % yield and is suitable for certain outlets. Further purification is necessary for critical derived dyes, and this is achieved by dissolving in dilute alkali, filtering at 80℃, and reprecipitating by addition of sodium chloride and hydrochloric acid. Filtration at 55℃ gives 90 % recovery of product.
Flammability and ExplosibilityNot classified
Tag:8-Hydroxy-2-naphthylamine-3,6-disulfonic acid(90-40-4) Related Product Information
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