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ChemicalBook >> CAS DataBase List >> (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM price.
  • $16 - $8610
  • Product name: (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
  • CAS: 301224-40-8
  • MF: C31H37Cl2N2ORu
  • MW: 625.62
  • EINECS:608-446-3
  • MDL Number:MFCD03701614
  • Synonyms:(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM;RUTHENIUM,[1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO[[2-(1-METHYLETHOXY)PHENYL]METHYLENE];[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxyphenylmethylene)ruthenium;Hoveyda-Grubbs Catalyst 2nd Generation,(1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium;(1,3-Bis-(2,4,6-triMethylphenyl)-2-iMidazolidinylidene)dichloro (o-isopropylphenylMethylene)rutheniuM;(1,3-DiMesityliMidazolidin-2-ylidene)(2-isopropoxybenzylidene)rutheniuM(VI) chloride;Dichloro(1,3-diMesityl-2-iMidazolidinylidene)(2-isopropoxybenzylidene)rutheniuM;Hoveyda-Grubbs Catalyst 2nd Generation,97%
Price23 Properties Safety Information Description
23 prices
Selected condition：
Brand
  • Abosyn
  • AK Scientific
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • Chemenu
  • ChemScene
  • Sigma-Aldrich
  • TRC
Package
  • 100mg
  • 0.25g
  • 250mg
  • 500mg
  • 1g
  • 2g
  • 5g
  • 10g
  • 25g
  • 200g
  • ManufacturerAbosyn
  • Product number61-5932
  • Product description(1,3-dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98+%
  • Packaging0.25g
  • Price$1300
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ97807
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride
  • Packaging250mg
  • Price$81
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number301224408
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride
  • Packaging1g
  • Price$197.96
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number301224408
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride
  • Packaging5g
  • Price$625.21
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685700
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98%
  • Packaging100mg
  • Price$16
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685700
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98%
  • Packaging250mg
  • Price$35
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685700
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98%
  • Packaging1g
  • Price$103
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685700
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98%
  • Packaging5g
  • Price$473
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA685700
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98%
  • Packaging10g
  • Price$851
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004327
  • Product descriptionHOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00%
  • Packaging100MG
  • Price$463.8
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004327
  • Product descriptionHOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00%
  • Packaging250MG
  • Price$500
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004327
  • Product descriptionHOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00%
  • Packaging1G
  • Price$608
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM102933
  • Product description(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 95+%
  • Packaging200g
  • Price$7875
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W007938
  • Product descriptionHoveyda-Grubbs2nd ≥98.0%
  • Packaging250mg
  • Price$53
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W007938
  • Product descriptionHoveyda-Grubbs2nd ≥98.0%
  • Packaging1g
  • Price$145
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W007938
  • Product descriptionHoveyda-Grubbs2nd ≥98.0%
  • Packaging5g
  • Price$570
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Abosyn 61-5932 (1,3-dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98+% 0.25g $1300 2021-12-16 Buy
AK Scientific J97807 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 250mg $81 2021-12-16 Buy
Alichem 301224408 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 1g $197.96 2021-12-16 Buy
Alichem 301224408 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 5g $625.21 2021-12-16 Buy
Ambeed A685700 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98% 100mg $16 2021-12-16 Buy
Ambeed A685700 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98% 250mg $35 2021-12-16 Buy
Ambeed A685700 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98% 1g $103 2021-12-16 Buy
Ambeed A685700 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98% 5g $473 2021-12-16 Buy
Ambeed A685700 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 98% 10g $851 2021-12-16 Buy
American Custom Chemicals Corporation ING0004327 HOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00% 100MG $463.8 2021-12-16 Buy
American Custom Chemicals Corporation ING0004327 HOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00% 250MG $500 2021-12-16 Buy
American Custom Chemicals Corporation ING0004327 HOVEYDA-GRUBBS CATALYST 2NDGENERATION 95.00% 1G $608 2021-12-16 Buy
Chemenu CM102933 (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI)chloride 95+% 200g $7875 2021-12-16 Buy
ChemScene CS-W007938 Hoveyda-Grubbs2nd ≥98.0% 250mg $53 2021-12-16 Buy
ChemScene CS-W007938 Hoveyda-Grubbs2nd ≥98.0% 1g $145 2021-12-16 Buy
ChemScene CS-W007938 Hoveyda-Grubbs2nd ≥98.0% 5g $570 2021-12-16 Buy
Next Last

Properties

Melting point :216-220 °C(lit.)
storage temp. :2-8°C
solubility :Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form :Solid
color :Green to Very Dark Green
Stability :Hygroscopic
InChIKey :ZRPFJAPZDXQHSM-UHFFFAOYSA-L
CAS DataBase Reference :301224-40-8
EPA Substance Registry System :Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-.kappa.O)phenyl]methylene-.kappa.C]-, (SP-5-41)- (301224-40-8)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Description

It′s a phosphine free version of Grubbs 2nd Generation Catalyst with comparable reactivity, but initiates more readily at lower temperatures. Efficient for metathesis of electron-deficient substrates including fluorinated olefins. Demonstrated in multiple large-scale pharmaceutical applications.
It can be used as a catalyst for olefin cross-metathesis with fluorinated olefins (CM), ring-closing metathesis (RCM), ring-opening metathesis (ROM), and a sequence of a metathesis reaction and subsequent dihydroxylation of the newly formed double bond.

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Suppliers and manufacturers

career henan chemical co
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
$1.00 /1KG
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM CAS:301224-40-8
Capot Chemical Co.,Ltd.
ATK CHEMICAL COMPANY LIMITED
AB PharmaTech,LLC
Changzhou Ansciep Chemical Co., Ltd.
Hubei Jusheng Technology Co.,Ltd.
Chongqing Chemdad Co., Ltd
Alchem Pharmtech,Inc.
CONIER CHEM AND PHARMA LIMITED
Richest Group Ltd