Chemical Safety Data Sheet MSDS / SDS
Zinc silicate
Revision Date:2026-03-21Revision Number:1
Product identifier
- Product name: Zinc silicate
- CBnumber: CB6270470
- CAS: 68611-47-2
- EINECS Number: 271-896-0
- Synonyms: fluorescence
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordWarning
P501 Dispose of contents/container to..…
P391 Collect spillage. Hazardous to the aquatic environment
P273 Avoid release to the environment.
Hazard statements
H410 Very toxic to aquatic life with long lasting effects
Substance
- Product name: Zinc silicate
- Synonyms: fluorescence
- CAS: 68611-47-2
- EC number: 271-896-0
- MF: Zn2SiO4
- MW: 222.9
4.1 Description of first-aid measures
No data available
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
4.4 Notes to physician
No data available
5.1 Extinguishing media
No data available
5.2 Special hazards arising from the substance or mixture
Nature of decomposition products not known.
Not combustible.
Not combustible.
5.3 Advice for firefighters
No data available
6.1 Personal precautions, protective equipment and emergency procedures
For personal protection see section 8.
6.2 Environmental precautions
No data available
6.3 Methods and materials for containment and cleaning up
No data available
6.4 Reference to other sections
For disposal see section 13.
7.1 Precautions for safe handling
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Recommended storage temperature see product label.
Storage class
Storage class (TRGS 510): 13: Non Combustible Solids
8.1 Control parameters
Ingredients with workplace control parameters| ['Component', 'CAS-No.', 'Value', 'Control\nparameters', 'Basis'] | ['Silicic acid\n(H4SiO4), zinc\nsalt (1:2),\nmanganese-doped', '68611-47-\n2', 'PC-TWA', '0.15 mg/m3', 'Occupational exposure limits for\nhazardous agents in the\nworkplace - Chemical\nhazardous agents.'] |
|---|
8.2 Exposure controls
Personal protective equipmentSkin protection
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:KCL 741 L
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:KCL 741 L
Control of environmental exposure
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:KCL 741 L
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:KCL 741 L
Prevent product from entering drains.
Information on basic physicochemical properties
- a) Physical statesolid
- b) Colorwhite
- c) Odorodorless
- d) Melting point/freezing pointMelting point/ range: > 450 °C at 1,013 hPa - OECD Test
Guideline 102 - e) Initial boiling point and boiling rangeNo data available
- f) Flammability (solid, gas)The product is not flammable. - Flammability (solids)
- g) Upper/lower flammability or explosive limitsNo data available
- h) Flash pointNot applicable
- i) Autoignition temperature> 450 °C - Relative self-ignition temperature for solidsdoes not ignite
- j) Decomposition temperatureNo data available
- k) pH7.0 (H2O)suspension
- l) ViscosityViscosity, kinematic: No data available
Viscosity, dynamic: No data available - m) Water solubility1 g/l at 25 °C - OECD Test Guideline 105- insoluble
- n) Partition coefficient n-octanol/waterNot applicable for inorganic substances
- o) Vapor pressureNo data available
- p) Density4.0 g/cm3 at 20 °C
- Relative density0.93 at 25 °C - OECD Test Guideline 109
- r) Particle characteristicsNo data available
- s) Explosive propertiesNo data available
- t) Oxidizing propertiesnone
- Solubility<0.1g/l
9.2 Other safety information
Bulk densityca.1,450 kg/m3
10.1 Chemical stability
No data available
10.2 Possibility of hazardous reactions
no information available
10.3 Conditions to avoid
No data available
10.4 Incompatible materials
Strong oxidizing agents
10.5 Hazardous decomposition products
In the event of fire: see section 5
11.1 Information on toxicological effects
Acute toxicityLD50 Oral - Rat - female - > 2,000 mg/kg (OECD Test Guideline 425)
Inhalation: No data available
Dermal: No data available
Skin corrosion/irritation
Inhalation: No data available
Dermal: No data available
Skin - reconstructed human epidermis (RhE)
Result: No skin irritation - 1 h (OECD Test Guideline 431)
Serious eye damage/eye irritation
Result: No skin irritation - 1 h (OECD Test Guideline 431)
Eyes - In vitro study
Result: No eye irritation - 6 h (OECD Test Guideline 492)
Respiratory or skin sensitization
Result: No eye irritation - 6 h (OECD Test Guideline 492)
Local lymph node assay (LLNA) - Mouse
Result: negative (OECD Test Guideline 429)
Germ cell mutagenicity
Result: negative (OECD Test Guideline 429)
Test Type: Ames test
Test system: S. typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Carcinogenicity
Test system: S. typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Classified based on available data. For more details, see section 2
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
Classified based on available data. For more details, see section 2
Specific target organ toxicity - repeated exposure
Classified based on available data. For more details, see section 2
Aspiration hazard
Classified based on available data. For more details, see section 2
11.2 Additional Information
Central nervous system depression, Pneumonia, Men exposed to manganese dusts showed a decrease in fertility. Chronic manganese poisoning primarily involves the central nervous system. Early symptoms include languor, sleepiness and weakness in the legs. A stolid mask-like appearance of the face, emotional disturbances such as uncontrollable laughter and a spastic gait with tendency to fall in walking are findings in more advanced cases.
High incidence of pneumonia has been found in workers exposed to the dust or fume of some manganese compounds.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Hazardous properties cannot be excluded but are unlikely when the product is handled appropriately.
Handle in accordance with good industrial hygiene and safety practice.
High incidence of pneumonia has been found in workers exposed to the dust or fume of some manganese compounds.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Hazardous properties cannot be excluded but are unlikely when the product is handled appropriately.
Handle in accordance with good industrial hygiene and safety practice.
12.1 Toxicity
Toxicity to daphnia static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h and other aquatic (OECD Test Guideline 202) invertebrates
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata - 0.4 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata - 0.4 mg/l - 72 h (OECD Test Guideline 201)
12.2 Persistence and degradability
The methods for determining biodegradability are not applicable to inorganic substances.
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Endocrine disrupting properties
No data available
12.7 Other adverse effects
No data available
14.1 UN number
ADR/RID: 3077
IMDG: 3077
IATA-DGR: 3077
IMDG: 3077
IATA-DGR: 3077
14.2 UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Silicic acid (H4SiO4), zinc salt (1:2), manganese-doped)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Silicic acid (H4SiO4), zinc salt (1:2), manganese-doped)
IATA-DGR: Environmentally hazardous substance, solid, n.o.s. (Silicic acid (H4SiO4), zinc salt (1:2), manganese-doped)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Silicic acid (H4SiO4), zinc salt (1:2), manganese-doped)
IATA-DGR: Environmentally hazardous substance, solid, n.o.s. (Silicic acid (H4SiO4), zinc salt (1:2), manganese-doped)
14.3 Transport hazard class(es)
ADR/RID: 9
IMDG: 9
IATA-DGR: 9
IMDG: 9
IATA-DGR: 9
14.4 Packaging group
ADR/RID: III
IMDG: III
IATA-DGR: III
IMDG: III
IATA-DGR: III
14.5 Environmental hazards
ADR/RID: yes
IMDG Marine pollutant: yes
IATA-DGR: yes
IMDG Marine pollutant: yes
IATA-DGR: yes
14.6 Special precautions for user
14.7 Incompatible materials
Strong oxidizing agents
Further information: EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.Packages smaller than or equal to 5 kg / L , not dangerous goods of
Class 9
Further information: EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.Packages smaller than or equal to 5 kg / L , not dangerous goods of
Class 9
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulatory information
Law on the Prevention and Control of Occupational Diseases
Regulations on Occupational Labor Protection in the at workplaces where Toxic
Substances Are Used
Catalogue of Highly Toxic Chemicals : Listed
Other regulations
Please pay attention on the waste treatment should also comply with local regulations requirement.
Law on the Prevention and Control of Occupational Diseases
Regulations on Occupational Labor Protection in the at workplaces where Toxic
Substances Are Used
Catalogue of Highly Toxic Chemicals : Listed
Other regulations
Please pay attention on the waste treatment should also comply with local regulations requirement.
Abbreviations and acronyms
CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.
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