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ChemicalBook >> CAS DataBase List >> Lithium tri-tert-butoxyaluminum hydride

Lithium tri-tert-butoxyaluminum hydride

Lithium tri-tert-butoxyaluminum hydride price.
  • $34.65 - $2417.82
  • Product name: Lithium tri-tert-butoxyaluminum hydride
  • CAS: 17476-04-9
  • MF: C12H28AlO3.Li
  • MW: 254.27
  • EINECS:241-490-8
  • MDL Number:MFCD00011532
  • Synonyms:Lithium hydridotris(tert-butoxy)aluminate, nominally 1M in THF, packaged under Argon in resealable ChemSealTM bottle;Lithium hydridotris(tert-butoxy)aluminate, 90% min;LITHIUM TRI-(T-BUTOXY)-ALUMINUM HYDRIDE;LITHIUM TRI-TERT-BUTOXYALUMINUM HYDRIDE;LITHIUM ALUMINIUM TRI-TERT-BUTOXYHYDRIDE;LITHIUM HYDRIDOTRIS(TERT-BUTOXY)ALUMINATE;LITHIUM HYDRIDOTRI-TERT-BUTOXOALUMINATE;LITHIUM TRI-TERT-BUTOXYALUMINOHYDRIDE, 1 .0M SOLUTION IN TETRAHYDROFURAN
14 prices
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Brand

  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Medical Isotopes, Inc.
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC

Package

  • 1g
  • 5g
  • 0.1mole
  • 10ml
  • 10g
  • 0.5mole
  • 25g
  • 50ml
  • 100ML
  • 100g
  • 800ml
  • ManufacturerAlfa Aesar
  • Product number043324
  • Product descriptionLithium tri-tert-butoxyaluminum hydride, nominally 1M in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging10ml
  • Price$34.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number030716
  • Product descriptionLithium tri-tert-butoxyaluminum hydride, 94%
  • Packaging10g
  • Price$93.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number043324
  • Product descriptionLithium tri-tert-butoxyaluminum hydride, nominally 1M in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging50ml
  • Price$149
  • Updated2024-03-01
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004421
  • Product descriptionLITHIUM TRI-TERT-BUTOXYALUMINUM HYDRIDE 95.00%
  • Packaging100ML
  • Price$2417.82
  • Updated2021-12-16
  • Buy
  • ManufacturerMedical Isotopes, Inc.
  • Product number71142
  • Product descriptionLithium tri-tert-butoxyaluminum hydride solution
  • Packaging1g
  • Price$610
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product numberL2904
  • Product descriptionLithium tri-tert-butoxyaluminum hydride 97%
  • Packaging5g
  • Price$123
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product numberL2904
  • Product descriptionLithium tri-tert-butoxyaluminum hydride 97%
  • Packaging25g
  • Price$159
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number241814
  • Product descriptionLithium tri-tert-butoxyaluminum hydride solution 1.0 M in THF
  • Packaging100ml
  • Price$212
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product numberL2904
  • Product descriptionLithium tri-tert-butoxyaluminum hydride 97%
  • Packaging100g
  • Price$378
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number241814
  • Product descriptionLithium tri-tert-butoxyaluminum hydride solution 1.0 M in THF
  • Packaging800ml
  • Price$708
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number03-4850
  • Product descriptionLithium tri-t-butoxyaluminohydride, ~1.0M in THF
  • Packaging0.1mole
  • Price$226
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number03-4850
  • Product descriptionLithium tri-t-butoxyaluminohydride, ~1.0M in THF
  • Packaging0.5mole
  • Price$853
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberL0159
  • Product descriptionLithium Tri-tert-butoxyaluminum Hydride (ca. 30% in Tetrahydrofuran, ca. 1.0mol/L)
  • Packaging100mL
  • Price$117
  • Updated2021-12-16
  • Buy
  • ManufacturerTRC
  • Product numberL469165
  • Product descriptionLithium tri-tert-butoxyaluminum hydride solution
  • Packaging1g
  • Price$120
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 043324 Lithium tri-tert-butoxyaluminum hydride, nominally 1M in THF, packaged under Argon in resealable ChemSeal? bottles 10ml $34.65 2024-03-01 Buy
Alfa Aesar 030716 Lithium tri-tert-butoxyaluminum hydride, 94% 10g $93.65 2024-03-01 Buy
Alfa Aesar 043324 Lithium tri-tert-butoxyaluminum hydride, nominally 1M in THF, packaged under Argon in resealable ChemSeal? bottles 50ml $149 2024-03-01 Buy
American Custom Chemicals Corporation ING0004421 LITHIUM TRI-TERT-BUTOXYALUMINUM HYDRIDE 95.00% 100ML $2417.82 2021-12-16 Buy
Medical Isotopes, Inc. 71142 Lithium tri-tert-butoxyaluminum hydride solution 1g $610 2021-12-16 Buy
Sigma-Aldrich L2904 Lithium tri-tert-butoxyaluminum hydride 97% 5g $123 2024-03-01 Buy
Sigma-Aldrich L2904 Lithium tri-tert-butoxyaluminum hydride 97% 25g $159 2024-03-01 Buy
Sigma-Aldrich 241814 Lithium tri-tert-butoxyaluminum hydride solution 1.0 M in THF 100ml $212 2024-03-01 Buy
Sigma-Aldrich L2904 Lithium tri-tert-butoxyaluminum hydride 97% 100g $378 2024-03-01 Buy
Sigma-Aldrich 241814 Lithium tri-tert-butoxyaluminum hydride solution 1.0 M in THF 800ml $708 2024-03-01 Buy
Strem Chemicals 03-4850 Lithium tri-t-butoxyaluminohydride, ~1.0M in THF 0.1mole $226 2024-03-01 Buy
Strem Chemicals 03-4850 Lithium tri-t-butoxyaluminohydride, ~1.0M in THF 0.5mole $853 2024-03-01 Buy
TCI Chemical L0159 Lithium Tri-tert-butoxyaluminum Hydride (ca. 30% in Tetrahydrofuran, ca. 1.0mol/L) 100mL $117 2021-12-16 Buy
TRC L469165 Lithium tri-tert-butoxyaluminum hydride solution 1g $120 2021-12-16 Buy

Properties

Melting point :300-319 °C (dec.) (lit.)
Boiling point :66°C (THF)
Density :0.942 g/mL at 25 °C
Flash point :95 °F
storage temp. :2-8°C
solubility :It is soluble in organic solvents at low temperatures.
form :Solution
color :Clear to slightly turbid colorless
Water Solubility :Reacts with water.
Sensitive :Air & Moisture Sensitive
BRN :5796791
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) Stability :Stable. Incompatible with alcohols. Reacts violently with water. Highly flammable.
InChIKey :BYBIDFZFKATBFH-UHFFFAOYSA-N
CAS DataBase Reference :17476-04-9(CAS DataBase Reference)
EPA Substance Registry System :Aluminate(1-), hydrotris(2-methyl-2-propanolato)-, lithium, (T-4)- (17476-04-9)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Lithium tri-tert-butoxyaluminum hydride is less reactive than lithium aluminum hydride (LAH) and is very useful in selective reductions of acyl halides, aldehydes, ketones, and esters. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff. LAH, is a reducing agent commonly employed in modern organic synthesis.

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