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118-30-9

118-30-9 Structure

118-30-9 Structure
IdentificationBack Directory
[Name]

2-ethoxy-1-naphthylamine
[CAS]

118-30-9
[Synonyms]

2-ethoxy-1-naphthylamine
2-ethoxynaphthalen-1-amine
2-Ethoxy-1-naphthalenamine
1-Amino-2-ethoxynaphthalene
1-Naphthalenamine, 2-ethoxy-
[EINECS(EC#)]

204-243-5
[Molecular Formula]

C12H13NO
[MDL Number]

MFCD14534842
[MOL File]

118-30-9.mol
[Molecular Weight]

187.24
Chemical PropertiesBack Directory
[Melting point ]

48-49 °C(Solv: ethanol (64-17-5))
[Boiling point ]

339.5±17.0 °C(Predicted)
[density ]

1.125±0.06 g/cm3(Predicted)
[pka]

3.40±0.10(Predicted)
Hazard InformationBack Directory
[Uses]

Sulfonation (H2SO4, 60℃) of 158 gives 1-amino-2-ethoxynaphthalene-6-sulfonic acid for use principally as an intermediate component in azo direct green dyes.
[Synthesis]

?A solution of 2-ethoxynaphthalene in 1,2-dichlorobenzene is reacted with nitric acid at 45℃. The organic layer is separated and washed at 60℃ before cooling to crystallize 1-nitro-2-ethoxynaphthalene (mp 95 – 100℃) in 80 % yield. Reduction with iron gives 2-ethoxy-1-naphthylamine in 74 % yield.
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