ChemicalBook
Chemical Safety Data Sheet MSDS / SDS

N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2

Revision Date:2026-03-20Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2
  • CBnumber: CB42709408
  • CAS: 1333981-84-2
  • Synonyms: (R,R)-Ts-DENEB

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 010-86108875

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordWarning
Precautionary statements
P405 Store locked up.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P391 Collect spillage. Hazardous to the aquatic environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P501 Dispose of contents/container to..…
Hazard statements
H411 Toxic to aquatic life with long lasting effects
H351 Suspected of causing cancer
H373 May cause damage to organs through prolonged or repeated exposure

SECTION 3: Composition/information on ingredients

Substance

  • Product name: N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2
  • Synonyms: (R,R)-Ts-DENEB
  • CAS: 1333981-84-2
  • MF: C31H33ClN2O3RuS
  • MW: 650.2

SECTION 4: First aid measures

If inhaled

Remove person to fresh air and keep comfortable for breathing. Get medical advice/ attention.

In case of skin contact

Take off all contaminated clothing immediately. If on skin, rinse well with water. Get medical advice/ attention.

In case of eye contact

Rinse with plenty of water. If easy to do, remove contact lens, if worn. Get medical advice/ attention.

If swallowed

Get medical advice/ attention. Rinse mouth.

Most important symptoms and effects, both acute and delayed

None known.

SECTION 5: Firefighting measures

Suitable extinguishing media

Dry powder, Foam, Water spray, Carbon dioxide (CO2)

Specific hazards during fire fighting

No information available.

Specific extinguishing methods

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Immediately evacuate personnel to safe areas. Remove undamaged containers from fire area if it is safe to do so.

Special protective equipment for fire-fighters

Use personal protective equipment.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Wear suitable protective equipment. Keep people away from and upwind of spill/leak. Entry to non-involved personnel should be controlled around the leakage area by roping off, etc.

Environmental precautions

Should not be released into the environment.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust.

SECTION 7: Handling and storage

Handling

Technical measures
Prevent dispersion of dust.
Local/Total ventilation
Ensure adequate ventilation. Handle product only in closed system or provide appropriate exhaust ventilation at machinery. Use a local exhaust ventilation.
Advice on safe handling
Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Wash hands and face thoroughly after handling.
Avoidance of contact
Oxidizing agents

Storage

Conditions for safe storage
Keep container tightly closed. Store in a cool and shaded area. Keep under inert gas. Store locked up.

SECTION 8: Exposure controls/personal protection

Ingredients with workplace control parameters

ComponentsCAS RNValue type (Form of ex- posure)Control parameters / Permissible con- centrationBasis
4-Methyl-2-pentanone108-10-1TWA20 ppmACGIH
STEL75 ppmACGIH
Heptane142-82-5PC-TWA500 mg/m3CN OEL
PC-STEL1,000 mg/m3CN OEL
TWA400 ppmACGIH
STEL500 ppmACGIH

Components CAS RN Value type Control parameters Basis (Form of ex- / Permissible conposure) centration 4-Methyl-2-pentanone 108-10-1 TWA 20 ppm ACGIH
STEL 75 ppm ACGIH
Heptane 142-82-5 PC-TWA 500 mg/m3 CN OEL
PC-STEL 1,000 mg/m3 CN OEL
TWA 400 ppm ACGIH
STEL 500 ppm ACGIH

Engineering measures

Install a closed system or local exhaust.
Also install safety shower and eye bath.

Personal protective equipment

Respiratory protection
Dustproof gas mask
Self-contained breathing apparatus
Eye/face protection
Safety glasses
Safety goggles
Face-shield
Skin and body protection
Impervious protective clothing
Hand protection
Impervious gloves *Use personal protective equipment(PPE) approved under appropriate government standards and follow local and national regulations.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Molecular weight650.20 g/mol
  • Viscosity, kinematicNo data available
  • Viscosity, dynamicNo data available
  • Decomposition temperatureNo data available
  • Autoignition temperatureNo data available
  • Partition coefficient: n-octanol/water (log value)No data available
  • Solubility in other solventsNo data available
  • Water solubilityNo data available
  • Vapor pressureNo data available
  • Lower explosion limit / Lower flammability limitNo data available
  • Physical statesolid
  • Upper explosion limit / Upper flammability limitNo data available
  • FlammabilityNo data available
  • Evaporation rateNo data available
  • Flash pointNo data available
  • Boiling point/boiling rangeNo data available
  • Melting point/freezing pointNo data available
  • pHNo data available
  • Odor ThresholdNo data available
  • OdorNo data available
  • Colorwhite - yellow
  • Appearancesolid

SECTION 10: Stability and reactivity

Reactivity

No data available

Chemical stability

Stable under normal conditions.

Possibility of hazardous reactions

None under normal processing.

Conditions to avoid

Exposure to air.

Incompatible materials

Oxidizing agents

Hazardous decomposition products

Carbon monoxide, Carbon dioxide (CO2), Nitrogen oxides (NOx), Hydrogen chloride gas, Metal oxides

SECTION 11: Toxicological information

Acute toxicity

Product

Acute oral toxicity

Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method

Acute inhalation toxicity

Acute toxicity estimate: > 10 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method

Acute dermal toxicity

Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method

Components

3-Methoxy-1-propanol

Acute oral toxicity

LD50 (Rat): 5,710 mg/kg Assessment: The substance or mixture has no acute oral toxicity

Acute dermal toxicity

LD50 (Rabbit): 5,320.4 mg/kg Assessment: The substance or mixture has no acute dermal toxicity

4-Methyl-2-pentanone

Acute oral toxicity

LD50 (Rat): 2,080 mg/kg Assessment: The component/mixture is minimally toxic after single ingestion.

Acute inhalation toxicity

Assessment: The component/mixture is moderately toxic after short term inhalation.

Acute toxicity (other routes of administration)

LD50 (Rat): 400 mg/kg Application Route: Intraperitoneal injection

Heptane

Acute inhalation toxicity

TCLo (Humans): 1000 ppm Exposure time: 6 min Test atmosphere: gas Assessment: The substance or mixture has no acute inhalation toxicity

LC50 (Rat)

103 g/m3 Exposure time: 4 h Test atmosphere: dust/mist

Acute dermal toxicity

Assessment: The component/mixture is minimally toxic after single contact with skin.

Acute toxicity (other routes of administration)

LD50 (Mouse): 222 mg/kg Application Route: Intravenous

Skin corrosion/irritation

Components

Heptane

Result

Skin irritation

Serious eye damage/eye irritation

Components

4-Methyl-2-pentanone

Result

Eye irritation

Heptane

Result

Mild eye irritation

Respiratory or skin sensitization

Classified based on available data. For more details, see section 2.

Germ cell mutagenicity

Classified based on available data. For more details, see section 2.

Carcinogenicity

Components

4-Methyl-2-pentanone

Carcinogenicity - Assessment

Suspected human carcinogens

Reproductive toxicity

Classified based on available data. For more details, see section 2.

STOT-single exposure

Components

4-Methyl-2-pentanone

Assessment

May cause respiratory irritation. May cause drowsiness or dizziness.

Heptane

Assessment

May cause respiratory irritation. May cause drowsiness or dizziness.

STOT-repeated exposure

Product

Target Organs

Nervous system

Assessment

May cause damage to organs through prolonged or repeated exposure.

Components

4-Methyl-2-pentanone

Target Organs

Nervous system

Assessment

Causes damage to organs through prolonged or repeated exposure.

Repeated dose toxicity

Classified based on available data. For more details, see section 2.

Aspiration toxicity

Components

Heptane

RTECS No.

UB7650000 (3-Methoxy-1-propanol) SA9275000 (4-Methyl-2-pentanone) MI7700000 (Heptane)

SECTION 12: Ecological information

Ecotoxicity

Components: (R,R)-Ts-DENEB®:

Ecotoxicology Assessment

Acute aquatic toxicity
Harmful to aquatic life.
Chronic aquatic toxicity
Harmful to aquatic life with long lasting effects.

Heptane:

Ecotoxicology Assessment

Acute aquatic toxicity
Very toxic to aquatic life.
Chronic aquatic toxicity
Very toxic to aquatic life with long lasting effects.

Persistence and degradability

No data available

Bioaccumulative potential

Components:

4-Methyl-2-pentanone:

octanol/water (log value)
Partition coefficient: noctanol/water (log value)
1.38

Heptane:

octanol/water (log value)
Partition coefficient: noctanol/water (log value)
4.66

Mobility in soil

Components:

4-Methyl-2-pentanone:

tal compartments
Distribution among environmental compartments
Koc: 123

Heptane:

tal compartments
Distribution among environmental compartments
Koc: 240

Other adverse effects

No data available

SECTION 13: Disposal considerations

Disposal methods

Waste from residues
Disposal in accordance with local and national regulations. Entrust disposal to a licensed waste disposal company.
Contaminated packaging
Disposal in accordance with local and national regulations. Before disposal of used container, remove contents completely.

SECTION 14: Transport information

International Regulations

IATA-DGR

UN/ID No.
Not applicable
Proper shipping name
Not applicable
Class
Not applicable
Subsidiary risk
Not applicable
Packing group
Not applicable

IMDG-Code

UN number
Not applicable
Proper shipping name
Not applicable
Class
Not applicable
Subsidiary risk
Not applicable
Packing group
Not applicable
EmS Code
Not applicable

Domestic regulation

GB 6944/12268

UN number
Not applicable
Proper shipping name
Not applicable
Class
Not applicable
Subsidiary risk
Not applicable
Packing group
Not applicable

SECTION 15: Regulatory information

Measures on the Environmental Administration of New Chemical Substances Registration

Registration/Notification number
B1A232216155
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.

The ingredients of this product are reported in the following inventories

TCSI
Not in compliance with the inventory
TSCA
Product contains substance(s) not listed on TSCA inventory.
AIIC
Not in compliance with the inventory
DSL
This product contains the following components that are not on the
Canadian DSL nor NDSL.
(R,R)-Ts-DENEB®
ENCS
Not in compliance with the inventory
ISHL
Not in compliance with the inventory
KECI
Not in compliance with the inventory
PICCS
Not in compliance with the inventory
IECSC
Not in compliance with the inventory
NZIoC
Not in compliance with the inventory
TECI
Not in compliance with the inventory

SECTION 16: Other information

Abbreviations and acronyms

CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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