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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)

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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Suppliers list
Company Name: Alfa Chemistry
Tel: +1-5166625404
Email: Info@alfa-chemistry.com
Products Intro: Product Name:[NH2Me2][(RuCl((S)-binap))2(μ-Cl)3]
CAS:199541-17-8
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: 0551-65418684 +8618949823763
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Products Intro: Product Name:Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(d...
CAS:199541-17-8
Company Name: Aladdin Scientific
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Products Intro: Product Name:Dimethylammonium Dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
CAS:199541-17-8
Purity:95% Package:$20.9/100mg;$87.9/500mg;Bulk package Remarks:95%
Company Name: J & K SCIENTIFIC LTD.  
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Products Intro: Product Name:Dimethylammonium dichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-binap)}2(mu-Cl)3]
CAS:199541-17-8
Package:1g;250mg;5g
Company Name: TCI (Shanghai) Development Co., Ltd.  
Tel: 021-67121386
Email: Sales-CN@TCIchemicals.com
Products Intro: Product Name:[NH2Me2][(RuCl((S)-binap))2(mu-Cl)3]
CAS:199541-17-8
Package:1G,200MG
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Basic information
Reaction
Product Name:Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
Synonyms:[NH2Me2][{RuCl((S)-binap)}2(mu-Cl)3];(S)-[(RuCl(BINAP))2(mu-Cl)3][NH2Me2];[NH2ME2][(RUCL((S)-BINAP))2(Μ-CL)3];-binaphthyl]diruthenate(II),[NH2Me2][{RuCl((S);-Cl)3][NH2Me2];DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II),[NH2ME2][{RUCL((S);Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II);(S)-[(RuCl(BINAP))2(μ-Cl)3][NH2Me2]
CAS:199541-17-8
MF:2C44H32P2.C2H7N.Cl.Cl3Ru2.ClH
MW:1670.87
EINECS:
Product Categories:Ru
Mol File:199541-17-8.mol
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Structure
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Chemical Properties
Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form Powder
color orange
Sensitive air sensitive
Safety Information
Hazard Codes F
Risk Statements 11
RIDADR UN 1325 4.1/PG 3
WGK Germany 3
HS Code 2843.90.0000
MSDS Information
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Usage And Synthesis
Reaction
  1. (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester.
  2. Useful ligand in asymmetric Heck processes.
  3. 3. Ligand employed in palladium-catalyzed asymmetric arylation of ketones.
  4. 4. Ligand employed in rhodium-catalyzed 1,4-additions to enones.
  5. 5. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives.
  6. 6. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction.
  7. 7. Ligand employed in rhodium-catalyzed kinetic resolution of enynes.
  8. 8. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes.
  9. 9. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers.
  10. 10. Ligand employed in palladium-catalyzed synthesis of chiral allenes.
  11. 11. Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives.
  12. 12. Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols.
  13. 13. Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones.
  14. 14. Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols.
  15. 15. Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage.
Reactions of 199541-17-8_1
Reactions of 199541-17-8_2
Reactions of 199541-17-8_3
Reactions of 199541-17-8_4
UsesTakasago Ligands and Complexes for Asymmetric Reactions
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials
Tag:Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)(199541-17-8) Related Product Information
Tris(triphenylphosphine)ruthenium(II) chloride DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis[di-(3,5-xylyl)phosphino]-1,1μ-binaphthyl]diruthenate(II) CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)