Chemical Safety Data Sheet MSDS / SDS

Zinc sulphate

Revision Date:2022-11-19Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: Zinc sulphate
  • CBnumber: CB2727299
  • CAS: 7733-02-0
  • EINECS Number: 231-793-3
  • Synonyms: zinc sulfate,Zinc Sulphate

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 400-158-6606

SECTION 2: Hazards identification

Classification of the substance or mixture

Acute toxicity - Category 4, Oral

Serious eye damage, Category 1

Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1

Label elements

Pictogram(s)
  • Signal wordDanger
Hazard statement(s)

H318 Causes serious eye damage

H319 Causes serious eye irritation

H401 Toxic to aquatic life

H410 Very toxic to aquatic life with long lasting effects

H411 Toxic to aquatic life with long lasting effects

Precautionary statement(s)

P264 Wash hands thoroughly after handling.

P264 Wash skin thouroughly after handling.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313 IF eye irritation persists: Get medical advice/attention.

P501 Dispose of contents/container to..…

Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P273 Avoid release to the environment.

Response

P301+P317 IF SWALLOWED: Get medical help.

P330 Rinse mouth.

P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P317 Get medical help.

P391 Collect spillage.

Storage

none

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards

no data available

SECTION 3: Composition/information on ingredients

Substance

  • Product name: Zinc sulphate
  • Synonyms: zinc sulfate,Zinc Sulphate
  • CAS: 7733-02-0
  • EC number: 231-793-3
  • MF: O4SZn
  • MW: 161.45

SECTION 4: First aid measures

Description of first aid measures

If inhaled

Fresh air, rest. Seek medical attention if you feel unwell.

Following skin contact

Rinse skin with plenty of water or shower.

Following eye contact

Rinse with plenty of water for several minutes (remove contact lenses if easily possible).

Following ingestion

Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .

Most important symptoms and effects, both acute and delayed

no data available

Indication of any immediate medical attention and special treatment needed

no data available

SECTION 5: Firefighting measures

Extinguishing media

Use dry chemical, carbon dioxide or alcohol-resistant foam.

Specific Hazards Arising from the Chemical

Not combustible.

Advice for firefighters

In case of fire in the surroundings, use appropriate extinguishing media.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.

Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Dry. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.

SECTION 8: Exposure controls/personal protection

Control parameters

Occupational Exposure limit values

MAK: (respirable fraction): 0.1 mg/m3; peak limitation category: I(4).MAK: (inhalable fraction): 2 mg/m3; peak limitation category: I(2).MAK: pregnancy risk group: C

Biological limit values

no data available

Exposure controls

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

Individual protection measures

Eye/face protection

Wear safety spectacles.

Skin protection

Protective gloves.

Respiratory protection

Use local exhaust or breathing protection.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Physical stateLiquid
  • ColourColorless
  • Odour

    no data available

  • Melting point/freezing point

    > 231 - < 276 °C. Atm. press.:Ca. 1 atm. Remarks:Monohydrate in nitrogen atmosphere.;> 56 - < 76 °C. Atm. press.:Ca. 1 atm. Remarks:Monohydrate in nitrogen.;> 56 - < 79 °C. Atm. press.:Ca. 1 atm. Remarks:Heptahydrate in nitrogen.

  • Boiling point or initial boiling point and boiling range

    330°C at 760 mmHg

  • Flammability

    no data available

  • Lower and upper explosion limit/flammability limit

    no data available

  • Flash point

    no data available

  • Auto-ignition temperature

    no data available

  • Decomposition temperature

    no data available

  • pH4.0±0.5
  • Kinematic viscosity

    no data available

  • SolubilityH2O: soluble
  • Partition coefficient n-octanol/water

    -0.07

  • Vapour pressure

    no data available

  • Density and/or relative density

    3.35 g/cm3. Temperature:22 °C.;2.05 g/cm3. Temperature:22 °C.;1.98 g/cm3. Temperature:22 °C.

  • Relative vapour density

    no data available

  • Particle characteristics

    no data available

SECTION 10: Stability and reactivity

Reactivity

no data available

Chemical stability

no data available

Possibility of hazardous reactions

The solution in water is a weak acid.

Conditions to avoid

no data available

Incompatible materials

no data available

Hazardous decomposition products

no data available

SECTION 11: Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: no data available
  • Dermal: LD50 - rat (male/female) - > 2 000 mg/kg bw.
  • Skin corrosion/irritation

    no data available

    Serious eye damage/irritation

    no data available

    Respiratory or skin sensitization

    no data available

    Germ cell mutagenicity

    no data available

    Carcinogenicity

    no data available

    Reproductive toxicity

    no data available

    STOT-single exposure

    The substance is severely irritating to the eyes. The substance is irritating to the gastrointestinal tract and respiratory tract.

    STOT-repeated exposure

    no data available

    Aspiration hazard

    A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.

    SECTION 12: Ecological information

    Toxicity

  • Toxicity to fish: LC50 - Thymallus arcticus - 315 μg/L - 96 h.
  • Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna - 860 μg/L - 48 h.
  • Toxicity to algae: NOEC - Ulva pertusa, Green macroalga, Ulvaceae - 313 μg/L - 5 d.
  • Toxicity to microorganisms: EC50 - activated sludge of a predominantly domestic sewage - 5.2 mg/L - 3 h. Remarks:Respiration rate.
  • Persistence and degradability

    no data available

    Bioaccumulative potential

    no data available

    Mobility in soil

    no data available

    Other adverse effects

    no data available

    SECTION 13: Disposal considerations

    Disposal methods

    Product

    The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

    Contaminated packaging

    Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

    SECTION 14: Transport information

    UN Number

    ADR/RID: UN3082 (For reference only, please check.)

    IMDG: UN3082 (For reference only, please check.)

    IATA: UN3082 (For reference only, please check.)

    UN Proper Shipping Name

    ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (For reference only, please check.)

    IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (For reference only, please check.)

    IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (For reference only, please check.)

    Transport hazard class(es)

    ADR/RID: 9 (For reference only, please check.)

    IMDG: 9 (For reference only, please check.)

    IATA: 9 (For reference only, please check.)

    Packing group, if applicable

    ADR/RID: III (For reference only, please check.)

    IMDG: III (For reference only, please check.)

    IATA: III (For reference only, please check.)

    Environmental hazards

    ADR/RID: Yes

    IMDG: Yes

    IATA: Yes

    Special precautions for user

    no data available

    Transport in bulk according to IMO instruments

    no data available

    SECTION 15: Regulatory information

    Safety, health and environmental regulations specific for the product in question

    European Inventory of Existing Commercial Chemical Substances (EINECS)
    Listed.
    EC Inventory
    Listed.
    United States Toxic Substances Control Act (TSCA) Inventory
    Listed.
    China Catalog of Hazardous chemicals 2015
    Not Listed.
    New Zealand Inventory of Chemicals (NZIoC)
    Listed.
    PICCS
    Listed.
    Vietnam National Chemical Inventory
    Listed.
    IECSC
    Listed.
    Korea Existing Chemicals List (KECL)
    Listed.

    SECTION 16: Other information

    Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%
  • References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/
  • Disclaimer:

    The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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