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13865-50-4

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13865-50-4 Structure

13865-50-4 Structure
IdentificationBack Directory
[Name]

METHOXYMETHYL PHENYL SULFIDE
[CAS]

13865-50-4
[Synonyms]

ALPHA-METHOXYTHIOANISOLE
Methoxy(phenylthio)methane
Phenylthiomethylmethyl ether
methoxymethylsulfanylbenzene
[(METHOXYMETHYL)THIO]BENZENE
METHOXYMETHYL PHENYL SULFIDE
METHYL PHENYLTHIOMETHYL ETHER
MethoxymethylPhenylSulfide>
(MethoxyMethyl)(phenyl)sulfane
Benzene, [(methoxymethyl)thio]-
alpha-Methoxythioanisole Methyl Phenylthiomethyl Ether
[Molecular Formula]

C8H10OS
[MDL Number]

MFCD00008496
[MOL File]

13865-50-4.mol
[Molecular Weight]

154.23
Chemical PropertiesBack Directory
[Boiling point ]

113-114 °C18 mm Hg(lit.)
[density ]

1.047 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.5632(lit.)
[Fp ]

203 °F
[form ]

clear liquid
[color ]

Colorless to Almost colorless
Safety DataBack Directory
[RIDADR ]

UN 3334
[WGK Germany ]

3
[HS Code ]

29309090
Hazard InformationBack Directory
[Uses]

Methoxymethyl phenyl sulfide has been used in the preparation of methoxymethyl phenyl sulfoxide.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 51, p. 879, 1986 DOI: 10.1021/jo00356a025
[General Description]

Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide to methoxymethyl benzenesulfenate has been reported. Methoxymethyl phenyl sulfide undergoes solvent free permanganate oxidation to yield methoxymethyl phenyl sulfone.
Spectrum DetailBack Directory
[Spectrum Detail]

METHOXYMETHYL PHENYL SULFIDE(13865-50-4)1HNMR
METHOXYMETHYL PHENYL SULFIDE(13865-50-4)Raman
METHOXYMETHYL PHENYL SULFIDE(13865-50-4)IR
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