ChemicalBook--->CAS DataBase List--->1333981-84-2

1333981-84-2

1333981-84-2 Structure

1333981-84-2 Structure
IdentificationBack Directory
[Name]

N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2
[CAS]

1333981-84-2
[Synonyms]

(R,R)-Ts-DENEB
(R,R)-Ts-DENEB[R]
(R,R)-Ts-DENEB(regR)
N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II)
Chloro{N-[(1R,2R)-1,2-diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II)
Ruthenium(2+) chloride [(1R,2R)-2-({2-[(4-methylbenzyl)oxy]ethyl}amino)-1,2-diphenylethyl][(4-methylphenyl)sulfonyl]azanide (1:1:1)
Chloro{N-[(1R,2R)-1,2-diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (R,R)-Ts-DENEB(TM)
N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2
[Molecular Formula]

C31H33ClN2O3RuS
[MDL Number]

MFCD20922902
[MOL File]

1333981-84-2.mol
[Molecular Weight]

645.16
Chemical PropertiesBack Directory
[form ]

solid
[color ]

gray to brown
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS08,GHS09
[Signal word ]

Warning
[Hazard statements ]

H373-H351-H411
[Precautionary statements ]

P501-P273-P260-P202-P201-P280-P391-P308+P313-P405
[RIDADR ]

UN 3077 9/PG III
[HS Code ]

2843.90.0000
[HazardClass ]

9
[PackingGroup ]

III
Questions And AnswerBack Directory
[Reaction]

Catalyst used for asymmetric -transfer hydrogenation. Reactions of 1333981-84-2_1 Catalyst used for asymmetric H2 – hydrogenation. Reactions of 1333981-84-2_2 3. Catalyst used for dynamic kinetic resolution. Reactions of 1333981-84-2_3
Hazard InformationBack Directory
[Uses]

(R,R)-Ts-DENEB (CAS# 1333981-84-2) is a catalyst used in asymmetric hydrogen transfer reactions, such as in the synthesis of 2-(1,2,3,4-tetrahydro-1-isoquinolyl)ethanol derivatives. (R,R)-Ts-DENEB is used to form hydrogen carrier systems, where the catalytic dehydrogenative coupling of methanol and 1,2-diamine is used to generate H2 without the production of CO2.
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