Chemical Safety Data Sheet MSDS / SDS
Phoxim
Revision Date:2026-04-11Revision Number:1
Product identifier
- Product name: Phoxim
- CBnumber: CB2255860
- CAS: 14816-18-3
- EINECS Number: 238-887-3
- Synonyms: Phoxim,Phoxime
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
P201 Obtain special instructions before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Hazard statements
H302 Harmful if swallowed
H311 Toxic in contact with skin
H317 May cause an allergic skin reaction
H330 Fatal if inhaled
H410 Very toxic to aquatic life with long lasting effects
Substance
- Product name: Phoxim
- Synonyms: Phoxim,Phoxime
- CAS: 14816-18-3
- EC number: 238-887-3
- MF: C12H15N2O3PS
- MW: 298.3
First Aid Measures
General adviceIf symptoms persist, call a physician. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing.
Eye contact
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician.
Skin Contact
Consult a physician if necessary. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Wash off immediately with soap and plenty of water.
Inhalation
Remove to fresh air If breathing is irregular or stopped, administer artificial respiration Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation Call a physician
Ingestion
Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician. Rinse mouth.
Self-protection of the first aider
Use personal protective equipment as required.
Most important symptoms and effects, both acute and delayed
SymptomsNo information available.
Indication of any immediate medical attention and special treatment needed
Note to physiciansMay cause sensitization of susceptible persons.
Suitable Extinguishing Media
Suitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media
No information available.
Specific hazards arising from the chemical
Specific hazards arising from the chemicalIn the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Hazardous combustion products
Hydrogen cyanide. Hydrogen sulfide. Carbon oxides. Nitrogen oxides (NOx).
Explosion data
Sensitivity to Mechanical ImpactNo information available.
Sensitivity to Static Discharge
No information available.
Protective equipment and precautions for firefighters
Protective equipment and precautions for firefightersAs in any fire, wear self contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Personal precautions, protective equipment and emergency procedures
Personal precautionsAvoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Environmental precautions
Environmental precautionsPrevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. See Section 12 for additional Ecological
Information. Prevent product from entering drains. Should not be released into the environment.
Information. Prevent product from entering drains. Should not be released into the environment.
Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so.
Methods for cleaning up
Cover liquid spill with sand, earth or other non-combustible absorbent material. Cover powder spill with plastic sheet or tarp to minimize spreading. Pick up and transfer to properly labeled containers. Soak up with inert absorbent material.
Precautions for safe handling
Advice on safe handlingAvoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray.
Conditions for safe storage, including any incompatibilities
Storage ConditionsKeep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Store at 4 °C.
Incompatible materials
None known based on information supplied.
Control parameters
Exposure Guidelines.
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
| Column 1 | Column 2 | Column 3 | Column 4 |
|---|---|---|---|
| Phoxim 14816-18-3 | - | TWA: 5 mg/m3 CN (vacated) TWA: 5 mg/m3 S* as CN | IDLH: 25 mg/m3 CN |
Appropriate engineering controls
Engineering ControlsShowers
Eyewash stations
Ventilation systems
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protectionTight sealing safety goggles.
Skin and Body Protection
Wear protective gloves and protective clothing.
Respiratory protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
General Hygiene Considerations
When using do not eat, drink or smoke. Wash contaminated clothing before reuse.
Information on basic physicochemical properties
- Physical Stateliquid
- AppearanceNo information available
- OdorNo information available
- pHNo information available
- Melting point/freezing pointNo information available
- Boiling pointbp0.01 102°
- Flash pointNo information available
- Liquid DensityNo information available
- Evaporation rateNo information available
- Upper flammability limitsNo information available
- Lower flammability limitNo information available
- Vapor pressure2.1×10-3 Pa (20 °C)
- Vapor densityNo information available
- Specific gravityNo information available
- Water solubility1.5 mg l-1 (20 °C)
- Solubility in other solventsNo information available
- Partition coefficientNo information available
- Autoignition temperatureNo information available
- Decomposition temperatureNo information available
- Kinematic viscosityNo information available
- Explosive propertiesNo information available
- Oxidizing propertiesNo information available
- Density and/or relative densityd420 1.176
- SolubilityAcetonitrile (Slightly), Chloroform (Slightly), Methanol (Slightly)
- ColourColorless to light yellow
Reactivity
Not applicable
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
Contact with acids may liberate toxic gas.
Hazardous polymerization
No information available.
Conditions to avoid
Extremes of temperature and direct sunlight.
Incompatible materials
Strong oxidizing agents.
Hazardous Decomposition Products
Hydrogen cyanide. Hydrogen sulfide. Carbon oxides. Nitrogen oxides (NOx).
Information on likely routes of exposure
InhalationClassified based on available data. For more details, see section 2.
Eye contact
Classified based on available data. For more details, see section 2.
Skin Contact
Classified based on available data. For more details, see section 2.
Ingestion
Classified based on available data. For more details, see section 2.
Information on toxicological effects
SymptomsClassified based on available data. For more details, see section 2.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chronic ToxicityRepeated contact may cause allergic reactions in very susceptible persons. Avoid repeated exposure. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical name ACGIH IARC NTP OSHA
Phoxim - Group2A - X 14816-18-3
Numerical measures of toxicity - Product Information
Unknown acute toxicityClassified based on available data. For more details, see section 2
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
The following values are calculated based on chapter 3.1 of the GHS document
300 mg/kg
ATEmix (dermal)
1000 mg/kg
ATEmix (inhalation-dust/mist)
0 mg/l
ATEmix (inhalation-vapor)
3200 mg/l
Ecotoxicity
Very toxic to aquatic life with long lasting effects
0% of the mixture consists of components(s) of unknown hazards to the aquatic environment.
0% of the mixture consists of components(s) of unknown hazards to the aquatic environment.
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations. Should not be released into the environment.
Contaminated packaging
Do not reuse container.
Other Information
Waste codes should be assigned by the user based on the application for which the product was used.
California Hazardous Waste Status
This product contains one or more substances that are listed with the State of California as a hazardous waste.
| Chemical name | California Hazardous Waste Status |
|---|---|
| Phoxim 14816-18-3 | Toxic |
DOT
UN/ID noUN2810
Hazard Class
6.1
Packing Group
III
Proper shipping name
Toxic liquids, organic, n.o.s.
Description
UN2810, Toxic liquids, organic, n.o.s. (Phoxim), 6.1, III, Marine pollutant Marine pollutant This product contains a chemical which is listed as a marine pollutant according to DOT
Emergency Response Guide Number
153
IMDG
UN/ID noUN2810
Hazard Class
6.1
Packing Group
III
Proper shipping name
Toxic liquid, organic, n.o.s.
Description
UN2810, Toxic liquid, organic, n.o.s. (Phoxim), 6.1, III, Marine pollutant
Special Provisions
223, 274
EmS-No
F-A, S-A
IATA
UN/ID noUN2810
Hazard Class
6.1
Packing Group
III
Proper shipping name
Toxic liquid, organic, n.o.s.
Description
UN2810, Toxic liquid, organic, n.o.s. (Phoxim), 6.1, III
ERG Code
6L
International Inventories
All of the components in the product are on the following Inventory lists
Canada (DSL/NDSL) Europe (EINECS/ELINCS/NLP) Australia (AICS) South Korea (KECL): China (IECSC) ENCS (Japan):
X - Listed
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
Canada (DSL/NDSL) Europe (EINECS/ELINCS/NLP) Australia (AICS) South Korea (KECL): China (IECSC) ENCS (Japan):
X - Listed
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
| Chemical name | TSCA | DSL | NDSL | EINECS | ELINCS | ENCS | IECSC | KECL | PICCS | AICS |
|---|---|---|---|---|---|---|---|---|---|---|
| Phoxim | - | X | - | X | - | X | X | X | - | X |
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute health hazardYes
Chronic Health Hazard
Yes
Fire hazard
No
Sudden release of pressure hazard
No
Reactive hazard
No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).
| Chemical name | CWA - Reportable Quantities | CWA - Toxic Pollutants | CWA - Priority Pollutants | CWA - Hazardous Substances |
|---|---|---|---|---|
| Phoxim 14816-18-3 | X | X |
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
| Chemical name | New Jersey | Massachusetts | Pennsylvania |
|---|---|---|---|
| Phoxim 14816-18-3 | X | Not Listed | X |
Abbreviations and acronyms
CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.