87630-35-1

1-(三异丙基甲硅烷基)吡咯(87630-35-1)核磁图(¹³CNMR)

产品名称:1-(三异丙基甲硅烷基)吡咯

CAS:87630-35-1

分子式:C13H25NSi

分子量: 223.43

InChI:InChI=1S/C13H25NSi/c1-11(2)15(12(3)4,13(5)6)14-9-7-8-10-14/h7-13H,1-6H3

InChIKey: FBQURXLBJJNDBX-UHFFFAOYSA-N

Smiles:N1([Si](C(C)C)(C(C)C)C(C)C)C=CC=C1

Mass

MS-IW-9281          
1-(triisopropylsilyl)pyrrole
C13H25NSi           (Mass of molecular ion:    223)

   Source Temperature: 220 °C
   Sample Temperature: 150 °C
   Reservoir, 75 eV

      27.0       1.9
      39.0       2.0
      41.0       3.7
      42.0       1.3
      43.0       9.6
      44.0       2.3
      45.0       8.0
      53.0       1.7
      54.0       1.1
      55.0       3.5
      57.0       1.1
      58.0       1.5
      59.0      28.1
      60.0       2.3
      61.0       1.0
      62.0       3.2
      66.0       1.1
      67.0       9.9
      68.0       4.3
      69.0       7.6
      70.0       2.2
      71.0       8.9
      72.0       1.7
      73.0       6.3
      81.0       1.4
      82.0       1.8
      83.0      13.8
      84.0       3.0
      85.0      13.9
      86.0       1.8
      87.0       3.3
      94.0      17.6
      95.0       5.7
      96.0       8.5
      97.0       8.5
      98.0       1.9
      99.0       1.1
     109.0       1.9
     110.0      33.2
     111.0       7.8
     112.0       2.0
     113.0       4.5
     114.0       1.1
     122.0       1.5
     123.0       1.1
     124.0      26.5
     125.0       5.1
     126.0       1.3
     136.0       2.7
     137.0       1.1
     138.0      25.0
     139.0      22.1
     140.0       3.7
     152.0      43.9
     153.0       7.6
     154.0       2.1
     164.0       1.0
     180.0     100.0
     181.0      35.6
     182.0       7.6
     183.0       1.3
     222.0       1.6
     223.0      42.5
     224.0       8.6
     225.0       2.2

400 MHz in CDCl3

¹H NMR	399.65 MHz
C₁₃ H₂₅ N Si	0.05 ml : 0.5 ml CDCl₃
1-(triisopropylsilyl)pyrrole

    Assign.     Shift(ppm)

      A             6.794
      B             6.312
      C             1.447
      D             1.097

     Hz     ppm     Int.

   2717.41   6.800    137
   2715.45   6.795    184
   2713.50   6.790    133
   2524.66   6.318    159
   2522.71   6.313    205
   2520.75   6.308    146
    594.60   1.488     46
    587.04   1.469    107
    579.47   1.450    149
    571.90   1.432    125
    564.45   1.413     75
    448.85   1.124     60
    442.26   1.107   1000
    434.57   1.088    921
    428.34   1.072     68

in CDCl3