Chemical Safety Data Sheet MSDS / SDS
Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl) aMino]rutheniuM(II), Min.98% Ru-MACHO BH
Revision Date:2026-03-20Revision Number:1
Product identifier
- Product name: Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl) aMino]rutheniuM(II), Min.98% Ru-MACHO BH
- CBnumber: CB62709891
- CAS: 1295649-41-0
- Synonyms: RU-MACHO-BH;Ru-MACHO®
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P314 Get medical advice/attention if you feel unwell.
P501 Dispose of contents/container to..…
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P309+P311 IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container to..…
Hazard statements
H371 May cause damage to organs
H373 May cause damage to organs through prolonged or repeated exposure
H360 May damage fertility or the unborn child
H340 May cause genetic defects
Substance
- Product name: Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl) aMino]rutheniuM(II), Min.98% Ru-MACHO BH
- Synonyms: RU-MACHO-BH;Ru-MACHO®
- CAS: 1295649-41-0
- MF: C29H35BNOP2Ru
- MW: 587.43
If inhaled
Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician.
In case of skin contact
Take off all contaminated clothing immediately. If on skin, rinse well with water. Call a POISON CENTER or doctor/ physician.
In case of eye contact
Rinse with plenty of water. If easy to do, remove contact lens, if worn. Call a POISON CENTER or doctor/ physician.
If swallowed
Call a POISON CENTER or doctor/ physician. Rinse mouth.
Most important symptoms and effects, both acute and delayed
None known.
Suitable extinguishing media
Dry powder, Foam, Water spray, Carbon dioxide (CO2)
Specific hazards during fire fighting
No information available.
Specific extinguishing methods
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Immediately evacuate personnel to safe areas. Remove undamaged containers from fire area if it is safe to do so.
Special protective equipment for fire-fighters
Use personal protective equipment.
Personal precautions, protective equipment and emergency procedures
Wear suitable protective equipment. Keep people away from and upwind of spill/leak. Entry to non-involved personnel should be controlled around the leakage area by roping off, etc.
Environmental precautions
Prevent product from entering drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust.
Handling
Technical measuresPrevent dispersion of dust.
Local/Total ventilation
Ensure adequate ventilation. Handle product only in closed system or provide appropriate exhaust ventilation at machinery. Use a local exhaust ventilation.
Advice on safe handling
Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Wash hands and face thoroughly after handling.
Avoidance of contact
Oxidizing agents
Storage
Conditions for safe storageKeep container tightly closed. Store in a cool and shaded area. Keep under inert gas. Store locked up.
Ingredients with workplace control parameters
| Components | CAS RN | Value type (Form of ex- posure) | Control parameters / Permissible con- centration | Basis |
|---|---|---|---|---|
| Toluene | 108-88-3 | PC-TWA | 50 mg/m3 | CN OEL |
| Further information: Skin | ||||
| PC-STEL | 100 mg/m3 | CN OEL | ||
| Further information: Skin | ||||
| TWA | 20 ppm | ACGIH | ||
| Ethanol | 64-17-5 | STEL | 1,000 ppm | ACGIH |
Components CAS RN Value type Control parameters Basis (Form of ex- / Permissible conposure) centration
Toluene 108-88-3 PC-TWA 50 mg/m3 CN OEL
Skin
PC-STEL 100 mg/m3 CN OEL
Further information
PC-STEL 100 mg/m3 CN OEL
Skin
TWA 20 ppm ACGIH
Ethanol 64-17-5 STEL 1,000 ppm ACGIH
TWA 20 ppm ACGIH
Ethanol 64-17-5 STEL 1,000 ppm ACGIH
Engineering measures
Install a closed system or local exhaust.
Also install safety shower and eye bath.
Also install safety shower and eye bath.
Personal protective equipment
Respiratory protectionDustproof gas mask
Self-contained breathing apparatus
Eye/face protection
Self-contained breathing apparatus
Safety glasses
Safety goggles
Face-shield
Skin and body protection
Safety goggles
Face-shield
Impervious protective clothing
Hand protection
Impervious gloves *Use personal protective equipment(PPE) approved under appropriate government standards and follow local and national regulations.
Information on basic physicochemical properties
- Physical statePowder
- Odor ThresholdNo data available
- Molecular weight586.42 g/mol
- Viscosity, kinematicNo data available
- Viscosity, dynamicNo data available
- Decomposition temperatureNo data available
- OdorNo data available
- Colorwhite - yellow
- Appearancesolid
- Autoignition temperatureNo data available
- Partition coefficient: n-octanol/water (log value)No data available
- Solubility in other solventsNo data available
- Water solubilityNo data available
- Vapor pressureNo data available
- Lower explosion limit / Lower flammability limitNo data available
- Upper explosion limit / Upper flammability limitNo data available
- FlammabilityNo data available
- Evaporation rateNo data available
- Flash pointNo data available
- Boiling point/boiling rangeNo data available
- Melting point/freezing pointNo data available
- pHNo data available
Reactivity
No data available
Chemical stability
Stable under normal conditions.
Possibility of hazardous reactions
None under normal processing.
Conditions to avoid
Exposure to air.
Incompatible materials
Oxidizing agents
Hazardous decomposition products
Carbon monoxide, Carbon dioxide (CO2), Nitrogen oxides (NOx), Oxides of phosphorus, Boron oxides, Metal oxides
Acute toxicity
Components
Toluene
Acute oral toxicity
LDLo (Humans): 50 mg/kg Assessment: The component/mixture is minimally toxic after single ingestion.
LD50 (Rat)
636 mg/kg
Acute inhalation toxicity
LCLo (Humans): 15,000 mg/m3 Exposure time: 1 h Test atmosphere: dust/mist Assessment: The component/mixture is moderately toxic after short term inhalation.
LC50 (Rat)
49 g/m3 Exposure time: 4 h Test atmosphere: dust/mist
Acute dermal toxicity
LD50 (Rabbit): 12,267 mg/kg Assessment: The substance or mixture has no acute dermal toxicity
Ethanol
Acute oral toxicity
LDLo (Humans): 1,400 mg/kg Assessment: The substance or mixture has no acute oral toxicity
LD50 (Rat)
7 g/kg
Acute inhalation toxicity
LC50 (Rat): 124,700 mg/m3 Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity
Acute dermal toxicity
LDLo (Rabbit): 20,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity
Skin corrosion/irritation
Components
Toluene
Result
Skin irritation
Serious eye damage/eye irritation
Components
Toluene
Result
Mild eye irritation
Ethanol
Result
Eye irritation
Respiratory or skin sensitization
Classified based on available data. For more details, see section 2.
Germ cell mutagenicity
Product
Germ cell mutagenicity - Assessment
Presumed to induce heritable mutations in the germ cells of humans.
Components
Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl)amino]ruthenium(II)
Germ cell mutagenicity - Assessment
Presumed to induce heritable mutations in the germ cells of humans.
Ethanol
Germ cell mutagenicity - Assessment
Presumed to induce heritable mutations in the germ cells of humans.
Carcinogenicity
Classified based on available data. For more details, see section 2.
Reproductive toxicity
Product
Reproductive toxicity - Assessment
Known human reproductive toxicant
Components
Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl)amino]ruthenium(II)
Reproductive toxicity - Assessment
Known human reproductive toxicant
Toluene
Reproductive toxicity - Assessment
Known human reproductive toxicant
Ethanol
Reproductive toxicity - Assessment
Known human reproductive toxicant
STOT-single exposure
Product
Target Organs
Central nervous system
Assessment
May cause damage to organs.
Components
Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl)amino]ruthenium(II)
Target Organs
Central nervous system
Assessment
May cause damage to organs.
Toluene
Assessment
May cause respiratory irritation.
Target Organs
Central nervous system
Assessment
Causes damage to organs.
Ethanol
Assessment
May cause respiratory irritation. May cause drowsiness or dizziness.
STOT-repeated exposure
Product
Target Organs
Liver, Kidney, Central nervous system
Assessment
May cause damage to organs through prolonged or repeated exposure.
Components
Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl)amino]ruthenium(II)
Target Organs
Liver, Kidney, Central nervous system
Assessment
May cause damage to organs through prolonged or repeated exposure.
Toluene
Target Organs
Liver, Kidney, Central nervous system
Assessment
Causes damage to organs through prolonged or repeated exposure.
Ethanol
Target Organs
Liver
Assessment
Causes damage to organs through prolonged or repeated exposure.
Target Organs
Nervous system
Assessment
May cause damage to organs through prolonged or repeated exposure.
Repeated dose toxicity
Classified based on available data. For more details, see section 2.
Aspiration toxicity
Components
Toluene
RTECS No.
XS5250000 (Toluene) KQ6300000 (Ethanol)
Ecotoxicity
Components:
Toluene:
Toxicity to fishLC50 (Oryzias latipes (Japanese medaka)): 25 mg/l Exposure time: 96 h
Toxicity to daphnia and other aquatic invertebrates
EC50 (Daphnia magna (Water flea)): 4.1 mg/l Exposure time: 48 h
Toxicity to algae/aquatic plants
EC50 (Selenastrum capricornutum (green algae)): 29 mg/l Exposure time: 72 h
Ecotoxicology Assessment
Acute aquatic toxicityToxic to aquatic life.
Chronic aquatic toxicity
This product has no known ecotoxicological effects.
Ethanol:
Toxicity to fishLC50 (Oryzias latipes (Japanese medaka)): 1,350 mg/l Exposure time: 48 h LC50 (Pimephales promelas (fathead minnow)): 12,720 mg/l Exposure time: 96 h
Toxicity to daphnia and other aquatic invertebrates
EC50 (Daphnia magna (Water flea)): 2 mg/l Exposure time: 48 h
Toxicity to algae/aquatic plants
EC50 (Selenastrum capricornutum (green algae)): 8.09 mg/l Exposure time: 48 h
Ecotoxicology Assessment
Acute aquatic toxicityToxic to aquatic life.
Chronic aquatic toxicity
This product has no known ecotoxicological effects.
Persistence and degradability
No data available
Bioaccumulative potential
Components:
Toluene:
octanol/water (log value)
Partition coefficient: noctanol/water (log value)
2.73
Ethanol:
octanol/water (log value)
Partition coefficient: noctanol/water (log value)
-0.31
Mobility in soil
Components:
Toluene:
tal compartments
Distribution among environmental compartments
Koc: 166
Ethanol:
tal compartments
Distribution among environmental compartments
Koc: 0.20
Other adverse effects
No data available
Disposal methods
Waste from residuesDisposal in accordance with local and national regulations. Entrust disposal to a licensed waste disposal company.
Contaminated packaging
Disposal in accordance with local and national regulations. Before disposal of used container, remove contents completely.
International Regulations
IATA-DGR
UN/ID No.Not applicable
Proper shipping name
Not applicable
Class
Not applicable
Subsidiary risk
Not applicable
Packing group
Not applicable
IMDG-Code
UN numberNot applicable
Proper shipping name
Not applicable
Class
Not applicable
Subsidiary risk
Not applicable
Packing group
Not applicable
EmS Code
Not applicable
Domestic regulation
GB 6944/12268
UN numberNot applicable
Proper shipping name
Not applicable
Class
Not applicable
Subsidiary risk
Not applicable
Packing group
Not applicable
Measures on the Environmental Administration of New Chemical Substances Registration
Registration/Notification numberB1A232215683
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.
The ingredients of this product are reported in the following inventories
CH BAGREGNot in compliance with the inventory
TSCA
Substance(s) not listed on TSCA inventory
AICS
Not in compliance with the inventory
DSL
This product contains the following components that are not on the
Canadian DSL nor NDSL.
Carbonylhydrido(tetrahydroborato)[bis(2diphenylphosphinoethyl)amino]ruthenium(II)
ENCS
Canadian DSL nor NDSL.
Carbonylhydrido(tetrahydroborato)[bis(2diphenylphosphinoethyl)amino]ruthenium(II)
Not in compliance with the inventory
ISHL
Not in compliance with the inventory
KECI
Not in compliance with the inventory
PICCS
Not in compliance with the inventory
IECSC
Not in compliance with the inventory
NZIoC
Not in compliance with the inventory
Abbreviations and acronyms
CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.
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